Catalytic polysulfide conversion in lithium-sulfur batteries by platinum nanoparticles supported on carbonized microspheres

doi:10.1016/j.cej.2022.135112

IMR OpenIR

	Catalytic polysulfide conversion in lithium-sulfur batteries by platinum nanoparticles supported on carbonized microspheres
	Qi, Yujie 1,2; Chai, Ning 1,3; Gu, Qinhua 1,2; Chen, Junnan 1,2; Lu, Ming 1,4; Zhang, Xia 3; Zhang, Bingsen 1,2
通讯作者	Zhang, Xia(xzhang@mail.neu.edu.cn) ; Zhang, Bingsen(bszhang@imr.ac.cn)
	2022-05-01
发表期刊	CHEMICAL ENGINEERING JOURNAL
ISSN	1385-8947
卷号	435 页码:11
摘要	Lithium-Sulfur (Li-S) battery has attracted extensive attentions in the field of energy storage due to its high theoretical specific capacity and low cost. However, the shuttle effect restricts its energy density and cycle performance, that hinders the industrialization process of Li-S battery. The introduction of catalysis in conversion of lithium polysulfides (LiPSs) is an effective strategy to suppress shuttle effect. Metal nanoparticles (NPs) are attractive catalysts due to excellent electrical conductivity and rapid electron transfer efficiency, therefore, metal NPs have great potential to be introduced in Li-S battery for studying and revealing elementary conversion reactions of LiPSs. Herein, based on the strategy of accelerating conversion of LiPSs integrated with physical confinement, we designed and synthesized Pt NPs supported on carbonized microspheres (Pt/CS composites). The catalytic conversion of LiPSs from charge transfer between Pt NPs and carbon matrix, combined with the strong physical confinement by surface pores of CS, result in upgraded electrochemical properties. It is demonstrated that the resulting Pt/CS cathode exhibits improved rate performance with specific capacity of 991.9 mAh g-1 at 0.1C, and maintains a fine cycling stability. This work provides a rational and facile route to construct metal supported catalytic electrode materials for Li-S battery.
关键词	Lithium-sulfur batteries Platinum nanoparticles Carbonized microspheres Catalysis Polysulfide conversion
资助者	National Natural Science Foundation of China ; Liaoning Revitalization Talents Program ; Research Fund of Shenyang National Laboratory for Materials Science, Natural Science Foundation of Jilin Province ; Science and Technology Research Project of Education Department of Jilin Province
DOI	10.1016/j.cej.2022.135112
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[51932005] ; National Natural Science Foundation of China[52161145403] ; National Natural Science Foundation of China[22072164] ; Liaoning Revitalization Talents Program[XLYC1807175] ; Research Fund of Shenyang National Laboratory for Materials Science, Natural Science Foundation of Jilin Province[20210101117JC] ; Science and Technology Research Project of Education Department of Jilin Province[JJKH20210453KJ] ; Science and Technology Research Project of Education Department of Jilin Province[JKH20210449KJ]
WOS研究方向	Engineering
WOS类目	Engineering, Environmental ; Engineering, Chemical
WOS记录号	WOS:000787114100001
出版者	ELSEVIER SCIENCE SA
引用统计	被引频次：16[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/172561
专题	中国科学院金属研究所
通讯作者	Zhang, Xia; Zhang, Bingsen
作者单位	1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 2.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China 3.Northeastern Univ, Coll Sci, Dept Chem, Shenyang 110819, Peoples R China 4.Jilin Normal Univ, Joint Lab MXene Mat, Key Lab Preparat & Applicat Environm Friendly Mat, Key Lab Funct Mat Phys & Chem,Minist Educ, Changchun 130103, Peoples R China
推荐引用方式 GB/T 7714	Qi, Yujie,Chai, Ning,Gu, Qinhua,et al. Catalytic polysulfide conversion in lithium-sulfur batteries by platinum nanoparticles supported on carbonized microspheres[J]. CHEMICAL ENGINEERING JOURNAL,2022,435:11.
APA	Qi, Yujie.,Chai, Ning.,Gu, Qinhua.,Chen, Junnan.,Lu, Ming.,...&Zhang, Bingsen.(2022).Catalytic polysulfide conversion in lithium-sulfur batteries by platinum nanoparticles supported on carbonized microspheres.CHEMICAL ENGINEERING JOURNAL,435,11.
MLA	Qi, Yujie,et al."Catalytic polysulfide conversion in lithium-sulfur batteries by platinum nanoparticles supported on carbonized microspheres".CHEMICAL ENGINEERING JOURNAL 435(2022):11.