| One-step supramolecular preorganization constructed crinkly graphitic carbon nitride nanosheets with enhanced photocatalytic activity | |
| Wang, Songcan1; Li, Yuelin1,2; Wang, Xin1; Zi, Guohao1,2; Zhou, Chenyang1,2; Liu, Boyan1; Liu, Gang5,6; Wang, Lianzhou3,4; Huang, Wei1 | |
| Corresponding Author | Wang, Songcan(iamscwang@nwpu.edu.cn) ; Wang, Lianzhou(l.wang@uq.edu.au) ; Huang, Wei(iamwhuang@nwpu.edu.cn) |
| 2022-03-30 | |
| Source Publication | JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
 |
| ISSN | 1005-0302 |
| Volume | 104Pages:155-162 |
| Abstract | Here we report a new one-step thermal polycondensation process to form crinkly graphitic carbon nitride nanosheets (CGCNNs) via supramolecular preorganization, using a mixture of urea and melamine as the starting material. Systematical studies reveal that the newly developed CGCNNs significantly strengthen the optical absorption, widen the bandgap, and increase the Hall mobility and carrier density compared to that of its bulk counterpart, regardless of the similar chemical composition and structure. As a result, the photocatalytic hydrogen production rate is improved by 7 times. Moreover, Na doping of CGCNNs can further promote its photocatalytic activity, leading to an excellent photocatalytic hydrogen production rate of 250.9 mu mol h -1 , which is approximately 10.5 times higher than its bulk counterpart. Moreover, an impressive apparent quantum efficiency of 19.12% is achieved at 420 nm. This study provides a facile strategy for the design of efficient low-cost carbon-nitride-based photocatalysts for solar fuel production. (c) 2022 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology. |
| Keyword | Carbon nitride Supramolecular preorganization Hall mobility Na doping Solar hydrogen |
| Funding Organization | National Natural Science Foundation of China ; Fundamental Research Funds for the Central Universities ; Joint Research Funds of Department of Science & Technology of Shaanxi Province ; Northwestern Polytechnical University ; Australian Research Council ; Laureate Fellowship |
| DOI | 10.1016/j.jmst.2021.07.014 |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | National Natural Science Foundation of China[52002328] ; Fundamental Research Funds for the Central Universities ; Joint Research Funds of Department of Science & Technology of Shaanxi Province ; Northwestern Polytechnical University[2020GXLH-Z-018] ; Australian Research Council ; Laureate Fellowship |
| WOS Research Area | Materials Science ; Metallurgy & Metallurgical Engineering |
| WOS Subject | Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering |
| WOS ID | WOS:000773043300008 |
| Publisher | JOURNAL MATER SCI TECHNOL |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/172991 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Wang, Songcan; Wang, Lianzhou; Huang, Wei |
| Affiliation | 1.Northwestern Polytech Univ, Frontiers Sci Ctr Flexible Elect, Xian Inst Flexible Elect IFE, Xian Inst Biomed Mat & Engn, 127 West Youyi Rd, Xian 710072, Peoples R China 2.Northwestern Polytech Univ, Honors Coll, 127 West Youyi Rd, Xian 710072, Peoples R China 3.Univ Queensland, Nanomat Ctr, Sch Chem Engn, Brisbane, Qld 4072, Australia 4.Univ Queensland, Australian Inst Bioengn & Nanotechnol, Brisbane, Qld 4072, Australia 5.Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, 72 Wenhua Rd, Shenyang 110016, Peoples R China 6.Univ Sci & Technol China, Sch Mat Sci & Engn, 72 Wenhua Rd, Shenyang 110016, Peoples R China |
| Recommended Citation GB/T 7714 | Wang, Songcan,Li, Yuelin,Wang, Xin,et al. One-step supramolecular preorganization constructed crinkly graphitic carbon nitride nanosheets with enhanced photocatalytic activity[J]. JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,2022,104:155-162. |
| APA | Wang, Songcan.,Li, Yuelin.,Wang, Xin.,Zi, Guohao.,Zhou, Chenyang.,...&Huang, Wei.(2022).One-step supramolecular preorganization constructed crinkly graphitic carbon nitride nanosheets with enhanced photocatalytic activity.JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,104,155-162. |
| MLA | Wang, Songcan,et al."One-step supramolecular preorganization constructed crinkly graphitic carbon nitride nanosheets with enhanced photocatalytic activity".JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY 104(2022):155-162. |
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