IMR OpenIR
HVOF喷涂WC-Co-Cr涂层的砂浆冲蚀行为研究
其他题名Study on Slurry Erosion Behavior of HVOF Sprayed WC-Co-Cr Coatings
张光华
学位类型硕士
导师李曙
2007-06-04
学位授予单位中国科学院金属研究所
学位授予地点金属研究所
学位专业材料学
关键词Hvof Wc-co-cr涂层 砂浆冲蚀 攻角 片状剥落
摘要HVOF喷涂碳化钨-金属涂层由于WC较高的沉积效率,所制备的涂层致密性好,与基体结合强度高,同时结合了WC颗粒的高硬度和金属粘结相的高韧性两方面的优势而具有优越的耐冲蚀性能,被用于水轮机过流部件的表面防护。水轮机过流部件在实际的使用过程中受到不同浓度、速度和攻角的含沙水流的冲蚀而产生严重的材料流失问题,因此研究此类复合涂层在服役工况下的砂浆冲蚀行为,了解其冲蚀机制和耐冲蚀规律,对于开发新型耐冲蚀防护涂层和确定使用条件,均具有非常重要的指导意义和应用价值。 本文介绍自行设计和研制的料浆罐砂浆冲蚀设备和射流式砂浆冲蚀设备,两台设备都可以方便地实现对砂浆浓度、冲击速度和攻角的调节。在料浆罐砂浆冲蚀设备中设置了水冷却系统,以保证实验能在较低的恒温下进行; 在料浆罐中加入挡板使实验条件更接近水轮机叶片运行工况。射流式砂浆冲蚀设备能够准确控制作用于样品表面的砂浆浓度、冲击速度和攻角等实验参数。 在自行研制的料浆罐砂浆冲蚀设备上对三种HVOF喷涂系统制备的九种WC-Co-Cr涂层进行砂浆冲蚀行为的研究,并以水轮机过流部件常用材料—0Cr13Ni5Mo马氏体不锈钢作为对比材料。实验用冲蚀粒子为粒度210µm-420µm的多角形石英砂,砂浆浓度为20wt.%,样品运动线速度6m/s,砂浆名义攻角分别为15°、45°、75°、90°,冲蚀时间选择12h、24h、36h。 实验结果表明:九种HVOF喷涂WC-Co-Cr涂层在各实验条件下的冲蚀失重均远小于0Cr13Ni5Mo不锈钢;并且冲蚀失重随攻角的变化幅度明显减小, WC颗粒与Co-Cr粘结相结合较好且无分层和层间裂纹的涂层,其冲蚀失重对攻角尤为不敏感,是一类较理想的表面耐冲蚀防护涂层,对于提高水轮机过流部件的使用寿命具有重要意义。 用SEM观测涂层冲蚀后的表面形貌,分析了HVOF喷涂WC-Co-Cr涂层的冲蚀机制。结果表明,涂层冲蚀失重主要来自片状剥落,片状剥落的程度与涂层气孔率之间存在密切的关系,高气孔率的涂层片状剥落更严重。
其他摘要Due to the high deposition efficiency of WC, HVOF sprayed WC-M coating has a dense microstructure and high adhesive strength with the substrate, it also combines the high hardness of WC particles and high toughness of metal binder, which lead to excellent erosion resistance, and was used to prevent the surfaces damage of flow parts of water turbine from severe erosion by slurry with different sand concentrations, impact velocity and impact angle. So it is important and constructive for the development of new erosion resistant coating and the confirmation of its application environment to investigate the slurry erosion resistance and erosion mechanism of this composite coating used in practice. In this paper, a slurry pot erosion equipment and a slurry jet erosion equipment were designed and developed, both of which can conveniently change the sand concentration, impact velocity and impact angle. A water cooling system was installed in the slurry pot erosion equipment to ensure the low constant temperature of experimental environment; and baffle plates were added in the slurry pot to make the experimental conditions be more close to the work environment of water turbine blade. The slurry jet erosion equipment could accurately control the experimental condition of the slurry jet impact such as sand concentration, impact velocity and impact angle. The slurry erosion behavior of nine WC-Co-Cr coatings sprayed by three different HVOF spray systems was studied on the self-manufactured slurry pot erosion equipment, with martensitic stainless steel 0Cr13Ni5Mo, which is always used to produce flow parts of water turbine, as the parallel sample. Erodent used in this paper was 210µm-420µm angular quartz sand, with sand concentration of 20wt.%, nominal impact angle of 15°, 45°, 75°, 90°; the rotary speed of sample was 6m/s and the erosion time of 12h, 24h, 36h was chosen.The experimental results indicated that, the erosion mass loss of nine HVOF sprayed WC-Co-Cr coatings under every experimental condition was far less than 0Cr13Ni5Mo stainless steel; the amplitude of variation of the erosion mass loss of the coating with impact angle was much smaller, and the erosion mass loss of the coating, which had fine combination of WC particles and Co-Cr binder and no splat boundaries and cracks, was insensitive to impact angle. So the HVOF sprayed WC-Co-Cr coating is an ideal erosion resistant protective coating for improving the service life of flow parts of water turbine. The erosion mechanism of HVOF sprayed WC-Co-Cr coating was analyzed by observing the surface SEM morphology of the coating after erosion. The results indicated that, the erosion mass loss of coating mostly came from detachment of splats. The extent of detachment of splats had a close relation with coating porosity, that the coating with high porosity was more severe.
页数82
语种中文
文献类型学位论文
条目标识符http://ir.imr.ac.cn/handle/321006/17097
专题中国科学院金属研究所
推荐引用方式
GB/T 7714
张光华. HVOF喷涂WC-Co-Cr涂层的砂浆冲蚀行为研究[D]. 金属研究所. 中国科学院金属研究所,2007.
条目包含的文件
条目无相关文件。
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[张光华]的文章
百度学术
百度学术中相似的文章
[张光华]的文章
必应学术
必应学术中相似的文章
[张光华]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。