Nitrogen-Doped Graphene Monolith Catalysts for Oxidative Dehydrogenation of Propane

doi:10.3389/fchem.2021.759936

IMR OpenIR

	Nitrogen-Doped Graphene Monolith Catalysts for Oxidative Dehydrogenation of Propane
	Liu, Weijie 1,2; Cao, Tianlong 1; Dai, Xueya 1,2; Bai, Yunli 1,2; Lu, Xingyu 1,2; Li, Fan 1,2; Qi, Wei 1,2
通讯作者	Qi, Wei(wqi@imr.ac.cn)
	2021-10-15
发表期刊	FRONTIERS IN CHEMISTRY
ISSN	2296-2646
卷号	9 页码:9
摘要	It's of paramount importance to develop renewable nanocarbon materials to replace conventional precious metal catalysts in alkane dehydrogenation reactions. Graphene-based materials with high surface area have great potential for light alkane dehydrogenation. However, the powder-like state of the graphene-based materials seriously limits their potential industrial applications. In the present work, a new synthetic route is designed to fabricate nitrogen-doped graphene-based monolith catalysts for oxidative dehydrogenation of propane. The synthetic strategy combines the hydrothermal-aerogel and the post thermo-treatment procedures with urea and graphene as precursors. The structural characterization and kinetic analysis show that the monolithic catalyst well maintains the structural advantages of graphene with relatively high surface area and excellent thermal stability. The homogeneous distributed nitrogen species can effectively improve the yield of propylene (5.3% vs. 1.9%) and lower the activation energy (62.6 kJ mol(-1) vs. 80.1 kJ mol(-1)) in oxidative dehydrogenation of propane reaction comparing with un-doped graphene monolith. An optimized doping amount at 1:1 weight content of the graphene to urea precursors could exhibit the best catalytic performance. The present work paves the way for developing novel and efficient nitrogen-doped graphene monolithic catalysts for oxidative dehydrogenation reactions of propane.
关键词	nitrogen doping graphene monolith oxidative dehydrogenation of propane nanocarbon materials kinetic analysis
资助者	NSFC of China ; Natural Science Foundation of Liaoning Province of China
DOI	10.3389/fchem.2021.759936
收录类别	SCI
语种	英语
资助项目	NSFC of China[22072163] ; NSFC of China[21761132010] ; NSFC of China[91645114] ; Natural Science Foundation of Liaoning Province of China[2020-YQ-02] ; Natural Science Foundation of Liaoning Province of China[2019-MS-296]
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000726372500001
出版者	FRONTIERS MEDIA SA
引用统计	被引频次：5[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/167584
专题	中国科学院金属研究所
通讯作者	Qi, Wei
作者单位	1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang, Peoples R China 2.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang, Peoples R China
推荐引用方式 GB/T 7714	Liu, Weijie,Cao, Tianlong,Dai, Xueya,et al. Nitrogen-Doped Graphene Monolith Catalysts for Oxidative Dehydrogenation of Propane[J]. FRONTIERS IN CHEMISTRY,2021,9:9.
APA	Liu, Weijie.,Cao, Tianlong.,Dai, Xueya.,Bai, Yunli.,Lu, Xingyu.,...&Qi, Wei.(2021).Nitrogen-Doped Graphene Monolith Catalysts for Oxidative Dehydrogenation of Propane.FRONTIERS IN CHEMISTRY,9,9.
MLA	Liu, Weijie,et al."Nitrogen-Doped Graphene Monolith Catalysts for Oxidative Dehydrogenation of Propane".FRONTIERS IN CHEMISTRY 9(2021):9.