Green strategy of scaleably synthesizing copper nanocomposites with remarkable catalytic activity for wastewater treatment

doi:10.1016/j.jmst.2021.04.017

IMR OpenIR

	Green strategy of scaleably synthesizing copper nanocomposites with remarkable catalytic activity for wastewater treatment
	Zhao, Bowen 1,2,3; Li, Hailong 1,3; Li, Zhengkun 1,3; Ge, Shaofan 1,2,3; Qin, Xindong 4; Zhang, Shiming 5; Wang, Aimin 1,3; Zhang, Haifeng 1,3; Zhu, Zhengwang 1,3
通讯作者	Zhu, Zhengwang(zwzhu@imr.ac.cn)
	2021-12-30
发表期刊	JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
ISSN	1005-0302
卷号	95 页码:158-166
摘要	The functional copper nanocomposites (Cu NCs) have received increasing attention in the environmental catalysis application for wastewater treatment due to their superior catalytic activity and reactivity. However, overcoming the pH limitations towards the neutral and alkaline wastewater remains a tricky challenge. In this work, we demonstrate a green strategy to synthesize Cu NCs with coexistence of active Cu, Cu2O and ZrO2 by self-propagating combustion of metallic glassy ribbons, which exhibit the extremely superior catalytic performance for degradation reaction, providing full conversion of organic dyes completely to the environmental friendly small species (efficiency > 99%) under acidic, neutral and alkaline conditions. Compared with all other catalysts developed thus far, the novel Cu NCs catalysts with more active sites present much enhanced catalytic capability of degradation efficiency without the use of any chemical reagents for neutral and alkaline organic dye solutions. The possible decomposition pathways of organic dyes for different pH systems were systematically investigated. More importantly, the two kinds of catalytic mechanism related to high reactivity of nanoscale Cu/Cu2O and strong oxidizing capability of activated OH/O-2 - radicals can also be successfully confirmed under different pH conditions. The green synthetic approach can be extended to design the various M-based nanocomposites (M = Fe, Co, Ni, Ag, Pd) as efficient catalysts for the functional applications of many chemical reactions. (C) 2021 Published by Elsevier Ltd on behalf of Chinese Society for Metals.
关键词	Copper nanocomposites Metallic glasses Self-propagating combustion Catalytic degradation Electron transfer Organic dyes
资助者	National Natural Science Foundation of China ; Liaoning Revitalization Talents Program ; fund of Qingdao
DOI	10.1016/j.jmst.2021.04.017
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[51801209] ; National Natural Science Foundation of China[51790484] ; Liaoning Revitalization Talents Program[XLYC1802078] ; Liaoning Revitalization Talents Program[XLYC1807062] ; fund of Qingdao[19-9-2-1-wz]
WOS研究方向	Materials Science ; Metallurgy & Metallurgical Engineering
WOS类目	Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering
WOS记录号	WOS:000733965200005
出版者	JOURNAL MATER SCI TECHNOL
引用统计	被引频次：8[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/173848
专题	中国科学院金属研究所
通讯作者	Zhu, Zhengwang
作者单位	1.Chinese Acad Sci, Shi Changxu Innovat Ctr Adv Mat, Inst Met Res, Shenyang 110016, Peoples R China 2.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China 3.Chinese Acad Sci, Inst Met Res, OCAS Key Lab Nucl Mat & Safety Assessment, Shenyang 110016, Peoples R China 4.Liaoning Univ, Coll Chem, Inst Rare & Scattered Elements, Shenyang 110036, Peoples R China 5.Qingdao Yunlu Adv Mat Technol Co Ltd, Qingdao 266232, Peoples R China
推荐引用方式 GB/T 7714	Zhao, Bowen,Li, Hailong,Li, Zhengkun,et al. Green strategy of scaleably synthesizing copper nanocomposites with remarkable catalytic activity for wastewater treatment[J]. JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,2021,95:158-166.
APA	Zhao, Bowen.,Li, Hailong.,Li, Zhengkun.,Ge, Shaofan.,Qin, Xindong.,...&Zhu, Zhengwang.(2021).Green strategy of scaleably synthesizing copper nanocomposites with remarkable catalytic activity for wastewater treatment.JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,95,158-166.
MLA	Zhao, Bowen,et al."Green strategy of scaleably synthesizing copper nanocomposites with remarkable catalytic activity for wastewater treatment".JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY 95(2021):158-166.