Fabrication of three dimensional SiC@C hybrid for efficient direct dehydrogenation of ethylbenzene to styrene

doi:10.1016/j.jmst.2021.06.044

IMR OpenIR

	Fabrication of three dimensional SiC@C hybrid for efficient direct dehydrogenation of ethylbenzene to styrene
	Wang, Jiashun 1,3; Wang, Linlin 2,4; Diao, Jiangyong 2; Xie, Xi 1; Lin, Guoming 1,3; Jia, Qing 1,3; Liu, Hongyang 2,3; Sui, Guoxin 1,3
通讯作者	Diao, Jiangyong(jydiao@imr.ac.cn) ; Liu, Hongyang(liuhy@imr.ac.cn) ; Sui, Guoxin(gxsui@imr.ac.cn)
	2022-03-20
发表期刊	JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
ISSN	1005-0302
卷号	103 页码:209-214
摘要	Synthesis of hybrid carbon materials with core-shell structure and robust catalytic performance is of great research interest, and remains a great challenge in catalytic dehydrogenation of hydrocarbons reaction. In this paper, few-layer sp(2) carbon decorated SiC nanocrystals with core-shell structure (SiC@C) were fabricated through a dual-confined magnesiothermic method by employing glucose and SiO2 as precursors. The SiC@C nanocrystals were further crosslinked to be a three dimensional (3D) mesoporous hybrid by the in situ generated carbon as binders and exhibiting a 410.30 m(2) g(-1) large surface area. The as-prepared SiC@C hybrid materials as metal-free catalysts were evaluated in the steam-free direct dehydrogenation of ethylbenzene to styrene. Benefiting from the abundant surface carbonyl groups on the graphite carbon layers, the optimized yield rate of styrene normalized by carbon mass was as high as 11.58 mmol g(-1) (carbon) h(-1), nearly 4 times that of nanodiamonds. Considering the low cost and excellent catalytic activity, the hybrid 3D SiC@C material may be a promising candidate for direct dehydrogenation of hydrocarbons. (C) 2022 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.
关键词	Silicon carbide Carbon material Core-shell structure Heterogeneous catalysis Direct dehydrogenation Ethylbenzene
资助者	Ministry of Science and Technology ; National Natural Science Foundation of China ; Institute of Metal Research, the Liaoning Revitalization Talents Program ; Sinopec China ; Shenyang National Laboratory for Materials Science ; State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals
DOI	10.1016/j.jmst.2021.06.044
收录类别	SCI
语种	英语
资助项目	Ministry of Science and Technology[2016YFA0204100] ; National Natural Science Foundation of China[21703261] ; National Natural Science Foundation of China[91845201] ; National Natural Science Foundation of China[21961160722] ; National Natural Science Foundation of China[22072162] ; Institute of Metal Research, the Liaoning Revitalization Talents Program[XLYC1907055] ; Sinopec China ; Shenyang National Laboratory for Materials Science[18LHPY010] ; State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals[18LHPY010]
WOS研究方向	Materials Science ; Metallurgy & Metallurgical Engineering
WOS类目	Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering
WOS记录号	WOS:000798995000001
出版者	JOURNAL MATER SCI TECHNOL
引用统计	被引频次：5[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/174180
专题	中国科学院金属研究所
通讯作者	Diao, Jiangyong; Liu, Hongyang; Sui, Guoxin
作者单位	1.Chinese Acad Sci, Inst Met Res, Shi Changxu Innovat Ctr Adv Mat, Shenyang 110016, Peoples R China 2.Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, Shenyang 110016, Peoples R China 3.Univ Sci & Technol China, Sch Mat Sci & Engn, Hefei 230026, Peoples R China 4.Northeastern Univ, Dept Chem, Shenyang 110819, Peoples R China
推荐引用方式 GB/T 7714	Wang, Jiashun,Wang, Linlin,Diao, Jiangyong,et al. Fabrication of three dimensional SiC@C hybrid for efficient direct dehydrogenation of ethylbenzene to styrene[J]. JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,2022,103:209-214.
APA	Wang, Jiashun.,Wang, Linlin.,Diao, Jiangyong.,Xie, Xi.,Lin, Guoming.,...&Sui, Guoxin.(2022).Fabrication of three dimensional SiC@C hybrid for efficient direct dehydrogenation of ethylbenzene to styrene.JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,103,209-214.
MLA	Wang, Jiashun,et al."Fabrication of three dimensional SiC@C hybrid for efficient direct dehydrogenation of ethylbenzene to styrene".JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY 103(2022):209-214.