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MP 159钴基合金强化机理研究
陈建春
学位类型硕士
导师师昌绪
1989-09-14
学位授予单位中国科学院金属研究所
学位授予地点中国科学院金属研究所
摘要本文研究了MP159钴基合金室温形变强化机理和时效强化机理,同时对MP159合金的长期时效性能稳定性及高温相变进行了研究。结果表明,MP159合金室温形变时产生大量的机械孪晶和少量的ε相,形变强化主要归于孪晶的作用。48%形变后经660℃/4h 进一步强化是由于合金中进一步发生了二次 γ→ε转变。同时在 650℃ 长期时效中,γ'相析出在固溶状态合金中分布均匀,对合金有显著硬化,48%形变状态合金中γ'在基体中存在广泛的贫化区(PFZ),使硬化不明显。长期时效后,48%形变合金中机械孪晶和一次ε相依然存在,二次 ε相及γ'和晶界、亚晶界的可能为 μ和σ的块状相产生,为此保证了形变合金的稳定性。同时发现,固溶状态合金在 800℃下 γ'迅速长大,硬度由8HRC提高到35HRC。经800 ℃/70h处理后,晶界析出μ相。48%变形合金在800℃下初期发生二次γ→ε转变,硬度升高,由于回复再结晶,硬度略下降,经800 ℃/70h处理后仍有孪晶和ε相存在,形变强化作用仍得以保持。
其他摘要Strengthening mechanism in MP159 Co-base alloy has been investigated. The stability of properties after prolonged aging and its relationship with phase transformation has also been Studied. Cold work (CW) of Solution treated (ST) alloy produces a large number of thin FCC twins and a few HCP ε-platelets. A deformation-induced strengthening is mainly attributed to the twins. The Subsequent age-strengthening effect at 660℃/4h is due to the transformation of additional γ_(fcc)→ε_(hcp). The γ' phase precipitated in alloy during 650℃ prolonged exposure hardens significantly ST alloy, but no effect on 48%CW alloy which can be explained by the formation of a zone depleted in γ' precipitates in 48%CW alloy. The wide precipitate-free zone (PFZ) impairs the strengthening effect. Because of the formation of secondary ε、γ'and possibly μ、σ-phase during prolonged aging, the 48%CW alloy still has high strength, hardness and ductility. γ' precipitate in ST alloy is nucleated and grown rapidly at 800 ℃ with the hardness increase from 8HRC to 35HRC、μ-phase is occurred on the boundary of ST alloy after 800℃/70h treatment. At the beginning, the additional γ_(fcc)→ε_(hcp) takes place in 48%CW alloy at 800 ℃, that makes the hardness increase quickly. Afterward, the hardness drops down slowly due to the effect of recovery and recrystallization. The properties of 48%CW alloy tends to be stable because of the existence of twins and the pinning effect of precipitation phase on the grain boundary and subgrain interface, that is the reason why the strengthening effect can be maintained after high temperature aging.
页数66
语种中文
文献类型学位论文
条目标识符http://ir.imr.ac.cn/handle/321006/17400
专题中国科学院金属研究所
推荐引用方式
GB/T 7714
陈建春. MP 159钴基合金强化机理研究[D]. 中国科学院金属研究所. 中国科学院金属研究所,1989.
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