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Leaching mechanism of strategic metals from superalloy scrap under ultrasonic cavitation
Wang, Long1; Sun, Yuan2,3; Wang, Shi-yang2,3; Zhang, Ting-an1; Lu, Guo-zhi1
Corresponding AuthorSun, Yuan(yuansun@imr.ac.cn) ; Zhang, Ting-an(zta2000@163.net)
2023
Source PublicationTRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA
ISSN1003-6326
Volume33Issue:1Pages:304-314
AbstractTo improve the recovery efficiency of strategic metals from superalloy scrap, an ultrasonic-assisted leaching method was proposed. During the ultrasonic-assisted leaching process, at 60 min, the leaching rates of Re, Ni, Co, Al, Cr, and W are 92.3%, 95.2%, 98.5%, 98.7%, 97.5%, and 27.2%, respectively, which are far superior to those in the normal leaching process at 120 min. The improvement in leaching efficiency can be attributed to the physical and chemical coupling effects of ultrasonic cavitation. The physical effect can prevent the formation of the impeded dissolution layer and encourage contact between solution and superalloy scrap, which improves the leaching rates of strategic metals. The chemical effect can promote the production of hydroxyl radicals in the HCl-H2O2 system, which can enhance the potential of the leaching system, resulting in stimulation of the chemical oxidation process of Re to ReO4-.
Keywordstrategic metals superalloy scrap leaching ultrasonic-assisted leaching hydroxyl radical
Funding OrganizationChinese Academy of Sciences, China ; Science and Technology Project of Shen -Fu Reform and innovation Demonstration Zone, China ; National Natural Science Foundation of China
DOI10.1016/S1003-6326(22)66108-9
Indexed BySCI
Language英语
Funding ProjectChinese Academy of Sciences, China[E055A101] ; Science and Technology Project of Shen -Fu Reform and innovation Demonstration Zone, China[2021JH15] ; National Natural Science Foundation of China[U1710257]
WOS Research AreaMetallurgy & Metallurgical Engineering
WOS SubjectMetallurgy & Metallurgical Engineering
WOS IDWOS:000923319900001
PublisherELSEVIER
Citation statistics
Cited Times:5[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/175137
Collection中国科学院金属研究所
Corresponding AuthorSun, Yuan; Zhang, Ting-an
Affiliation1.Northeastern Univ, Key Lab Ecol Utilizat Multimet Mineral, Minist Educ, Shenyang 110819, Peoples R China
2.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Peoples R China
3.Joint Innovat Lab Green Comprehens Utilizat Supera, Shenyang 110016, Peoples R China
Recommended Citation
GB/T 7714
Wang, Long,Sun, Yuan,Wang, Shi-yang,et al. Leaching mechanism of strategic metals from superalloy scrap under ultrasonic cavitation[J]. TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA,2023,33(1):304-314.
APA Wang, Long,Sun, Yuan,Wang, Shi-yang,Zhang, Ting-an,&Lu, Guo-zhi.(2023).Leaching mechanism of strategic metals from superalloy scrap under ultrasonic cavitation.TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA,33(1),304-314.
MLA Wang, Long,et al."Leaching mechanism of strategic metals from superalloy scrap under ultrasonic cavitation".TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA 33.1(2023):304-314.
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