Oxidation of 2,5-bis(hydroxymethyl)furan to 2,5-furandicarboxylic acid catalyzed by carbon nanotube-supported Pd catalysts

doi:10.1016/S1872-2067(21)63878-0

IMR OpenIR

	Oxidation of 2,5-bis(hydroxymethyl)furan to 2,5-furandicarboxylic acid catalyzed by carbon nanotube-supported Pd catalysts
	Li, Zhenyu 1; Huai, Liyuan 1; Hao, Panpan 1; Zhao, Xi 1; Wang, Yongzhao 2; Zhang, Bingsen 2; Chen, Chunlin 1; Zhang, Jian 1
通讯作者	Hao, Panpan(haopanpan@nimte.ac.cn) ; Zhang, Jian(jzhang@nimte.ac.cn)
	2022-03-01
发表期刊	CHINESE JOURNAL OF CATALYSIS
ISSN	0253-9837
卷号	43 期号:3 页码:793-801
摘要	The selective oxidation of 2,5-bis(hydroxymethyl)furan (BHMF) in this work was proven as a promising route to produce 2,5-furandicarboxylic acid (FDCA), an emerging bio-based building-block with wide application. Under ambient pressure, the modified carbon nanotube-supported Pd-based catalysts demonstrate the maximum FDCA yield of 93.0% with a full conversion of BHMF after 60 min at 60 degrees C, much superior to that of the traditional route using 5-hydroxymethylfurfural (HMF) as substrates (only a yield of 35.7%). The participation of PdHx active species with metallic Pd can be responsible for the encouraging performance. Meanwhile, a possible reaction pathway proceeding through 2,5-diformylfuran (DFF) and 5-formyl-2-furancarboxylic acid (FFCA) as process intermediates is suggested for BHMF route. The present work may provide new opportunities to synthesize other high value-added oxygenates by using BHMF as an alternative feedstock. (C) 2022, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
关键词	2,5-Bis(hydroxymethyl)furan 2,5-Furandicarboxylic acid Palladium hydride 5-Hydroxymethylfurfural Catalytic oxidation
资助者	National Natural Science Foundation of China ; Chinese Academy of Sciences ; Ningbo Science and Technology Bureau
DOI	10.1016/S1872-2067(21)63878-0
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[22072170] ; Chinese Academy of Sciences[QYZDB-SSW-JSC037] ; Ningbo Science and Technology Bureau[2018B10056] ; Ningbo Science and Technology Bureau[2019B10096]
WOS研究方向	Chemistry ; Engineering
WOS类目	Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
WOS记录号	WOS:000788414700008
出版者	ELSEVIER
引用统计	被引频次：4[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/172612
专题	中国科学院金属研究所
通讯作者	Hao, Panpan; Zhang, Jian
作者单位	1.Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Zhejiang, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China
推荐引用方式 GB/T 7714	Li, Zhenyu,Huai, Liyuan,Hao, Panpan,et al. Oxidation of 2,5-bis(hydroxymethyl)furan to 2,5-furandicarboxylic acid catalyzed by carbon nanotube-supported Pd catalysts[J]. CHINESE JOURNAL OF CATALYSIS,2022,43(3):793-801.
APA	Li, Zhenyu.,Huai, Liyuan.,Hao, Panpan.,Zhao, Xi.,Wang, Yongzhao.,...&Zhang, Jian.(2022).Oxidation of 2,5-bis(hydroxymethyl)furan to 2,5-furandicarboxylic acid catalyzed by carbon nanotube-supported Pd catalysts.CHINESE JOURNAL OF CATALYSIS,43(3),793-801.
MLA	Li, Zhenyu,et al."Oxidation of 2,5-bis(hydroxymethyl)furan to 2,5-furandicarboxylic acid catalyzed by carbon nanotube-supported Pd catalysts".CHINESE JOURNAL OF CATALYSIS 43.3(2022):793-801.