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近快速凝固制备高硅含量铝硅复合材料及其性能研究
其他题名Si-Al Alloy fabricated by Quasi-rapid Solidification and Its Properties
孟瑞林
学位类型硕士
导师王亚平
2007-02-04
学位授予单位中国科学院金属研究所
学位授予地点金属研究所
学位专业材料学
关键词近快速凝固 高硅铝复合材料 自生复合材料 冷却速率 封装
摘要摘 要 随着微电子技术及半导体技术的发展,越来越高的封装密度对封装材料提出了更高的要求。以硅颗粒增强铝基复合材料为代表的新兴封装材料具有高导热、低膨胀、低密度等优异的综合性能,在电子封装领域具有广阔的应用前景。研究铝硅电子封装材料的制备方法具有重要的理论意义和应用价值。 由液相直接凝固得到的不添加变质剂的铝硅复合材料作为一种自生复合材料,具有界面清洁,第二相与基体相容性好等优点。所以研究硅含量超过50%的高硅铝合金在不同冷却条件下的初生硅的形貌和尺寸,探索影响初生硅尺寸的因素,进而细化自生初生硅相,将会给高硅铝复合材料的制造工艺提供新的思路。 本文主要研究了硅含量和冷却速率对铝硅复合材料凝固组织的影响,结果表明硅含量对铝硅复合材料凝固组织当中初生硅的形貌基本无影响而主要影响初生硅的尺寸,硅含量越高,初生硅尺寸越大。冷却速率将同时影响凝固组织当中初生硅的形貌和尺寸。冷却速率越高,初生硅的尺寸越小;随着冷却速率的提高,初生硅的生长机制发生变化,由粗大针状逐步转变为针状、多角块状。此临界转变冷速发生在10 K/s至103 K/s冷速区间之内。 对所制备的铝硅自生复合材料进行了热变形、热膨胀、焊接、加工性能的测试。Al-50%Si自生复合材料的热膨胀系数为8.40×10-6/ K,与Si、GaAs很匹配。
其他摘要Abstract The development in electronics and semiconductors industry requires better packaging materials. Among the candidates is silicon particle reinforced Al-base composite material, which has high thermal conductivity, low thermal expansion and relatively low density. It is of great value both theoretically and commercially to investigate into this composite The solidified Al-Si composite is an in-situ composite. It is valuable to study the microstructure of primary Si phase solidified under different cooling conditions for better understanding and control of the primary Si phase in the composite. The microstructure of Al-50%Si, Al-60%Si and Al-70%Si (weight percent) composites solidified under different cooling rates were studied to investigate the influence of Si content and the cooling rate on the size and shape of primary Si. It was found that the Si content controls only the size of the primary Si in the composite. The size of primary Si phase increases with the adding of Si content in the composite. While the cooling rate controls both the size and the shape of the Si phase. With the increase of the cooing rate, the primary Si in the composite changes from huge acicular (under 10K/s) to refined acicular(under 20K/s) and even equiaxed fine grains(under 106K/s).There is a critical cooling rate between 10-103K/s at which the shape of the Si changes suddenly. A new fabrication method of Al-Si composite containing high silicon was indicated in this research. The composite was prepared by quasi-rapid solidification progress in vacuum. Microstructures and properties were studied and the results showed that the particle size of the primary Si could be refined to 10 μm ~30 μm, and the CTE of the Al-50%Si composite is 8.40×10-6/ K.
页数56
语种中文
文献类型学位论文
条目标识符http://ir.imr.ac.cn/handle/321006/16975
专题中国科学院金属研究所
推荐引用方式
GB/T 7714
孟瑞林. 近快速凝固制备高硅含量铝硅复合材料及其性能研究[D]. 金属研究所. 中国科学院金属研究所,2007.
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