Ultrafast crystallization of mesoporous Sn-MFI single crystals achieved by addition of the cationic polyelectrolyte in starting gels

doi:10.1016/j.micromeso.2022.111922

IMR OpenIR

	Ultrafast crystallization of mesoporous Sn-MFI single crystals achieved by addition of the cationic polyelectrolyte in starting gels
	Yuan, En-Hui 1; Li, Meng 1; Zhou, Jia-Feng 2; Niu, Yiming 3; Song, Yong-Hong 1; Zhang, Kun 2; Yang, Ming-Hui 1; Jiang, Jinqiang 1; Zhang, Bingsen 3; Xiao, Feng-Shou 4; Liu, Zhao-Tie 1; Liu, Zhong-Wen 1
通讯作者	Zhang, Kun(kzhang@chem.ecnu.edu.cn) ; Zhang, Bingsen(bszhang@imr.ac.cn) ; Liu, Zhong-Wen(zwliu@snnu.edu.cn)
	2022-05-01
发表期刊	MICROPOROUS AND MESOPOROUS MATERIALS
ISSN	1387-1811
卷号	337 页码:10
摘要	Hetematoms substituted zeolites (HSZ) are important absorbents/catalysts for many industrial processes. However, precisely locating the heteroatoms in the desired zeolite frameworks is still challenged by the low crystallization rate. Herein, we report that poly dimethyl diallyl ammonium chloride (PDDA) can greatly accelerate the HSZ crystallization with the simultaneous creation of mesopores. Significantly, highly crystallized Sn-MFI single crystals are obtained within 6 h, which is over one hundred times faster than that of the available methods (similar to 720 h). The addition of PDDA is revealed to speed up the in-situ depolymerization and re-condensation of nanosized silica precursors, leading to the rapid crystallization of MFI framework with the concomitantly homogeneous incorporation of tetra-coordinated Sn atoms. The obtained Sn-MFI mesoporous zeolites exhibit excellent catalytic performance for the hydration of epichlomhydrin to 1, 2-diol. More importantly, the realization of Sn-MEL, ZSM-11, Ga-MFI and ZSM-5 zeolites with prominently short time and the diversity of the cationic polyelectrolyte make the thus developed strategy a highly efficient and general method for synthesizing HSZ.
关键词	Cationic polyelectrolyte Ultrafast crystallization Mesoporous Sn-MFI single Crystal Electrostatic interaction Heterogeneous nucleation
资助者	National Natural Science Foundation of China ; Postdoctoral Science Foundation of China ; Natural Science Foundation of Shaanxi Province
DOI	10.1016/j.micromeso.2022.111922
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[21902097] ; National Natural Science Foundation of China[21636006] ; Postdoctoral Science Foundation of China[2019M653861XB] ; Natural Science Foundation of Shaanxi Province[2020JQ-409]
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Materials Science
WOS类目	Chemistry, Applied ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS记录号	WOS:000799814400001
出版者	ELSEVIER
引用统计	被引频次：4[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/174222
专题	中国科学院金属研究所
通讯作者	Zhang, Kun; Zhang, Bingsen; Liu, Zhong-Wen
作者单位	1.Shaanxi Normal Univ, Sch Chem & Chem Engn, Key Lab Syngas Convers Shaanxi Prov, Xian 710119, Peoples R China 2.East China Normal Univ, Coll Chem & Mol Engn, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China 3.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 4.Zhejiang Univ, Coll Chem & Biol Engn, Minist Educ, Key Lab Biomass Chem Engn, Hangzhou 310027, Peoples R China
推荐引用方式 GB/T 7714	Yuan, En-Hui,Li, Meng,Zhou, Jia-Feng,et al. Ultrafast crystallization of mesoporous Sn-MFI single crystals achieved by addition of the cationic polyelectrolyte in starting gels[J]. MICROPOROUS AND MESOPOROUS MATERIALS,2022,337:10.
APA	Yuan, En-Hui.,Li, Meng.,Zhou, Jia-Feng.,Niu, Yiming.,Song, Yong-Hong.,...&Liu, Zhong-Wen.(2022).Ultrafast crystallization of mesoporous Sn-MFI single crystals achieved by addition of the cationic polyelectrolyte in starting gels.MICROPOROUS AND MESOPOROUS MATERIALS,337,10.
MLA	Yuan, En-Hui,et al."Ultrafast crystallization of mesoporous Sn-MFI single crystals achieved by addition of the cationic polyelectrolyte in starting gels".MICROPOROUS AND MESOPOROUS MATERIALS 337(2022):10.