Temperature-dependent selective nucleation of single-walled carbon nanotubes from stabilized catalyst nanoparticles

doi:10.1016/j.cej.2021.133487

IMR OpenIR

	Temperature-dependent selective nucleation of single-walled carbon nanotubes from stabilized catalyst nanoparticles
	Wu, Qianru 1; Qiu, Lu 2; Zhang, Lili 3; Liu, Huaping 4; Ma, Ruixue 3; Xie, Piao 3; Liu, Runluan 1; Hou, Pengxiang 3; Ding, Feng 2; Liu, Chang 3; He, Maoshuai 1
通讯作者	Ding, Feng(f.ding@unist.ac.kr) ; Liu, Chang(cliu@imr.ac.cn) ; He, Maoshuai(hemaoshuai@qust.edu.cn)
	2022-03-01
发表期刊	CHEMICAL ENGINEERING JOURNAL
ISSN	1385-8947
卷号	431 页码:8
摘要	The utilization of metal nanoparticles supported on oxides substrate as a catalyst for rational single-walled carbon nanotube (SWCNT) growth is hindered by particle coarsening at high synthesis temperature, despite many empirical advances in supported catalyst design. In this study, a newly developed MgO-supported cobalt (Co-MgO) catalyst affords the formation of well-stabilized Co nanoparticles upon reduction, which is attributed to the electronic metal-support interaction and electrostatic stabilization at the Co-MgO interface. The highly stabilized Co nanoparticles led to the predominant growth of (6, 5) SWCNTs at 700 & DEG;C by CO disproportionation and the major SWCNT species was found to be (7, 5) SWCNTs at a reaction temperature of 800 & DEG;C. The temperature-dependent selective growth of the two SWCNT species was found, by density functional theory calculation, to be strongly correlated with the change of the relative thermodynamic stability of the SWCNT nuclei in the chirality assigning process at different temperatures.
关键词	Single-Walled Carbon Nanotubes Particle Stability Selective Growth Thermodynamic Stability Environmental Transmission Electron Microscopy
资助者	National Natural Science Foundation of China ; Key Basic Research Project of Shandong Province ; Taishan Scholar Advantage and Characteristic Discipline Team of Eco Chemical Process and Technology ; Institute for Basic Science
DOI	10.1016/j.cej.2021.133487
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[51972184] ; National Natural Science Foundation of China[51625203] ; National Natural Science Foundation of China[51802316] ; Key Basic Research Project of Shandong Province[ZR2019ZD49] ; Taishan Scholar Advantage and Characteristic Discipline Team of Eco Chemical Process and Technology[IBS-R019-D1] ; Institute for Basic Science[IBS-R019-D1]
WOS研究方向	Engineering
WOS类目	Engineering, Environmental ; Engineering, Chemical
WOS记录号	WOS:000772998200002
出版者	ELSEVIER SCIENCE SA
引用统计	被引频次：14[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/172931
专题	中国科学院金属研究所
通讯作者	Ding, Feng; Liu, Chang; He, Maoshuai
作者单位	1.Qingdao Univ Sci & Technol, State Key Lab Ecochem Engn, Minist Educ, Coll Chem & Mol Engn,Taishan Scholar Adv & Charac, Qingdao 266042, Peoples R China 2.Inst Basic Sci, Ctr Multidimens Carbon Mat, UNIST Gil 50, Ulsan 44919, South Korea 3.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Peoples R China 4.Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Wu, Qianru,Qiu, Lu,Zhang, Lili,et al. Temperature-dependent selective nucleation of single-walled carbon nanotubes from stabilized catalyst nanoparticles[J]. CHEMICAL ENGINEERING JOURNAL,2022,431:8.
APA	Wu, Qianru.,Qiu, Lu.,Zhang, Lili.,Liu, Huaping.,Ma, Ruixue.,...&He, Maoshuai.(2022).Temperature-dependent selective nucleation of single-walled carbon nanotubes from stabilized catalyst nanoparticles.CHEMICAL ENGINEERING JOURNAL,431,8.
MLA	Wu, Qianru,et al."Temperature-dependent selective nucleation of single-walled carbon nanotubes from stabilized catalyst nanoparticles".CHEMICAL ENGINEERING JOURNAL 431(2022):8.