Effective Ensemble of Pt Single Atoms and Clusters over the (Ni,Co)(OH)(2) Substrate Catalyzes Highly Selective, Efficient, and Stable Hydrogenation Reactions

doi:10.1021/acscatal.2c01901

IMR OpenIR

	Effective Ensemble of Pt Single Atoms and Clusters over the (Ni,Co)(OH)(2) Substrate Catalyzes Highly Selective, Efficient, and Stable Hydrogenation Reactions
	Zhu, Lihua 3,4,7; Sun, Yilun 1; Zhu, Huaze ; Chai, Guoliang 1; Yang, Zhiqing 2; Shang, Congxiao 3,4; Ye, Hengqiang 2; Chen, Bing Hui 5; Kroner, Anna 6; Guo, Zhengxiao 3,4
通讯作者	Zhu, Lihua(zhulihua@jxust.edu.cn) ; Chai, Guoliang(g.chai@fjirsm.ac.cn) ; Yang, Zhiqing(yangzq@imr.ac.cn) ; Guo, Zhengxiao(zxguo@hku.hk)
	2022-06-22
发表期刊	ACS CATALYSIS
ISSN	2155-5435
页码	8104-8115
摘要	A Pt-Ni-Co catalyst was synthesized with Pt single atoms and atomic clusters (SAACs) dispersed over (Ni,Co)(OH)(2) nanoparticles on a carbon matrix, which leads to high catalytic activity, up to 100% conversion, and selectivity in the hydrogenation of nitroaromatics under moderate conditions (H-2 similar to 1.0 MPa and <= 40 degrees C). A synergistically coordinated ensemble effect of the Pt SAACs is identified with the strongly polarized Pt single atoms preferentially adsorbing the -NO2 and the Pt clusters adsorbing and homolytically dissociating H-2 molecules, and the H species then readily move to the adsorbed -NO2 group, overcoming a much reduced energy barrier on the (Ni,Co)(OH)(2), enhancing the reaction rate by ca. 50 times. The approach not only reveals the coordinated ensemble catalysis mechanism of SAACs but also provides a strategy of developing highly efficient and selective catalysts by fine tuning of the electronic microenvironment from single atoms to atomic clusters co-located over a multimetallic substrate. The demonstrated case for nitroarenes can be readily applied for other species containing -NO2 or other easily hydrogenated groups (such as C=C, C Z, and C=O).
关键词	Pt single atoms and atomic clusters (SAACs) (Ni,Co)(OH)(2) nanoparticles hydrogenation reactions synergistic effect hydrogen spillover
资助者	National Natural Science Foundation of China ; Youth Jinggang Scholars Program in Jiangxi Province ; Program of Technology Innovation Talents of Ganzhou ; Research Fund Program of Key Laboratory of Fuel Cell Technology of Guangdong Province ; Guangdong Provincial Key RD Program ; National Key Research and Development Program of China ; Horizon 2020 Research and Innovation Program ; HKU Start-Up Fund ; HK Scholars Program ; EU/RGC Research and Innovation Cooperation Co-Funding Mechanism
DOI	10.1021/acscatal.2c01901
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[22162012] ; National Natural Science Foundation of China[21703248] ; Youth Jinggang Scholars Program in Jiangxi Province[[2019]57] ; Program of Technology Innovation Talents of Ganzhou ; Research Fund Program of Key Laboratory of Fuel Cell Technology of Guangdong Province ; Guangdong Provincial Key RD Program[2020B0101370003] ; National Key Research and Development Program of China[2017YFA0700103] ; National Key Research and Development Program of China[2018YFA0704502] ; Horizon 2020 Research and Innovation Program[862296-SABYDOMA] ; HKU Start-Up Fund ; HK Scholars Program ; EU/RGC Research and Innovation Cooperation Co-Funding Mechanism[RGC: E-HKU704/19]
WOS研究方向	Chemistry
WOS类目	Chemistry, Physical
WOS记录号	WOS:000819457800001
出版者	AMER CHEMICAL SOC
引用统计	被引频次：23[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/174808
专题	中国科学院金属研究所
通讯作者	Zhu, Lihua; Chai, Guoliang; Yang, Zhiqing; Guo, Zhengxiao
作者单位	1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 3.Univ Hong Kong, HKU CAS Joint Lab New Mat, Hong Kong, Peoples R China 4.Univ Hong Kong, Dept Chem, Hong Kong, Peoples R China 5.Xiamen Univ, Coll Chem & Chem Engn, Natl Engn Lab Green Prod Alcohols Ethers Esters, Dept Chem & Biochem Engn, Xiamen 361005, Peoples R China 6.Diamond Light Source, Chilton OX11 0DE, Oxfordsshire, England 7.Jiangxi Univ Sci & Technol, Fac Mat Met & Chem, Coll Chem & Chem Engn, Ganzhou Jiang Xi 341000, Peoples R China
推荐引用方式 GB/T 7714	Zhu, Lihua,Sun, Yilun,Zhu, Huaze,et al. Effective Ensemble of Pt Single Atoms and Clusters over the (Ni,Co)(OH)(2) Substrate Catalyzes Highly Selective, Efficient, and Stable Hydrogenation Reactions[J]. ACS CATALYSIS,2022:8104-8115.
APA	Zhu, Lihua.,Sun, Yilun.,Zhu, Huaze.,Chai, Guoliang.,Yang, Zhiqing.,...&Guo, Zhengxiao.(2022).Effective Ensemble of Pt Single Atoms and Clusters over the (Ni,Co)(OH)(2) Substrate Catalyzes Highly Selective, Efficient, and Stable Hydrogenation Reactions.ACS CATALYSIS,8104-8115.
MLA	Zhu, Lihua,et al."Effective Ensemble of Pt Single Atoms and Clusters over the (Ni,Co)(OH)(2) Substrate Catalyzes Highly Selective, Efficient, and Stable Hydrogenation Reactions".ACS CATALYSIS (2022):8104-8115.