The effect of oxygen mobility/vacancy on carbon gasification in nano catalytic dry reforming of methane: A review | |
Rosli, Siti Nor Amira1; Abidin, Sumaiya Zainal2,3; Osazuwa, Osarieme Uyi2,4; Fan, Xiaolei5; Jiao, Yilai6 | |
通讯作者 | Abidin, Sumaiya Zainal(sumaiya@ump.edu.my) |
2022-09-01 | |
发表期刊 | JOURNAL OF CO2 UTILIZATION
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ISSN | 2212-9820 |
卷号 | 63页码:19 |
摘要 | Dry reforming of methane (DRM) remains challenging due to catalyst deactivation driven primarily by carbon deposition and metal sintering. Nanocatalytic materials offer great activity and stability in the DRM reaction due to the high dispersion of ultrasmall metal nanoparticles. Here we present a designated review on the role of the catalyst's oxygen mobility/vacancy in carbon gasification during the DRM reaction. The presence of mobile oxygen and/or oxygen vacancy in nanocatalysts is significantly beneficial to react with the deposited carbon insitu during the DRM reaction. This review first discusses the state-of-the-art nanocatalysts being applied in the DRM reaction. Then, the effects of the type and physicochemical properties of the nanocatalysts on their catalytic performance in the DRM are outlined, followed by the elaboration of carbon gasification route/mechanism in the DRM reaction. Finally, a critical discussion on the kinetics of carbon gasification is detailed. This review can serve as a current knowledge base to encourage the continuous development of in-depth study of this promising catalytic field, especially the development of active yet stable nanocatalysts, which can contribute to valorization of carbon emissions. |
关键词 | Methane Dry reforming Nanocatalyst Carbon Syngas Oxygen mobility |
资助者 | Universiti Malaysia Pahang, Malaysia ; Post Graduate Research Grant Scheme |
DOI | 10.1016/j.jcou.2022.102109 |
收录类别 | SCI |
语种 | 英语 |
资助项目 | Universiti Malaysia Pahang, Malaysia[RDU203304] ; Post Graduate Research Grant Scheme[PGRS210382] |
WOS研究方向 | Chemistry ; Engineering |
WOS类目 | Chemistry, Multidisciplinary ; Engineering, Chemical |
WOS记录号 | WOS:000827278300003 |
出版者 | ELSEVIER SCI LTD |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/174678 |
专题 | 中国科学院金属研究所 |
通讯作者 | Abidin, Sumaiya Zainal |
作者单位 | 1.Univ Malaysia Pahang, Kuantan 26300, Pahang, Malaysia 2.Univ Malaysia Pahang, Ctr Res Adv Fluid & Proc, Lebuhraya Tun Razak,Gambang, Kuantan 26300, Pahang, Malaysia 3.Ind Univ Ho Chi Minh City, Fac Chem Engn, 12 Nguyen Bao St,Go Vap Dist, Ho Chi Minh City, Vietnam 4.Univ Benin, Dept Chem Engn, PMB 1154, Benin, Edo, Nigeria 5.Univ Manchester, Sch Engn, Dept Chem Engn, Oxford Rd, Manchester M13 9PL, Lancashire, United Kingdom 6.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Peoples R China |
推荐引用方式 GB/T 7714 | Rosli, Siti Nor Amira,Abidin, Sumaiya Zainal,Osazuwa, Osarieme Uyi,et al. The effect of oxygen mobility/vacancy on carbon gasification in nano catalytic dry reforming of methane: A review[J]. JOURNAL OF CO2 UTILIZATION,2022,63:19. |
APA | Rosli, Siti Nor Amira,Abidin, Sumaiya Zainal,Osazuwa, Osarieme Uyi,Fan, Xiaolei,&Jiao, Yilai.(2022).The effect of oxygen mobility/vacancy on carbon gasification in nano catalytic dry reforming of methane: A review.JOURNAL OF CO2 UTILIZATION,63,19. |
MLA | Rosli, Siti Nor Amira,et al."The effect of oxygen mobility/vacancy on carbon gasification in nano catalytic dry reforming of methane: A review".JOURNAL OF CO2 UTILIZATION 63(2022):19. |
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