Crystal phase-selective synthesis of intermetallic palladium borides and their phase-regulated (electro)catalytic properties

doi:10.1039/d1cy02112e

IMR OpenIR

	Crystal phase-selective synthesis of intermetallic palladium borides and their phase-regulated (electro)catalytic properties
	Li, Zhenyu 1,2; Zhao, Linmin 3; Chen, Hui 1; Liang, Xiao 1; Ai, Xuan 1; Xie, Zhoubing 1; Li, Xiaotian 2; Yang, Feng 4; Liu, Hongyang 3; Zou, Xiaoxin 1
通讯作者	Liu, Hongyang(liuhy@imr.ac.cn) ; Zou, Xiaoxin(xxzou@jlu.edu.cn)
	2021-12-13
发表期刊	CATALYSIS SCIENCE & TECHNOLOGY
ISSN	2044-4753
页码	5
摘要	Three crystal phases of Pd-B intermetallics, namely, Pd6B, Pd5B2 and Pd2B, are synthesized, and their phase-dependent catalytic activities toward electrochemical water splitting and Suzuki coupling reactions are studied. In both reactions, their catalytic activities are found to increase in the order Pd, Pd6B, Pd5B2 and Pd2B. This activity trend is strongly associated with the Pd(d)-B(s,p) orbital hybridization-regulated surface adsorption properties.
资助者	National Natural Science Foundation of China (NSFC) ; Fok Ying Tung Education Foundation ; Fundamental Research Funds for the Central Universities, NSFC ; 111 Project
DOI	10.1039/d1cy02112e
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China (NSFC)[21922507] ; National Natural Science Foundation of China (NSFC)[21771079] ; National Natural Science Foundation of China (NSFC)[21901083] ; National Natural Science Foundation of China (NSFC)[22179046] ; Fok Ying Tung Education Foundation[161011] ; Fundamental Research Funds for the Central Universities, NSFC[21621001] ; 111 Project[B17020]
WOS研究方向	Chemistry
WOS类目	Chemistry, Physical
WOS记录号	WOS:000747885300001
出版者	ROYAL SOC CHEMISTRY
引用统计	被引频次：7[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/173618
专题	中国科学院金属研究所
通讯作者	Liu, Hongyang; Zou, Xiaoxin
作者单位	1.Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China 2.Jilin Univ, Coll Mat Sci & Engn, Changchun 130022, Peoples R China 3.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 4.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Peoples R China
推荐引用方式 GB/T 7714	Li, Zhenyu,Zhao, Linmin,Chen, Hui,et al. Crystal phase-selective synthesis of intermetallic palladium borides and their phase-regulated (electro)catalytic properties[J]. CATALYSIS SCIENCE & TECHNOLOGY,2021:5.
APA	Li, Zhenyu.,Zhao, Linmin.,Chen, Hui.,Liang, Xiao.,Ai, Xuan.,...&Zou, Xiaoxin.(2021).Crystal phase-selective synthesis of intermetallic palladium borides and their phase-regulated (electro)catalytic properties.CATALYSIS SCIENCE & TECHNOLOGY,5.
MLA	Li, Zhenyu,et al."Crystal phase-selective synthesis of intermetallic palladium borides and their phase-regulated (electro)catalytic properties".CATALYSIS SCIENCE & TECHNOLOGY (2021):5.