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铸造Mg-Zn-Y-Zr合金的组织性能、糊状区特性及热裂敏感性
其他题名Microstructure,Mechanical Properties,Characteristics of Mushy Zone and Hot Tearing Susceptibility of Cast Mg-Zn-Y-Zr Alloys
黄张洪
学位类型博士
导师韩恩厚
2009-05-30
学位授予单位中国科学院金属研究所
学位授予地点金属研究所
学位专业材料学
关键词Mg-zn-y-zr合金 显微组织 力学性能 热分析 糊状区 热裂
摘要近年来,镁合金在航空航天、汽车和3C工业日益获得越来越广泛的应用。Mg-Zn-Y-Zr系(ZW系)镁合金是近几年开发的一种新型高强度耐热镁合金。已有的半连续铸造成形实验表明,一些Mg-Zn-Y-Zr合金具有强烈的热裂倾向,难以制备大尺寸铸锭。合金的热裂敏感性与其糊状区的组织和力学特性等密切相关。为理解ZW系镁合金铸造过程中热裂的形成机理,发展兼具优良铸造成形性能和力学性能的新型Mg-Zn-Y系合金,本文系统研究了Mg-Zn-Y三元系富镁角的合金的化学成分、组织和相组成、力学性能之间的关系;表征了该合金系成分、糊状区组织、强度特性、热裂敏感性之间的关系。 组织分析和热分析冷却曲线研究发现,在富镁角(2.00~6.36wt.%Zn,1.03~6.96wt.%Y的成分范围内),Mg-Zn-Y-Zr合金的组织、力学性能及凝固路径不仅取决于合金中化学元素的含量,还取决于Zn/Y比(质量比,下同),因此将合金定性分成五个相区。处于各个相区的合金的相组成及凝固路径中除涉及α-Mg相外,其金属间化合物相的种类及其形成路径各不相同:相区(Ⅰ),低Zn、高Y含量,0.35
其他摘要The development and application of magnesium alloys have been used more and more widely recent years, and great achievement has been already made in aerospace, automobile and 3C industry. Mg-Zn-Y-Zr alloys (ZW series alloys) are newly developed high strength heat-resistant magnesium alloys. Commercial DC casting results show that some ZW alloys are prone to hot tearing and it is nearly impossible to gain heavy gauge ingot. Since hot tearing is related to the microstructures, mechanical properties in the mushy zone. To understand the mechanism of hot tearing of ZW series alloys, and develop newly Mg-Zn-Y series alloys with good casting and mechanical properties, in this dissertation, investigation of relation among chemical composition, microstructure and phase, mechanical properties of mg-rich corner ZW alloys have been systematically studied. Relation among chemical composition, microstructure in mushy zone, characteristics of strength, hot tearing susceptibility is then characterized. By microstructure observation and thermal analysis cooling curve research, it is found that microstructure, mechanical properties and solidification pathways depend not only on the chemical composition but Zn/Y ratio(Mass ratio) in Mg-Zn-Y-Zr alloys in mg-rich corner, Zn content between 2.00~6.36wt.%, Y content between 1.03~6.96wt. % and these alloys can be qualitatively divided into five phase areas. Alloys in different phase areas have different phase constitutes, solidification pathways except for α-Mg: No.1 phase area(Ⅰ), with low Zn and high Y content, 0.35
页数138
语种中文
文献类型学位论文
条目标识符http://ir.imr.ac.cn/handle/321006/17131
专题中国科学院金属研究所
推荐引用方式
GB/T 7714
黄张洪. 铸造Mg-Zn-Y-Zr合金的组织性能、糊状区特性及热裂敏感性[D]. 金属研究所. 中国科学院金属研究所,2009.
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