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Corrosion resistance of calcium zirconate crucible to titanium-copper melts
Song, Qingzhong1,2; Liang, Tian1,3; Qian, Kun1,2; Xing, Weiwei1,3; Zha, Xiangdong1,3; Chen, Bo1,3; Ma, Yingche1,3; Liu, Kui1,3
Corresponding AuthorMa, Yingche() ; Liu, Kui()
2022-07-01
Source PublicationJOURNAL OF THE EUROPEAN CERAMIC SOCIETY
ISSN0955-2219
Volume42Issue:7Pages:3321-3331
AbstractThe corrosion resistance of refractory materials to the titanium alloy melts is vital for the production of titanium alloys by vacuum induction melting. In this study, the corrosion behavior of calcia-stabilized zirconia, solid state synthesized calcium zirconate, and fused calcium zirconate refractory suffering Ti-5 wt% Cu melts were investigated at 1680 degrees C for 15 min of soaking time by the cup test method. It was found that the three crucibles directly dissolved into the titanium melt, then generated Ti (Zr, O) and CaZrO3 in the infiltration layer, and eventually developed a porous Ti3O layer in the lining. Besides, the contamination of Ti-5 wt% Cu alloy (oxygen: 5.3 wt%; zirconium: 6.01 wt%; calcium: 0.42 wt%) by fused calcium zirconate crucible was significantly less than the solid state synthesized one (oxygen: 5.83 wt%; zirconium: 6.14 wt%; calcium: 0.43 wt%), implying that the production method of calcium zirconate notably affected the impurity of titanium alloys.
KeywordInterfacial reaction Vacuum induction melting Calcia-stabilized zirconia Calcium zirconate Titanium-copper alloy
DOI10.1016/j.jeurceramsoc.2022.02.011
Indexed BySCI
Language英语
WOS Research AreaMaterials Science
WOS SubjectMaterials Science, Ceramics
WOS IDWOS:000766630300002
PublisherELSEVIER SCI LTD
Citation statistics
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/173220
Collection中国科学院金属研究所
Corresponding AuthorMa, Yingche; Liu, Kui
Affiliation1.Chinese Acad Sci, Inst Met Res, Shi Changxu Innovat Ctr Adv Mat, Shenyang 110016, Peoples R China
2.Univ Sci & Technol China, Sch Mat Sci & Engn, Hefei 230026, Peoples R China
3.CAS Key Lab Nucl Mat & Safety Assessment, IMR NMSA, Shenyang 110016, Peoples R China
Recommended Citation
GB/T 7714
Song, Qingzhong,Liang, Tian,Qian, Kun,et al. Corrosion resistance of calcium zirconate crucible to titanium-copper melts[J]. JOURNAL OF THE EUROPEAN CERAMIC SOCIETY,2022,42(7):3321-3331.
APA Song, Qingzhong.,Liang, Tian.,Qian, Kun.,Xing, Weiwei.,Zha, Xiangdong.,...&Liu, Kui.(2022).Corrosion resistance of calcium zirconate crucible to titanium-copper melts.JOURNAL OF THE EUROPEAN CERAMIC SOCIETY,42(7),3321-3331.
MLA Song, Qingzhong,et al."Corrosion resistance of calcium zirconate crucible to titanium-copper melts".JOURNAL OF THE EUROPEAN CERAMIC SOCIETY 42.7(2022):3321-3331.
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