Schottky heterojunction-assisted photocatalytic hydrogen evolution by ZnIn2S4/Co3S4 hollow leaves derived from Co-ZIF-L

doi:10.1002/aoc.6874

IMR OpenIR

	Schottky heterojunction-assisted photocatalytic hydrogen evolution by ZnIn2S4/Co3S4 hollow leaves derived from Co-ZIF-L
	Song, Huihui 1; Sun, Zhongqiao 1; Chai, Ning 1; Han, Yide 1; Xu, Yan 1; Meng, Hao 1; Sun, Ting 1; Zhang, Bingsen 2; Zhang, Xia 1
通讯作者	Zhang, Bingsen(bszhang@imr.ac.cn) ; Zhang, Xia(xzhang@mail.neu.edu.cn)
	2022-09-06
发表期刊	APPLIED ORGANOMETALLIC CHEMISTRY
ISSN	0268-2605
页码	13
摘要	The hetero-photocatalysts in hollow structure may provide more dispersive reactive sites, the easily accessible open channel for substrates and the intensive visible light harvest ability, which have shown evidently promoting photocatalytic efficiency. Herein, a novel photocatalyst ZIS/Co(3)S(4)HLs in hierarchical hollow heterostructure has been constructed by epitaxially growing 2D ZnIn2S4 (ZIS) nanosheets on Co-ZIF-L-derived Co3S4 hollow leaves (Co(3)S(4)HLs). The formation of the Schottky junction has promoted the photogenerated charges transfer, which is well proven by the electrochemical analyses and the DFT calculation. It is suggested that both constructed hierarchical hollow heterostructure and the Schottky junction with well-matched band potentials are responsible for the remarkable H-2 evolution rates under the visible light irradiation, which are much higher than most of the reported results by other ZIS-based composite photocatalysts. The good cyclic photocatalytic activity and structural stability of these hierarchical hollow leaves provide new insight into designing a high-efficient heterostructure being used in solar energy conversion.
关键词	Co3S4 hollow leaves hierarchical hollow heterostructure photocatalytic hydrogen evolution Schottky junction ZnIn2S4
资助者	SYNL; LiaoNing Revitalization Talents Program ; Liao Ning Science and Technology Development Foundation Guided by Central Government
DOI	10.1002/aoc.6874
收录类别	SCI
语种	英语
资助项目	SYNL; LiaoNing Revitalization Talents Program[XLYC1807175] ; Liao Ning Science and Technology Development Foundation Guided by Central Government[2021JH6/10500141]
WOS研究方向	Chemistry
WOS类目	Chemistry, Applied ; Chemistry, Inorganic & Nuclear
WOS记录号	WOS:000850484300001
出版者	WILEY
引用统计	被引频次：6[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/175062
专题	中国科学院金属研究所
通讯作者	Zhang, Bingsen; Zhang, Xia
作者单位	1.Northeastern Univ, Coll Sci, Dept Chem, Shenyang 110819, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China
推荐引用方式 GB/T 7714	Song, Huihui,Sun, Zhongqiao,Chai, Ning,et al. Schottky heterojunction-assisted photocatalytic hydrogen evolution by ZnIn2S4/Co3S4 hollow leaves derived from Co-ZIF-L[J]. APPLIED ORGANOMETALLIC CHEMISTRY,2022:13.
APA	Song, Huihui.,Sun, Zhongqiao.,Chai, Ning.,Han, Yide.,Xu, Yan.,...&Zhang, Xia.(2022).Schottky heterojunction-assisted photocatalytic hydrogen evolution by ZnIn2S4/Co3S4 hollow leaves derived from Co-ZIF-L.APPLIED ORGANOMETALLIC CHEMISTRY,13.
MLA	Song, Huihui,et al."Schottky heterojunction-assisted photocatalytic hydrogen evolution by ZnIn2S4/Co3S4 hollow leaves derived from Co-ZIF-L".APPLIED ORGANOMETALLIC CHEMISTRY (2022):13.