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镍基单晶高温合金的残余应力衍射测试与分析
其他题名Measurement and Analysis of Residual Stress in Ni-base Single Crystal Superalloy
张俊
学位类型硕士
导师吴二冬
2007-09-24
学位授予单位中国科学院金属研究所
学位授予地点金属研究所
学位专业材料物理与化学
关键词镍基单晶高温合金 残余应力 X射线衍射 中子衍射 喷丸 热机械疲劳
摘要在镍基单晶高温合金叶片的生产和服役过程中,存在大量因素引入残余应力,其与外载应力叠加作用将对材料的组织与性能产生重要影响。目前,对单晶高温合金中残余应力大部分都是通过有限元数值模拟和汇聚束电子衍射进行研究,而在多晶材料中被广泛应用的X射线衍射(XRD)和中子衍射方法却未被广泛应用,本文通过XRD和中子衍射对镍基单晶高温合金中的残余应力进行测试和研究。 首先,通过四点弯曲法验证针对含有γ/γ'两相的镍基单晶高温合金的XRD应力测试方法的可靠性。通过XRD对去应力退火的校正试样表层的残余应力重复测定,推断XRD法测定单晶高温合金应力的精度为±30MPa,符合测量单晶高温合金应力要求。在室温状态下,发现四点弯曲法弹性加载条件下合金表层的宏观应力应变与机械拉伸实验测定的应力及应变片法测定的加载应变数据吻合较好,证明利用XRD测试含有γ/γ'两相的单晶高温合金的应力方法可行和数据可靠;同时也发现沿加载方向上相间应力结果为:γ相受拉,γ'相受压;相间应力随着加载量增加而增加。 其次,针对叶片在制造过程中可能引入残余应力,利用XRD测定不同取向(A-(100),B-(110),C-(111))喷丸样品的残余应力分布,通过观察高温时效后材料组织变化研究残余应力对材料组织结构的影响。发现在喷丸试样中与试样表面平行的应力分量为压应力,并逐渐减小,在一定深度时转变成拉应力;而与试样表面垂直的应力分量为拉应力并在变形层内保持一致,塑性变形量也沿着层深逐渐减小。材料本身的力学性质对应力分布影响较大,A、B、C样品在相同喷丸处理条件下,其应力状态分布为 ,与屈服强度相对应。喷丸试样在时效处理过程中表面发生了再结晶和“异常”筏化组织变化,认为“异常”筏化与应力热松弛一致,是一种扩散过程,“异常”筏化主要原因是喷丸变形引起的三维残余应力状态,与试样表面平行的压应力相互“抵消”不起作用,与表面垂直的拉应力分量在时效过程中对筏化起主要作用。 最后,针对叶片在服役过程中引入的残余应力,利用同相位热机械疲劳(TMF)对沿[001]方向生长的单晶高温合金进行模拟,并分别利用XRD和中子衍射方法测定TMF变形后试样内的应力状态。结果表明试样内部γ/γ'两相的残余内应力状态为:γ(γ')相在[001]方向受压(拉),而在[010]/[100]方向则受拉(压);同一试样的不同位置的塑性变形是不均匀的,试样中心位置的γ/γ'两相应力值要大于其他部位,且中心位置的γ/γ'两相的点阵常数变化程度也同样大于其他部位,所以中心位置的变形程度最大。利用XRD分别测量样品{400}衍射峰得试样中γ/γ'两相发生了不同程度的四方畸变:γ相,c-b为;γ'相,c-b为正;其绝对值随着变形程度的增加而增加;试样在[001]方向和[010]/[100]方向的点阵错配度不同,在[001]方向为正,约为+0.05%,而在[100]/[010]方向则为负,约为-0.25%。
其他摘要There are many possibilities to induce residual stress in Ni-base single crystal superalloy during the manufacture and service procedures. The residual stress combined with the applied stress will affect the microstructure and mechanical performance significantly. Finite Element Method and Convergent Beam Electronic Diffraction have been extensively used to study the stress state in Ni-base single crystal superalloy, but X-ray diffraction (XRD) method and neutron diffraction which have been used wildly for the stress measurement in polycrystal haven’t been applied wildly. The aim of this work is to study the residual stress in Ni-base single-crystal superalloy by XRD and neutron diffraction. First, XRD method for the stress measurement in single-crystal superalloy was examined by the four-point bending tests. Experiment errors from the repeated measurements for the same stress-free sample was about ±30MPa and this proved XRD method was suitable for the stress measurement in this experiment. Stress states of the superalloy during four-point bending tests were measured by XRD at room temperature. The results from the calculation by separated information of γ/γ' phase showed that the measurement technology and analysis method were correct. The inter-phase stress states of γ/γ' phases during the tests increased with the deformation while the γ (γ') phase was in tension (compression). Second, samples with different surface direction (A-(100), B-(110), and C-(111)) were shot peened to simulate the residual stress state introduced during the manufacture process and shot peened samples were aged to observe the different microstructures. The experiment results showed that the stress tensors parallel to the sample surface was compressive stress and decreased with the depth; it changed to tensile in interior and balanced with the compressive stress in the sub-surface. The stress tenor along the depth within the deformed layer was tensile. The mechanical performances of the material play an important role in the stress state of shot peened samples. The stress distribution state is while the corresponding yield strength is . Recrystallization and “anomalous” rafting structure were observed in the shot peened sample after ageing heat treatment. Rafting was supposed to be a result of the diffusion process which was consistent of the thermal relaxation of the residual stress. The tensile stress tensor along the depth was supposed to be the critical reason for the rafting structure while the stress tensors parallel to the surface were countervailed. Third, in-phase thermal-mechanical fatigue (IP TMF) was performed to simulate the service condition. The TMF samples were measured by XRD and neutron diffraction. Experiment results showed that the stress state of γ/γ' phase within the sample was: γ (γ') along the [001] direction was compressive (tensile) and opposite along the [100]/[010] direction. The stress states in the deformed sample were inhomogeneous, as the stress and the changes of the lattice parameter in the center was larger than the other position. The results from the {400} profiles indicated the γ/γ' phases were tetragonal distorted, c-b for γ (γ') phase was negative (positive) and increased with the deformation process; the lattice parameter mismatch in axial (side) case was positive (negative) with the corresponding value of +0.05% (-0.25%).
页数81
语种中文
文献类型学位论文
条目标识符http://ir.imr.ac.cn/handle/321006/17100
专题中国科学院金属研究所
推荐引用方式
GB/T 7714
张俊. 镍基单晶高温合金的残余应力衍射测试与分析[D]. 金属研究所. 中国科学院金属研究所,2007.
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