Crystal phase-selective synthesis of intermetallic palladium borides and their phase-regulated (electro)catalytic properties | |
Li, Zhenyu1,2; Zhao, Linmin3; Chen, Hui1; Liang, Xiao1; Ai, Xuan1; Xie, Zhoubing1; Li, Xiaotian2; Yang, Feng4; Liu, Hongyang3; Zou, Xiaoxin1 | |
Corresponding Author | Liu, Hongyang(liuhy@imr.ac.cn) ; Zou, Xiaoxin(xxzou@jlu.edu.cn) |
2021-12-13 | |
Source Publication | CATALYSIS SCIENCE & TECHNOLOGY
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ISSN | 2044-4753 |
Pages | 5 |
Abstract | Three crystal phases of Pd-B intermetallics, namely, Pd6B, Pd5B2 and Pd2B, are synthesized, and their phase-dependent catalytic activities toward electrochemical water splitting and Suzuki coupling reactions are studied. In both reactions, their catalytic activities are found to increase in the order Pd, Pd6B, Pd5B2 and Pd2B. This activity trend is strongly associated with the Pd(d)-B(s,p) orbital hybridization-regulated surface adsorption properties. |
Funding Organization | National Natural Science Foundation of China (NSFC) ; Fok Ying Tung Education Foundation ; Fundamental Research Funds for the Central Universities, NSFC ; 111 Project |
DOI | 10.1039/d1cy02112e |
Indexed By | SCI |
Language | 英语 |
Funding Project | National Natural Science Foundation of China (NSFC)[21922507] ; National Natural Science Foundation of China (NSFC)[21771079] ; National Natural Science Foundation of China (NSFC)[21901083] ; National Natural Science Foundation of China (NSFC)[22179046] ; Fok Ying Tung Education Foundation[161011] ; Fundamental Research Funds for the Central Universities, NSFC[21621001] ; 111 Project[B17020] |
WOS Research Area | Chemistry |
WOS Subject | Chemistry, Physical |
WOS ID | WOS:000747885300001 |
Publisher | ROYAL SOC CHEMISTRY |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.imr.ac.cn/handle/321006/173618 |
Collection | 中国科学院金属研究所 |
Corresponding Author | Liu, Hongyang; Zou, Xiaoxin |
Affiliation | 1.Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China 2.Jilin Univ, Coll Mat Sci & Engn, Changchun 130022, Peoples R China 3.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 4.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Peoples R China |
Recommended Citation GB/T 7714 | Li, Zhenyu,Zhao, Linmin,Chen, Hui,et al. Crystal phase-selective synthesis of intermetallic palladium borides and their phase-regulated (electro)catalytic properties[J]. CATALYSIS SCIENCE & TECHNOLOGY,2021:5. |
APA | Li, Zhenyu.,Zhao, Linmin.,Chen, Hui.,Liang, Xiao.,Ai, Xuan.,...&Zou, Xiaoxin.(2021).Crystal phase-selective synthesis of intermetallic palladium borides and their phase-regulated (electro)catalytic properties.CATALYSIS SCIENCE & TECHNOLOGY,5. |
MLA | Li, Zhenyu,et al."Crystal phase-selective synthesis of intermetallic palladium borides and their phase-regulated (electro)catalytic properties".CATALYSIS SCIENCE & TECHNOLOGY (2021):5. |
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