Strong metal-support interactions on gold nanoparticle catalysts achieved through Le Chatelier's principle

doi:10.1038/s41929-021-00611-3

IMR OpenIR

	Strong metal-support interactions on gold nanoparticle catalysts achieved through Le Chatelier's principle
	Wang, Hai 1; Wang, Liang 1; Lin, Dong 2; Feng, Xiang 2; Niu, Yiming 3; Zhang, Bingsen 3; Xiao, Feng-Shou 1,4
通讯作者	Wang, Liang(liangwang@zju.edu.cn) ; Xiao, Feng-Shou(fsxiao@zju.edu.cn)
	2021-05-10
发表期刊	NATURE CATALYSIS
ISSN	2520-1158
页码	7
摘要	Strong metal-support interactions (SMSIs) are crucial for the preparation of supported metal catalysts. A prevailing view is that the redox feature of the metal oxide support is the driving force behind SMSI construction. Herein we demonstrate CO2-induced SMSIs between irreducible oxide MgO and noble gold nanoparticles, presenting electronic and geometric features that are similar to those of classical SMSIs. The key to these interactions is activating the oxide surface by a reversible reaction, MgO + CO2 reversible arrow MgCO3, which leads to migration of the support onto the gold nanoparticles to form thin overlayers. The overlayer is permeable to the reactant molecules, stable under the oxidation conditions and even water tolerant, resulting in sinter-resistant gold nanoparticle catalysts. This investigation provides an approach for the rational design and optimization of supported metal catalysts based on irreducible oxides, and deepens our understanding of the mechanism of SMSI formation.
资助者	National Key Research and Development Program of China ; National Natural Science Foundation of China ; Natural Science Foundation of Zhejiang Province
DOI	10.1038/s41929-021-00611-3
收录类别	SCI
语种	英语
资助项目	National Key Research and Development Program of China[2018YFD1000806-01] ; National Natural Science Foundation of China[21822203] ; National Natural Science Foundation of China[21932006] ; Natural Science Foundation of Zhejiang Province[LR18B030002]
WOS研究方向	Chemistry
WOS类目	Chemistry, Physical
WOS记录号	WOS:000648815300001
出版者	NATURE RESEARCH
引用统计	被引频次：173[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/162132
专题	中国科学院金属研究所
通讯作者	Wang, Liang; Xiao, Feng-Shou
作者单位	1.Zhejiang Univ, Coll Chem & Biol Engn, Minist Educ, Key Lab Biomass Chem Engn, Hangzhou, Peoples R China 2.China Univ Petr, State Key Lab Heavy Oil Proc, Qingdao, Peoples R China 3.Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, Shenyang, Peoples R China 4.Zhejiang Univ, Dept Chem, Key Lab Appl Chem Zhejiang Prov, Hangzhou, Peoples R China
推荐引用方式 GB/T 7714	Wang, Hai,Wang, Liang,Lin, Dong,et al. Strong metal-support interactions on gold nanoparticle catalysts achieved through Le Chatelier's principle[J]. NATURE CATALYSIS,2021:7.
APA	Wang, Hai.,Wang, Liang.,Lin, Dong.,Feng, Xiang.,Niu, Yiming.,...&Xiao, Feng-Shou.(2021).Strong metal-support interactions on gold nanoparticle catalysts achieved through Le Chatelier's principle.NATURE CATALYSIS,7.
MLA	Wang, Hai,et al."Strong metal-support interactions on gold nanoparticle catalysts achieved through Le Chatelier's principle".NATURE CATALYSIS (2021):7.