Crystal phase-selective synthesis of intermetallic palladium borides and their phase-regulated (electro)catalytic properties

doi:10.1039/d1cy02112e

IMR OpenIR

	Crystal phase-selective synthesis of intermetallic palladium borides and their phase-regulated (electro)catalytic properties
	Li, Zhenyu 1,2; Zhao, Linmin 3; Chen, Hui 1; Liang, Xiao 1; Ai, Xuan 1; Xie, Zhoubing 1; Li, Xiaotian 2; Yang, Feng 4; Liu, Hongyang 3; Zou, Xiaoxin 1
Corresponding Author	Liu, Hongyang(liuhy@imr.ac.cn) ; Zou, Xiaoxin(xxzou@jlu.edu.cn)
	2021-12-13
Source Publication	CATALYSIS SCIENCE & TECHNOLOGY
ISSN	2044-4753
Pages	5
Abstract	Three crystal phases of Pd-B intermetallics, namely, Pd6B, Pd5B2 and Pd2B, are synthesized, and their phase-dependent catalytic activities toward electrochemical water splitting and Suzuki coupling reactions are studied. In both reactions, their catalytic activities are found to increase in the order Pd, Pd6B, Pd5B2 and Pd2B. This activity trend is strongly associated with the Pd(d)-B(s,p) orbital hybridization-regulated surface adsorption properties.
Funding Organization	National Natural Science Foundation of China (NSFC) ; Fok Ying Tung Education Foundation ; Fundamental Research Funds for the Central Universities, NSFC ; 111 Project
DOI	10.1039/d1cy02112e
Indexed By	SCI
Language	英语
Funding Project	National Natural Science Foundation of China (NSFC)[21922507] ; National Natural Science Foundation of China (NSFC)[21771079] ; National Natural Science Foundation of China (NSFC)[21901083] ; National Natural Science Foundation of China (NSFC)[22179046] ; Fok Ying Tung Education Foundation[161011] ; Fundamental Research Funds for the Central Universities, NSFC[21621001] ; 111 Project[B17020]
WOS Research Area	Chemistry
WOS Subject	Chemistry, Physical
WOS ID	WOS:000747885300001
Publisher	ROYAL SOC CHEMISTRY
Citation statistics
Document Type	期刊论文
Identifier	http://ir.imr.ac.cn/handle/321006/173618
Collection	中国科学院金属研究所
Corresponding Author	Liu, Hongyang; Zou, Xiaoxin
Affiliation	1.Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China 2.Jilin Univ, Coll Mat Sci & Engn, Changchun 130022, Peoples R China 3.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 4.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Peoples R China
Recommended Citation GB/T 7714	Li, Zhenyu,Zhao, Linmin,Chen, Hui,et al. Crystal phase-selective synthesis of intermetallic palladium borides and their phase-regulated (electro)catalytic properties[J]. CATALYSIS SCIENCE & TECHNOLOGY,2021:5.
APA	Li, Zhenyu.,Zhao, Linmin.,Chen, Hui.,Liang, Xiao.,Ai, Xuan.,...&Zou, Xiaoxin.(2021).Crystal phase-selective synthesis of intermetallic palladium borides and their phase-regulated (electro)catalytic properties.CATALYSIS SCIENCE & TECHNOLOGY,5.
MLA	Li, Zhenyu,et al."Crystal phase-selective synthesis of intermetallic palladium borides and their phase-regulated (electro)catalytic properties".CATALYSIS SCIENCE & TECHNOLOGY (2021):5.

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