Revealing tribo-oxidation mechanisms of the copper-WC system under high tribological loading | |
Chen, X.1; Ma, Y.2,3; Yang, Y.1; Meng, A.1; Han, Z. X.4; Han, Z.4; Zhao, Y. H.1 | |
Corresponding Author | Chen, X.(xiang.chen@njust.edu.cn) ; Ma, Y.(y.ma@mpie.de) ; Zhao, Y. H.(yhzhao@njust.edu.cn) |
2021-11-01 | |
Source Publication | SCRIPTA MATERIALIA
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ISSN | 1359-6462 |
Volume | 204Pages:5 |
Abstract | The near-surface structural and chemical changes were investigated for pure copper against a tungsten carbide (WC) sphere during high tribological loading. Fundamental stages are identified in the Cu-WC tribo-system: (i) high tribological stress promotes grain refinement to the ultra-fine grains regime in the very beginning; (ii) nucleation of extremely fine (similar to 3 nm) oxygen-enriched Cu nano particles in the nearsurface layer and subsequent growth of the Cu2O oxide; (iii) formation of continuous nanostructured mixing layer with heterogeneous Cu and O distribution in the late stage. Near-surface mechanical mixing is presumably the main contribution to chemical modifications under high tribological loading. Our findings shed atomic-insights into intricate tribochemical modifications, one of the most intriguing phenomena in material-oriented tribology. (C) 2021 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved. |
Keyword | Tribology Oxidation Transmission electron microscopy (TEM) Atom probe tomography Copper |
Funding Organization | National Natural Science Foundation of China ; Natural Science Foundation of Jiangsu Province , China ; Fundamental Research Funds for the Central Universities |
DOI | 10.1016/j.scriptamat.2021.114142 |
Indexed By | SCI |
Language | 英语 |
Funding Project | National Natural Science Foundation of China[52001165] ; National Natural Science Foundation of China[51931003] ; Natural Science Foundation of Jiangsu Province , China[BK20200475] ; Fundamental Research Funds for the Central Universities[30921011215] |
WOS Research Area | Science & Technology - Other Topics ; Materials Science ; Metallurgy & Metallurgical Engineering |
WOS Subject | Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering |
WOS ID | WOS:000690402200003 |
Publisher | PERGAMON-ELSEVIER SCIENCE LTD |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.imr.ac.cn/handle/321006/166866 |
Collection | 中国科学院金属研究所 |
Corresponding Author | Chen, X.; Ma, Y.; Zhao, Y. H. |
Affiliation | 1.Nanjing Univ Sci & Technol, Nano & Heterogeneous Mat Ctr, Sch Mat Sci & Engn, Nanjing 210094, Peoples R China 2.Rhein Westfal TH Aachen, Steel Inst IEHK, Intzestr 1, D-52072 Aachen, Germany 3.Max Planck Inst Eisenforsch GmbH MPIE, Max Planck Str 1, D-40237 Dusseldorf, Germany 4.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Peoples R China |
Recommended Citation GB/T 7714 | Chen, X.,Ma, Y.,Yang, Y.,et al. Revealing tribo-oxidation mechanisms of the copper-WC system under high tribological loading[J]. SCRIPTA MATERIALIA,2021,204:5. |
APA | Chen, X..,Ma, Y..,Yang, Y..,Meng, A..,Han, Z. X..,...&Zhao, Y. H..(2021).Revealing tribo-oxidation mechanisms of the copper-WC system under high tribological loading.SCRIPTA MATERIALIA,204,5. |
MLA | Chen, X.,et al."Revealing tribo-oxidation mechanisms of the copper-WC system under high tribological loading".SCRIPTA MATERIALIA 204(2021):5. |
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