PPy coated nanoflower like CuCo2O4 based on in situ growth of nanoporous copper for high-performance supercapacitor electrodes | |
Zhao, Zongchen1; Zheng, Lili2; Li, Haoran1; He, Zeyin1; Han, Dong1; Shi, Jing1; Xu, Bin3,4; Wang, Huanlei1 | |
Corresponding Author | Shi, Jing(shijing@ouc.edu.cn) ; Xu, Bin(bxu@imr.ac.cn) |
2022-04-09 | |
Source Publication | NANOTECHNOLOGY
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ISSN | 0957-4484 |
Volume | 33Issue:15Pages:11 |
Abstract | General CuCo2O4 electrodes suffer a very low reversible capacity and poor cycling stability because of easily fading phenomena and volume change during cycling. To optimize the electrode, a facile method is conducted to fabricate a novel electrode of Cu@CuCo2O4@polypyrrole nanoflowers. Due to larger specific surface area and more electrochemical reactive areas of CuCo2O4@polypyrrole nanoflowers, the pseudocapacitance of the in situ grown CuCo2O4@polypyrrole (912 F g(-1) at 2 A g(-1)) is much higher than the pristine CuCo2O4 (618 F g(-1) at 2 A g(-1)). Remarkably, the CuCo2O4@polypyrrole (cathode) and active carbon (anode) are used to assemble an asymmetric supercapacitor, which exhibits a relatively high energy density of 90 Wh kg(-1) at a power density of 2519 W kg(-1) and 35 Wh kg(-1) at a high-power density of 9109 W kg(-1), and excellent cycling stability (about 90.4% capacitance retention over 10 000 cycles). The prominent performance of CuCo2O4@polypyrrole makes it as a potential electrode for supercapacitor. |
Keyword | CuCo2O4 PPy nanoporous copper supercapacitor |
Funding Organization | National Natural Science Foundation of China ; Natural Science Foundation of Shandong Province |
DOI | 10.1088/1361-6528/ac4660 |
Indexed By | SCI |
Language | 英语 |
Funding Project | National Natural Science Foundation of China[52001179] ; Natural Science Foundation of Shandong Province[ZR2020ME019] |
WOS Research Area | Science & Technology - Other Topics ; Materials Science ; Physics |
WOS Subject | Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied |
WOS ID | WOS:000744269700001 |
Publisher | IOP Publishing Ltd |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.imr.ac.cn/handle/321006/173615 |
Collection | 中国科学院金属研究所 |
Corresponding Author | Shi, Jing; Xu, Bin |
Affiliation | 1.Ocean Univ China, Sch Mat Sci & Engn, Qingdao 266100, Peoples R China 2.Qingdao Univ, Coll Mech & Elect Engn, Natl Engn Res Ctr Intelligent Elect Vehicle Power, Qingdao 266071, Peoples R China 3.Chinese Acad Sci, Inst Met Res, Shengyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 4.Chinese Acad Sci, Inst Met Res, Key Lab Nucl Mat & Safety, Shenyang 11016, Peoples R China |
Recommended Citation GB/T 7714 | Zhao, Zongchen,Zheng, Lili,Li, Haoran,et al. PPy coated nanoflower like CuCo2O4 based on in situ growth of nanoporous copper for high-performance supercapacitor electrodes[J]. NANOTECHNOLOGY,2022,33(15):11. |
APA | Zhao, Zongchen.,Zheng, Lili.,Li, Haoran.,He, Zeyin.,Han, Dong.,...&Wang, Huanlei.(2022).PPy coated nanoflower like CuCo2O4 based on in situ growth of nanoporous copper for high-performance supercapacitor electrodes.NANOTECHNOLOGY,33(15),11. |
MLA | Zhao, Zongchen,et al."PPy coated nanoflower like CuCo2O4 based on in situ growth of nanoporous copper for high-performance supercapacitor electrodes".NANOTECHNOLOGY 33.15(2022):11. |
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