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氮化硅陶瓷与40Cr钢的钎焊机制及接头性能的研究
赵容福
学位类型硕士
导师斯重遥
1990
学位授予单位中国科学院金属研究所
学位授予地点中国科学院金属研究所
摘要本文对氮化硅陶瓷进行了银基,铜基,铟基钎料的润湿性试验,研究了活性金属元素对润湿性及对氮化硅陶瓷与40Cr钢钎焊接头性能的影响机制,确定了最佳系列钎料,提出了钎料中活性金属元素的合理含量。通过加入过渡层金属,改善钎焊接头性能的研究,发现过渡层金属的选择,即要考虑它们的线膨胀系数,又要考虑其弹性模量,屈服强度等,在膨胀系数基本匹配的条件下,尽可能的选择弹性模量,屈服强度小的材料做过渡层,使其产生塑性变形,以缓和接头的热应力,氮化氮化硅陶瓷与40Cr钢的钎焊接头经SEM,EDX,EPMA等观察分析,认为活性钎料钎焊氮化硅陶瓷与40Cr钢的接合机理是钎料中活性元素钛扩散到界面与氮化硅陶瓷发生化学反应,生成钛氮,钛硅化合物,而形成牢固的接头,活性元素的含量及钎焊工艺参数对接头的强度有着直接影响。
其他摘要In the present paper, wetting experiments of silver, copper and indium based fillers on the silicon nitride ceramic have been investigated. The effects of active metal elements on its mechanism on silicon nitride ceramic and 40Cr steel also have been studied. The optimum filler metal and its concentration of active metal element have been proposed. The mechanical properties of brazing joints were improved by using intermediate metal layers. In order that the intermediate metal acts as a buffer metal which will yield and absorb the heat stresses, arisen from the great diffefrence of thermal expansion of 40Cr steel and Si_3N_4 the intermediate metal should have low elastic modulus and low yield strength. The brazing mechanism of joining silicon nitride ceramic to 40Cr steel was offered based on the analyses of SEM, EDX, EPMA etc. Active Ti in fillers will diffuse into the interface and react with silicon nitride to form TiN, Ti_5Si_3 and TiSi_2 to form a strong joint. The concentration of active elements in fillers and technological parameter of brazing would directly affect the strength of Si_3N_4/40Cr steel joints.
页数93
语种中文
文献类型学位论文
条目标识符http://ir.imr.ac.cn/handle/321006/17460
专题中国科学院金属研究所
推荐引用方式
GB/T 7714
赵容福. 氮化硅陶瓷与40Cr钢的钎焊机制及接头性能的研究[D]. 中国科学院金属研究所. 中国科学院金属研究所,1990.
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