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Microstructure and Hydrogen Storage Characteristics of Rhodium Substituted Ti-V-Cr Alloys
Abdul, Jimoh Mohammed1,2,3,6; Kolawole, Sharafadeen Kunle4,6; Salawu, Ganiyat Abiodun5,6
通讯作者Abdul, Jimoh Mohammed(jmabdul@gmail.com)
2021-10-25
发表期刊JOM
ISSN1047-4838
页码7
摘要The effects of 0.05 at.% and 0.10 at.% Rh addition on the microstructure and hydrogen storage properties of Ti35V40Cr25 were investigated by x-ray diffraction (XRD) and pressure-composition-temperature (PCT) measurements. All three alloys exhibited a primary body-centered cubic (BCC) phase and a secondary Laves phase. Addition of rhodium enhanced both the hydrogen absorption and the useful hydrogen storage capacity. The absorption capacity was similar for both 0.05 at.% and 0.10 at.% Rh alloys but desorption was highest with 0.10 at.% Rh addition. The plateau pressure was significantly reduced with addition of 0.05 at.% Rh, but only marginal reduction was observed with 0.10 at.% Rh. Both the enthalpy and entropy of hydride formation increased with the addition of rhodium.
资助者African Materials Science and Engineering Network (AMSEN) ; National Research Foundation (NRF) Thuthuka Programme
DOI10.1007/s11837-021-04952-z
收录类别SCI
语种英语
资助项目African Materials Science and Engineering Network (AMSEN) ; National Research Foundation (NRF) Thuthuka Programme
WOS研究方向Materials Science ; Metallurgy & Metallurgical Engineering ; Mineralogy ; Mining & Mineral Processing
WOS类目Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering ; Mineralogy ; Mining & Mineral Processing
WOS记录号WOS:000710887400002
出版者SPRINGER
引用统计
被引频次:4[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/167083
专题中国科学院金属研究所
通讯作者Abdul, Jimoh Mohammed
作者单位1.Univ Witwatersrand, Sch Chem & Met Engn, Private Bag 3, ZA-2050 Johannesburg, Wits, South Africa
2.Univ Witwatersrand, African Mat Sci & Engn Network AMSEN, Private Bag 3, ZA-2050 Johannesburg, Wits, South Africa
3.Univ Witwatersrand, Mat Energy Res Grp MERG, Private Bag 3, ZA-2050 Johannesburg, Wits, South Africa
4.Chinese Acad Sci, Shi Changxu Innovat Ctr Adv Mat, Inst Met Res, Shenyang 110016, Peoples R China
5.Univ Kwazu Lu Natal, Mech Engn Dept, Durban, South Africa
6.Fed Polytech, PMB 420, Offa, Kwara State, Nigeria
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Abdul, Jimoh Mohammed,Kolawole, Sharafadeen Kunle,Salawu, Ganiyat Abiodun. Microstructure and Hydrogen Storage Characteristics of Rhodium Substituted Ti-V-Cr Alloys[J]. JOM,2021:7.
APA Abdul, Jimoh Mohammed,Kolawole, Sharafadeen Kunle,&Salawu, Ganiyat Abiodun.(2021).Microstructure and Hydrogen Storage Characteristics of Rhodium Substituted Ti-V-Cr Alloys.JOM,7.
MLA Abdul, Jimoh Mohammed,et al."Microstructure and Hydrogen Storage Characteristics of Rhodium Substituted Ti-V-Cr Alloys".JOM (2021):7.
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