Lithiophilic ZnO confined in microscale carbon cubes as a stable host for lithium metal anodes

doi:10.1016/j.carbon.2022.04.045

IMR OpenIR

	Lithiophilic ZnO confined in microscale carbon cubes as a stable host for lithium metal anodes
	Yu, Wan-Jing 1; Liu, Fan 1; Zhang, Lili 2; Liu, Zhiyuan 1; Wang, Sumei 3; Tong, Hui 1,4,5
通讯作者	Tong, Hui(huitong@csu.edu.cn)
	2022-08-30
发表期刊	CARBON
ISSN	0008-6223
卷号	196 页码:92-101
摘要	The high energy density metallic Li anode is a desired electrode candidate for commercial application in future. However, uncontrolled growth of Li dendrites can easily lead to thermal runaway and infinite volume changes. Herein, we propose the addition of lithiophilic ZnO filled into the microsized cubic carbon framework through in situ pyrolyzation of the multiwalled carbon nanotubes-implanted Zn-MOF (denoted as ZnO@C-MWCNTs) as the three-dimensional (3D) host for stable metallic Li anodes. The proposed 3D host with a high specific surface area can effectively accommodate the tremendous volume change of the metallic Li anodes. Meanwhile, this 3D host can prohibit the emergence of Li dendrites by adjusting the local current density. Lithiophilic ZnO, as the homogeneous nucleation site loaded in the 3D structure, can induce homogeneous Li deposition to form a stable Li metal composite electrode with a long cycling life. The 3D ZnO@C-MWCNTs host can hold a high Coulombic efficiency (CE) of 98.5% at 1.0 mA cm-2 and 1.0 mAh cm-2 for more than 240 cycles. Long lifespans of symmetric cells for 320 h at 2.0 mA cm-2 and 1.0 mAh cm-2 with a lower polarization (~28.0 mV) can be achieved.
关键词	Zn-MOF Microscale carbon cube Lithiophilic ZnO Metallic Li anodes Homogeneous nucleation
资助者	Natural Science Foundation of Hunan Province ; Science and Technology Innovation Program of Hunan Province ; Fundamental Research Funds for Central Universities of the Central South University
DOI	10.1016/j.carbon.2022.04.045
收录类别	SCI
语种	英语
资助项目	Natural Science Foundation of Hunan Province[2019JJ50814] ; Science and Technology Innovation Program of Hunan Province[2020SK2007] ; Fundamental Research Funds for Central Universities of the Central South University[2021zzts0606]
WOS研究方向	Chemistry ; Materials Science
WOS类目	Chemistry, Physical ; Materials Science, Multidisciplinary
WOS记录号	WOS:000804037300001
出版者	PERGAMON-ELSEVIER SCIENCE LTD
引用统计	被引频次：4[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/174150
专题	中国科学院金属研究所
通讯作者	Tong, Hui
作者单位	1.Cent South Univ, Sch Met & Environm, Changsha 410083, Peoples R China 2.Chinese Acad Sci, Inst Met Res, 72 Wenhua Rd, Shenyang 110016, Peoples R China 3.Cent South Univ, Powder Met Inst, Changsha 410083, Peoples R China 4.Cent South Univ, Engn Res Ctr Minist Educ Adv Battery Mat, Changsha 410083, Peoples R China 5.Cent South Univ, Natl Engn Res Ctr Low Carbon Nonferrous Met, Changsha 410083, Peoples R China
推荐引用方式 GB/T 7714	Yu, Wan-Jing,Liu, Fan,Zhang, Lili,et al. Lithiophilic ZnO confined in microscale carbon cubes as a stable host for lithium metal anodes[J]. CARBON,2022,196:92-101.
APA	Yu, Wan-Jing,Liu, Fan,Zhang, Lili,Liu, Zhiyuan,Wang, Sumei,&Tong, Hui.(2022).Lithiophilic ZnO confined in microscale carbon cubes as a stable host for lithium metal anodes.CARBON,196,92-101.
MLA	Yu, Wan-Jing,et al."Lithiophilic ZnO confined in microscale carbon cubes as a stable host for lithium metal anodes".CARBON 196(2022):92-101.