Ultrafast Electrochemical Growth of Lithiophilic Nano-Flake Arrays for Stable Lithium Metal Anode

doi:10.1002/adfm.202103309

IMR OpenIR

	Ultrafast Electrochemical Growth of Lithiophilic Nano-Flake Arrays for Stable Lithium Metal Anode
	Shen, Haorui 1,2; Qi, Fulai 1,2; Li, Hucheng 1,2; Tang, Pei 1,2; Gao, Xuning 1,2; Yang, Shan 1,3; Hu, Zichen 1,2; Li, Zhuangnan 4; Tan, Jun 5; Bai, Shuo 1,2; Li, Feng 1,2,6
通讯作者	Tan, Jun(tanjun@jihualab.com) ; Bai, Shuo(sbai@imr.ac.cn) ; Li, Feng(fli@imr.ac.cn)
	2021-08-31
发表期刊	ADVANCED FUNCTIONAL MATERIALS
ISSN	1616-301X
页码	10
摘要	Lithium dendrites caused by nonuniform Li+ flux leads to the capacity fade and short-circuit hazard of lithium metal batteries. The solid electrolyte interface (SEI) is critical to the uniformity of Li+ flux. Here, an ultrafast preparation of uniform and vertical Cu7S4 nano-flake arrays (Cu7S4 NFAs) on the Cu substrate is reported. These arrays can largely improve the lithiophilicity of the anode and form Li2S-enriched SEI due to the electrochemical reduction of Cu7S4 NFAs with lithium. A further statistical analysis suggests that the SEI, with a higher content of Li2S, is more effective to inhibit the formation of lithium dendrites and yields less dead lithium. A quite stable coulombic efficiency of 98.6% can be maintained for 400 cycles at 1 mA cm(-2). Furthermore, at negative to positive electrode capacity ratio of 1.5 (N/P = 1.5), the full battery of Li@Cu7S4 NFAs\|\|S shows 83% capacity retention after 100 cycles at 1 C, much higher than that of Li@Cu\|\|S (33%). The findings demonstrate that high Li2S content in the SEI is crucial for the dendrite inhibition to achieve better electrochemical performance.
关键词	Cu S-7 (4) nano-flake arrays dead lithium Li S-2-enriched solid electrolyte interface lithium dendrites lithium metal anode
资助者	National Natural Science Foundation of China ; National Key R&D Program of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; LiaoNing Revitalization Talents Program ; DNL Cooperation Fund, CAS
DOI	10.1002/adfm.202103309
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[52020105010] ; National Natural Science Foundation of China[51927803] ; National Natural Science Foundation of China[51525206] ; National Key R&D Program of China[2016YFB0100100] ; National Key R&D Program of China[2016YFA0200100] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDA22010602] ; LiaoNing Revitalization Talents Program[XLYC1908015] ; DNL Cooperation Fund, CAS[DNL202019]
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
WOS类目	Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter
WOS记录号	WOS:000693308200001
出版者	WILEY-V C H VERLAG GMBH
引用统计	被引频次：26[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/166910
专题	中国科学院金属研究所
通讯作者	Tan, Jun; Bai, Shuo; Li, Feng
作者单位	1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 2.Univ Sci & Technol China, Sch Mat Sci & Engn, Hefei 230026, Peoples R China 3.Sichuan Univ, Sch Chem Engn, 24 South Sect 1,Yihuan Rd, Chengdu 610065, Peoples R China 4.Univ Cambridge, Dept Mat Sci & Met, Cambridge CB3 0FS, England 5.Ji Hua Lab, Foshan 528000, Guangdong, Peoples R China 6.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Shen, Haorui,Qi, Fulai,Li, Hucheng,et al. Ultrafast Electrochemical Growth of Lithiophilic Nano-Flake Arrays for Stable Lithium Metal Anode[J]. ADVANCED FUNCTIONAL MATERIALS,2021:10.
APA	Shen, Haorui.,Qi, Fulai.,Li, Hucheng.,Tang, Pei.,Gao, Xuning.,...&Li, Feng.(2021).Ultrafast Electrochemical Growth of Lithiophilic Nano-Flake Arrays for Stable Lithium Metal Anode.ADVANCED FUNCTIONAL MATERIALS,10.
MLA	Shen, Haorui,et al."Ultrafast Electrochemical Growth of Lithiophilic Nano-Flake Arrays for Stable Lithium Metal Anode".ADVANCED FUNCTIONAL MATERIALS (2021):10.