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One-step supramolecular preorganization constructed crinkly graphitic carbon nitride nanosheets with enhanced photocatalytic activity
Wang, Songcan1; Li, Yuelin1,2; Wang, Xin1; Zi, Guohao1,2; Zhou, Chenyang1,2; Liu, Boyan1; Liu, Gang5,6; Wang, Lianzhou3,4; Huang, Wei1
Corresponding AuthorWang, Songcan(iamscwang@nwpu.edu.cn) ; Wang, Lianzhou(l.wang@uq.edu.au) ; Huang, Wei(iamwhuang@nwpu.edu.cn)
2022-03-30
Source PublicationJOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
ISSN1005-0302
Volume104Pages:155-162
AbstractHere we report a new one-step thermal polycondensation process to form crinkly graphitic carbon nitride nanosheets (CGCNNs) via supramolecular preorganization, using a mixture of urea and melamine as the starting material. Systematical studies reveal that the newly developed CGCNNs significantly strengthen the optical absorption, widen the bandgap, and increase the Hall mobility and carrier density compared to that of its bulk counterpart, regardless of the similar chemical composition and structure. As a result, the photocatalytic hydrogen production rate is improved by 7 times. Moreover, Na doping of CGCNNs can further promote its photocatalytic activity, leading to an excellent photocatalytic hydrogen production rate of 250.9 mu mol h -1 , which is approximately 10.5 times higher than its bulk counterpart. Moreover, an impressive apparent quantum efficiency of 19.12% is achieved at 420 nm. This study provides a facile strategy for the design of efficient low-cost carbon-nitride-based photocatalysts for solar fuel production. (c) 2022 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.
KeywordCarbon nitride Supramolecular preorganization Hall mobility Na doping Solar hydrogen
Funding OrganizationNational Natural Science Foundation of China ; Fundamental Research Funds for the Central Universities ; Joint Research Funds of Department of Science & Technology of Shaanxi Province ; Northwestern Polytechnical University ; Australian Research Council ; Laureate Fellowship
DOI10.1016/j.jmst.2021.07.014
Indexed BySCI
Language英语
Funding ProjectNational Natural Science Foundation of China[52002328] ; Fundamental Research Funds for the Central Universities ; Joint Research Funds of Department of Science & Technology of Shaanxi Province ; Northwestern Polytechnical University[2020GXLH-Z-018] ; Australian Research Council ; Laureate Fellowship
WOS Research AreaMaterials Science ; Metallurgy & Metallurgical Engineering
WOS SubjectMaterials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering
WOS IDWOS:000773043300008
PublisherJOURNAL MATER SCI TECHNOL
Citation statistics
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/172991
Collection中国科学院金属研究所
Corresponding AuthorWang, Songcan; Wang, Lianzhou; Huang, Wei
Affiliation1.Northwestern Polytech Univ, Frontiers Sci Ctr Flexible Elect, Xian Inst Flexible Elect IFE, Xian Inst Biomed Mat & Engn, 127 West Youyi Rd, Xian 710072, Peoples R China
2.Northwestern Polytech Univ, Honors Coll, 127 West Youyi Rd, Xian 710072, Peoples R China
3.Univ Queensland, Nanomat Ctr, Sch Chem Engn, Brisbane, Qld 4072, Australia
4.Univ Queensland, Australian Inst Bioengn & Nanotechnol, Brisbane, Qld 4072, Australia
5.Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, 72 Wenhua Rd, Shenyang 110016, Peoples R China
6.Univ Sci & Technol China, Sch Mat Sci & Engn, 72 Wenhua Rd, Shenyang 110016, Peoples R China
Recommended Citation
GB/T 7714
Wang, Songcan,Li, Yuelin,Wang, Xin,et al. One-step supramolecular preorganization constructed crinkly graphitic carbon nitride nanosheets with enhanced photocatalytic activity[J]. JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,2022,104:155-162.
APA Wang, Songcan.,Li, Yuelin.,Wang, Xin.,Zi, Guohao.,Zhou, Chenyang.,...&Huang, Wei.(2022).One-step supramolecular preorganization constructed crinkly graphitic carbon nitride nanosheets with enhanced photocatalytic activity.JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,104,155-162.
MLA Wang, Songcan,et al."One-step supramolecular preorganization constructed crinkly graphitic carbon nitride nanosheets with enhanced photocatalytic activity".JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY 104(2022):155-162.
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