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Molten salt synthesis of orthorhombic CrB and Cr2AlB2 ceramics
Wang, Ying1,2; Yang, Ling Xu3; Liu, Rui Jia1,2; Bu, Huan Peng3; Mu, Yong Biao3; Liu, Hui Jun3; Zeng, Chao Liu3; Zhu, Sheng Long1; Fu, Chao3
通讯作者Liu, Hui Jun(hui_jun_liu@163.com) ; Zeng, Chao Liu(clzeng@imr.ac.cn)
2021-11-15
发表期刊CERAMICS INTERNATIONAL
ISSN0272-8842
卷号47期号:22页码:31772-31779
摘要High-purity and fine CrB powders are firstly synthesized from Cr and B powders in (Na, K)Cl molten salt at 850 degrees C for 2 h. Then the as-achieved CrB powders are used as precursors to synthesize homogeneous and size-controlled Cr2AlB2 powders in (Na, K)Cl molten salt at 900 degrees C for 2 h. Additionally, the formation mechanisms of CrB and Cr2AlB2 in (Na, K)Cl molten salt are also investigated. Results show that the Cr atom, formed by disproportionation of Cr2+ ions in molten salt, reacts in-situ with B powders to form CrB. For the formation of Cr2AlB2, Al and CrB migrate mutually and assemble firstly in the molten salt, and then Al intercalates into CrB to generate Cr2AlB2.
关键词MAB phase Cr2AlB2 CrB Molten salt Electrochemistry
DOI10.1016/j.ceramint.2021.08.059
收录类别SCI
语种英语
WOS研究方向Materials Science
WOS类目Materials Science, Ceramics
WOS记录号WOS:000702772700004
出版者ELSEVIER SCI LTD
引用统计
被引频次:10[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/166807
专题中国科学院金属研究所
通讯作者Liu, Hui Jun; Zeng, Chao Liu
作者单位1.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Peoples R China
2.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China
3.Songshan Lake Mat Lab, Dongguan 523808, Peoples R China
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GB/T 7714
Wang, Ying,Yang, Ling Xu,Liu, Rui Jia,et al. Molten salt synthesis of orthorhombic CrB and Cr2AlB2 ceramics[J]. CERAMICS INTERNATIONAL,2021,47(22):31772-31779.
APA Wang, Ying.,Yang, Ling Xu.,Liu, Rui Jia.,Bu, Huan Peng.,Mu, Yong Biao.,...&Fu, Chao.(2021).Molten salt synthesis of orthorhombic CrB and Cr2AlB2 ceramics.CERAMICS INTERNATIONAL,47(22),31772-31779.
MLA Wang, Ying,et al."Molten salt synthesis of orthorhombic CrB and Cr2AlB2 ceramics".CERAMICS INTERNATIONAL 47.22(2021):31772-31779.
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