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Leaching mechanism of strategic metals from superalloy scrap under ultrasonic cavitation
Wang, Long1; Sun, Yuan2,3; Wang, Shi-yang2,3; Zhang, Ting-an1; Lu, Guo-zhi1
通讯作者Sun, Yuan(yuansun@imr.ac.cn) ; Zhang, Ting-an(zta2000@163.net)
2023
发表期刊TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA
ISSN1003-6326
卷号33期号:1页码:304-314
摘要To improve the recovery efficiency of strategic metals from superalloy scrap, an ultrasonic-assisted leaching method was proposed. During the ultrasonic-assisted leaching process, at 60 min, the leaching rates of Re, Ni, Co, Al, Cr, and W are 92.3%, 95.2%, 98.5%, 98.7%, 97.5%, and 27.2%, respectively, which are far superior to those in the normal leaching process at 120 min. The improvement in leaching efficiency can be attributed to the physical and chemical coupling effects of ultrasonic cavitation. The physical effect can prevent the formation of the impeded dissolution layer and encourage contact between solution and superalloy scrap, which improves the leaching rates of strategic metals. The chemical effect can promote the production of hydroxyl radicals in the HCl-H2O2 system, which can enhance the potential of the leaching system, resulting in stimulation of the chemical oxidation process of Re to ReO4-.
关键词strategic metals superalloy scrap leaching ultrasonic-assisted leaching hydroxyl radical
资助者Chinese Academy of Sciences, China ; Science and Technology Project of Shen -Fu Reform and innovation Demonstration Zone, China ; National Natural Science Foundation of China
DOI10.1016/S1003-6326(22)66108-9
收录类别SCI
语种英语
资助项目Chinese Academy of Sciences, China[E055A101] ; Science and Technology Project of Shen -Fu Reform and innovation Demonstration Zone, China[2021JH15] ; National Natural Science Foundation of China[U1710257]
WOS研究方向Metallurgy & Metallurgical Engineering
WOS类目Metallurgy & Metallurgical Engineering
WOS记录号WOS:000923319900001
出版者ELSEVIER
引用统计
被引频次:5[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/175137
专题中国科学院金属研究所
通讯作者Sun, Yuan; Zhang, Ting-an
作者单位1.Northeastern Univ, Key Lab Ecol Utilizat Multimet Mineral, Minist Educ, Shenyang 110819, Peoples R China
2.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Peoples R China
3.Joint Innovat Lab Green Comprehens Utilizat Supera, Shenyang 110016, Peoples R China
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GB/T 7714
Wang, Long,Sun, Yuan,Wang, Shi-yang,et al. Leaching mechanism of strategic metals from superalloy scrap under ultrasonic cavitation[J]. TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA,2023,33(1):304-314.
APA Wang, Long,Sun, Yuan,Wang, Shi-yang,Zhang, Ting-an,&Lu, Guo-zhi.(2023).Leaching mechanism of strategic metals from superalloy scrap under ultrasonic cavitation.TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA,33(1),304-314.
MLA Wang, Long,et al."Leaching mechanism of strategic metals from superalloy scrap under ultrasonic cavitation".TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA 33.1(2023):304-314.
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