The effect of oxygen mobility/vacancy on carbon gasification in nano catalytic dry reforming of methane: A review | |
Rosli, Siti Nor Amira1; Abidin, Sumaiya Zainal2,3; Osazuwa, Osarieme Uyi2,4; Fan, Xiaolei5; Jiao, Yilai6 | |
Corresponding Author | Abidin, Sumaiya Zainal(sumaiya@ump.edu.my) |
2022-09-01 | |
Source Publication | JOURNAL OF CO2 UTILIZATION
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ISSN | 2212-9820 |
Volume | 63Pages:19 |
Abstract | Dry reforming of methane (DRM) remains challenging due to catalyst deactivation driven primarily by carbon deposition and metal sintering. Nanocatalytic materials offer great activity and stability in the DRM reaction due to the high dispersion of ultrasmall metal nanoparticles. Here we present a designated review on the role of the catalyst's oxygen mobility/vacancy in carbon gasification during the DRM reaction. The presence of mobile oxygen and/or oxygen vacancy in nanocatalysts is significantly beneficial to react with the deposited carbon insitu during the DRM reaction. This review first discusses the state-of-the-art nanocatalysts being applied in the DRM reaction. Then, the effects of the type and physicochemical properties of the nanocatalysts on their catalytic performance in the DRM are outlined, followed by the elaboration of carbon gasification route/mechanism in the DRM reaction. Finally, a critical discussion on the kinetics of carbon gasification is detailed. This review can serve as a current knowledge base to encourage the continuous development of in-depth study of this promising catalytic field, especially the development of active yet stable nanocatalysts, which can contribute to valorization of carbon emissions. |
Keyword | Methane Dry reforming Nanocatalyst Carbon Syngas Oxygen mobility |
Funding Organization | Universiti Malaysia Pahang, Malaysia ; Post Graduate Research Grant Scheme |
DOI | 10.1016/j.jcou.2022.102109 |
Indexed By | SCI |
Language | 英语 |
Funding Project | Universiti Malaysia Pahang, Malaysia[RDU203304] ; Post Graduate Research Grant Scheme[PGRS210382] |
WOS Research Area | Chemistry ; Engineering |
WOS Subject | Chemistry, Multidisciplinary ; Engineering, Chemical |
WOS ID | WOS:000827278300003 |
Publisher | ELSEVIER SCI LTD |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.imr.ac.cn/handle/321006/174678 |
Collection | 中国科学院金属研究所 |
Corresponding Author | Abidin, Sumaiya Zainal |
Affiliation | 1.Univ Malaysia Pahang, Kuantan 26300, Pahang, Malaysia 2.Univ Malaysia Pahang, Ctr Res Adv Fluid & Proc, Lebuhraya Tun Razak,Gambang, Kuantan 26300, Pahang, Malaysia 3.Ind Univ Ho Chi Minh City, Fac Chem Engn, 12 Nguyen Bao St,Go Vap Dist, Ho Chi Minh City, Vietnam 4.Univ Benin, Dept Chem Engn, PMB 1154, Benin, Edo, Nigeria 5.Univ Manchester, Sch Engn, Dept Chem Engn, Oxford Rd, Manchester M13 9PL, Lancashire, United Kingdom 6.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Peoples R China |
Recommended Citation GB/T 7714 | Rosli, Siti Nor Amira,Abidin, Sumaiya Zainal,Osazuwa, Osarieme Uyi,et al. The effect of oxygen mobility/vacancy on carbon gasification in nano catalytic dry reforming of methane: A review[J]. JOURNAL OF CO2 UTILIZATION,2022,63:19. |
APA | Rosli, Siti Nor Amira,Abidin, Sumaiya Zainal,Osazuwa, Osarieme Uyi,Fan, Xiaolei,&Jiao, Yilai.(2022).The effect of oxygen mobility/vacancy on carbon gasification in nano catalytic dry reforming of methane: A review.JOURNAL OF CO2 UTILIZATION,63,19. |
MLA | Rosli, Siti Nor Amira,et al."The effect of oxygen mobility/vacancy on carbon gasification in nano catalytic dry reforming of methane: A review".JOURNAL OF CO2 UTILIZATION 63(2022):19. |
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