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Synthesis of amorphous FeNiCo trimetallic hybrid electrode from ZIF precursors for efficient oxygen evolution reaction
Ma,Junchao1; Lu,Xingyu2; Wang,Chao3; Wang,Sha1; He,Wenxiu1; Zhang,Bing1; Shao,Lei1; Zhai,Xu1; Han,Jingrui1; Feng,Shiyi1; Fu,Yu1; Qi,Wei2,4
通讯作者Qi,Wei()
2021-10-27
发表期刊Nanotechnology
ISSN0957-4484
卷号33期号:3
摘要Abstract Development of non-noble multi-metallic electrocatalyst with high oxygen evolution reaction (OER) activity via a simple and low-cost method is of great importance for improving the efficiency of water electro-chemical splitting. Herein, a solution impregnation strategy was proposed to synthesize novel FeNi-doped Co-ZIF-L trimetallic hybrid electrocatalyst using Co-ZIF-L as sacrificial templates and Fe and Ni ions as etchants and dopants. This synthetic strategy could be realized via the etching-coprecipitation mechanism to obtain an amorphous hybrid containing multi-metal hydroxides. The as-prepared electrocatalyst loaded on Ni foam displays a low overpotential of 245 mV at 10 mA·cm?2, a small Tafel slope of 54.9 mV·dec?1, and excellent stability at least 12 h in the OER process. The facile and efficient synthetic strategy presents a new entry for the fabrication of ZIFs-derived multi-metallic electrocatalysts for OER electrocatalysis.
关键词Co-ZIF-L trimetallic hybrid electrocatalyst solution impregnation oxygen evolution reaction
DOI10.1088/1361-6528/ac2dc9
语种英语
WOS记录号IOP:nano_33_3_035403
出版者IOP Publishing
引用统计
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/166508
专题中国科学院金属研究所
通讯作者Qi,Wei
作者单位1.Department of Chemistry, College of Sciences, Northeastern University, Shenyang 110819, People’s Republic of China
2.Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, People’s Republic of China
3.School of Medical Devices, Shenyang Pharmaceutical University, Shenyang 110016, People’s Republic of China
4.School of Materials Science and Engineering, University of Science and Technology of China, Shenyang 110016, People’s Republic of China
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GB/T 7714
Ma,Junchao,Lu,Xingyu,Wang,Chao,et al. Synthesis of amorphous FeNiCo trimetallic hybrid electrode from ZIF precursors for efficient oxygen evolution reaction[J]. Nanotechnology,2021,33(3).
APA Ma,Junchao.,Lu,Xingyu.,Wang,Chao.,Wang,Sha.,He,Wenxiu.,...&Qi,Wei.(2021).Synthesis of amorphous FeNiCo trimetallic hybrid electrode from ZIF precursors for efficient oxygen evolution reaction.Nanotechnology,33(3).
MLA Ma,Junchao,et al."Synthesis of amorphous FeNiCo trimetallic hybrid electrode from ZIF precursors for efficient oxygen evolution reaction".Nanotechnology 33.3(2021).
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