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Ti-Al基合金洁净粉末的表征及挤压材组织和性能研究
其他题名Study on characterizations of high purity TiAl alloy powder and organizations, performances of extruded TiAl alloy powder
徐强
学位类型硕士
导师杨锐
2009-05-29
学位授予单位中国科学院金属研究所
学位授予地点金属研究所
学位专业材料学
关键词Γ-tial合金 O相合金 挤压 性能
摘要TiAl基合金密度低、比强度和比模量高,具有较好的抗氧化性和持久性能,在航空航天和汽车等领域具有广阔的应用前景。TiAl基合金作为一种新型轻质高温结构材料,近年来受到国内外研究者的普遍关注。目前制约TiAl基合金应用的主要因素是较低的室温塑性和断裂韧性,发展具有良好综合性能的均匀细小组织,发掘TiAl基合金最大潜力成为TiAl基合金研究的热点之一。通过高温挤压可以制备出具有优异性能的变形TiAl基合金材料,然而因TiAl合金铸锭易产生成分偏析,因此挤压难以形成细小均匀的微观组织。本文采用洁净制粉工艺制备了Ti-Al基合金粉末,热等静压制坯之后进行高温挤压,期望得到细小均匀并具备较优良性能的Ti-Al基合金组织。 本文采用无坩埚感应熔炼气体雾化法制备了洁净的O相预合金粉末和洁净的γ-TiAl合金粉末,对应不同的热等静压制度进行了热等静压,O相合金热等静压制度为1000℃/130MPa/4h,γ-TiAl合金热等静压制度为1100℃/130MPa/4h,均得到了细小均匀的等轴晶组织,但O相压坯组织仍有部分粉末边界存留,而γ-TiAl合金压坯组织的粉末边界完全消失,有利于进一步的热挤压工艺处理。 对γ-TiAl合金热等静压后的压坯在1300℃温度下进行热挤压,得到与铸态挤压件组织相比更加均匀细小的组织,减少了偏析,可期待得到好的力学性能。对挤压件样品进行1340℃/10min/FC固溶处理,然后在900℃/8h进行稳定化处理,取拉伸试样进行拉伸力学实验,得到了较好的力学性能,但力学性能差于铸态挤压件,这是由于粉末之间的结合效果不够理想,在拉伸过程中,裂纹源会较容易出现在粉末之间结合的界面上,从而产生使试样断裂的裂纹,对力学性能造成了一定的影响。改进粉末封装和真空除气工艺,使粉末之间结合更加紧密,以提高挤压件的力学性能。
其他摘要TiAl alloys are a new lightweight high temperature structural materials and have a broad application in aerospace, automotive and other fields for their low density, high specific strength, high modulus, good resistance to oxidation and excellent fatigue properties. In recent years, TiAl alloys are attracting world-wide attention and much work has been done. The major factors of restrain TiAl alloys to use are the lower room temperature ductility and fracture toughness, development of good performance of fine homogeneous organizations to explore the largest potential is to be the focus of TiAl alloys investigation. TiAl alloy materials with good performance can be made through hot extrusion, but there are component segregations in cast ingots, and fine homogeneous organizations can’t be obtained during extrusion processing. In this study, TiAl alloys are treated through powder metallurgy and hot extrusion to obtain fine homogeneous organizations with a view to be an excellent performance. High purity pre-alloyed O-phase powders and γ-TiAl powders have been produced by Electrode Induction Melting Gas Atomization (EIGA) method. O-phase powders have been HIPped under the condition of 1000℃/130MPa/4h, and fine homogeneous equiaxed grain organizations are obtained, but some powder boundary still exists. γ-TiAl powders have been HIPped under the condition of 1100℃/130MPa/4h, and fine homogeneous equiaxed grain organizations are obtained with no powder boundary, which have good hot-working ability. As HIP-compacted γ-TiAl alloy has been extruded under the condition of 1300℃, compared with extruded cast organizations, the organizations obtained are finer and more homogeneous, which have less component segregations, and it can be expected to have an excellent performance. After heat treatment under the conditions of 1340℃/10min/FC and 900℃/8h, the extruded γ-TiAl alloy has been tested for tensile performances. The tested tensile performances is good but worse than the performances of extruded cast γ-TiAl alloy. The reason is that the combining effect between powders is not good enough, during the tensile test, the crack resources can easily appear on the boundaries of combined powders, and they produce cracks which lead to fracture and make the tensile performance worse. The performance of extruded γ-TiAl alloy can be improved through improving powder capsulation and vacuum degassing technology, which makes the combining effect between powders better.
页数70
语种中文
文献类型学位论文
条目标识符http://ir.imr.ac.cn/handle/321006/17265
专题中国科学院金属研究所
推荐引用方式
GB/T 7714
徐强. Ti-Al基合金洁净粉末的表征及挤压材组织和性能研究[D]. 金属研究所. 中国科学院金属研究所,2009.
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