Atomically dispersed metal catalysts on nanodiamond and its derivatives: synthesis and catalytic application

doi:10.1039/d1cc05202k

IMR OpenIR

	Atomically dispersed metal catalysts on nanodiamond and its derivatives: synthesis and catalytic application
	Chen, Xiaowen 1,2; Jia, Zhimin 1,2; Huang, Fei 2; Diao, Jiangyong 2; Liu, Hongyang 1,2
通讯作者	Liu, Hongyang(liuhy@imr.ac.cn)
	2021-11-04
发表期刊	CHEMICAL COMMUNICATIONS
ISSN	1359-7345
卷号	57 期号:88 页码:11591-11603
摘要	Atomically dispersed metal catalysts (ADMCs) have attracted increasing interest in the field of heterogeneous catalysis. As sub-nanometric catalysts, ADMCs have exhibited remarkable catalytic performance in many reactions. ADMCs are classified into two categories: single atom catalysts (SACs) and atomically dispersed clusters with a few atoms. To stabilize the highly active ADMCs, nanodiamond (ND) and its derivatives (NDDs) are promising supports. In this Feature Article, we have introduced the advantages of NDDs with a highly curved surface and tunable surface properties. The controllable defective sites and oxygen functional groups are known as the anchoring sites for ADMCs. Tunable surface acid-base properties enable ADMCs supported on NDDs to exhibit unique selectivity towards target products and an extended lifetime in many reactions. In addition, we have firstly overviewed the recent advances in the synthesis strategies for effectively fabricating ADMCs on NDDs, and further discussed how to achieve the atomic dispersion of metal precursors and stabilize the as-formed metal atoms against migration and agglomeration based on NDDs. And then, we have also systematically summarized the advantages of ADMCs supported on NDDs in reactions, including hydrogenation, dehydrogenation, aerobic oxidation and electrochemical reaction. These reactions can also effectively guide the design of ADMCs. The recent progress in understanding the effect of structure of active centers and metal-support interactions (MSIs) on the catalytic performance of ADMCs is particularly highlighted. At last, the possible research directions in ADMCs are forecasted.
资助者	National Key R&D Program of China ; National Natural Science Foundation of China ; Liaoning Revitalization Talents Program ; Dalian National Lab for Clean Energy (DNL Cooperation Fund) ; Shenyang National Laboratory for Materials Science ; Sinopec China
DOI	10.1039/d1cc05202k
收录类别	SCI
语种	英语
资助项目	National Key R&D Program of China[2016YFA0204100] ; National Natural Science Foundation of China[21961160722] ; National Natural Science Foundation of China[91845201] ; National Natural Science Foundation of China[22072162] ; Liaoning Revitalization Talents Program[XLYC1907055] ; Dalian National Lab for Clean Energy (DNL Cooperation Fund)[202001] ; Shenyang National Laboratory for Materials Science ; Sinopec China
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000708033200001
出版者	ROYAL SOC CHEMISTRY
引用统计	被引频次：11[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/166620
专题	中国科学院金属研究所
通讯作者	Liu, Hongyang
作者单位	1.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
推荐引用方式 GB/T 7714	Chen, Xiaowen,Jia, Zhimin,Huang, Fei,et al. Atomically dispersed metal catalysts on nanodiamond and its derivatives: synthesis and catalytic application[J]. CHEMICAL COMMUNICATIONS,2021,57(88):11591-11603.
APA	Chen, Xiaowen,Jia, Zhimin,Huang, Fei,Diao, Jiangyong,&Liu, Hongyang.(2021).Atomically dispersed metal catalysts on nanodiamond and its derivatives: synthesis and catalytic application.CHEMICAL COMMUNICATIONS,57(88),11591-11603.
MLA	Chen, Xiaowen,et al."Atomically dispersed metal catalysts on nanodiamond and its derivatives: synthesis and catalytic application".CHEMICAL COMMUNICATIONS 57.88(2021):11591-11603.