Defect anchoring of atomically dispersed Pd on nitrogen-doped holey carbon nanotube for catalytic hydrogenation of nitroarenes

doi:10.1016/j.apsusc.2023.156344

IMR OpenIR

	Defect anchoring of atomically dispersed Pd on nitrogen-doped holey carbon nanotube for catalytic hydrogenation of nitroarenes
	Huang, Jie 1; Li, Xiaozhi 1; Xie, Rui-Hong 3,4; Tan, Xinglong 1; Xi, Jiangbo 1; Tian, Fan 1; Liu, Pei 2; Hansen, Thomas Willum 2; Bai, Zheng-Wu 1
通讯作者	Xi, Jiangbo(jbxi@wit.edu.cn) ; Tian, Fan(tf@wit.edu.cn) ; Liu, Pei(peiliu@dtu.dk)
	2023-04-01
发表期刊	APPLIED SURFACE SCIENCE
ISSN	0169-4332
卷号	615 页码:8
摘要	High-density dispersion and efficient exposure of active metal sites are crucial for enhancing the catalytic activity of metal-based heterogeneous catalysts and improving the utilization of precious metal atoms. Increasing the surface to volume ratio by decreasing the size of metal nanoparticles is considered an ideal and straightforward strategy to increase catalytic activity. However, the generation of stable metal clusters or even single-atom metal species on supports is challenging since metal atoms are prone to agglomerate. In this work, we report a facile and practical method to anchor atomically dispersed Pd on an N-doped holey carbon nanotube (Pd/NHCNT) by efficiently strengthening metal-support interaction. Due to the unique characteristics of defected NHCNT sup-port, highly dispersed Pd clusters and single atoms can be facilely introduced and anchored onto NHCNT. The resultant Pd/NHCNT catalyst exhibits a remarkable activity for nitroarenes hydrogenation with a turnover fre-quency as high as 1091.49 min-1, which surpasses the reported noble metal-based catalysts. Furthermore, theoretical simulations are applied for the understanding of the defect anchoring of atomically Pd and the interaction between active sites and substrate. The defect-induced anchoring approach provides a new avenue for designing and preparing other highly active atomic metal catalysts with high metal dispersion and can be applied to diverse organic reactions.
关键词	Defect-induction strategy Carbon nanotube Nitrogen doping Atomically dispersed palladium Nitroarene hydrogenation
资助者	Key Research and Development Program of Hubei Province ; Major Project of Hubei Provincial Department of Education ; Open Project of Ministry-of-Education Key Laboratory for Green Preparation and Application of Functional Materials ; Carlsberg Foundation ; Science Foundation of Wuhan Institute of Technology ; Open/Innovation Project of Key Laboratory of Novel Biomass-Based Environmental and Energy Materials in Petroleum and Chemical Industry
DOI	10.1016/j.apsusc.2023.156344
收录类别	SCI
语种	英语
资助项目	Key Research and Development Program of Hubei Province[2022BAA026] ; Major Project of Hubei Provincial Department of Education[D20211502] ; Open Project of Ministry-of-Education Key Laboratory for Green Preparation and Application of Functional Materials ; Carlsberg Foundation[CF20-0612] ; Science Foundation of Wuhan Institute of Technology[K2021072] ; Open/Innovation Project of Key Laboratory of Novel Biomass-Based Environmental and Energy Materials in Petroleum and Chemical Industry[2022BEEA06]
WOS研究方向	Chemistry ; Materials Science ; Physics
WOS类目	Chemistry, Physical ; Materials Science, Coatings & Films ; Physics, Applied ; Physics, Condensed Matter
WOS记录号	WOS:000923743000001
出版者	ELSEVIER
引用统计	被引频次：36[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/175191
专题	中国科学院金属研究所
通讯作者	Xi, Jiangbo; Tian, Fan; Liu, Pei
作者单位	1.Wuhan Inst Technol, Engn Res Ctr Phosphorus Resources Dev, Sch Chem & Environm Engn, Key Lab Novel Biomass Based Environm & Energy Mat, Wuhan 430073, Peoples R China 2.DTU Nanolab Tech Univ Denmark, Fysikvej 2800 kgs, DK-2800 Lyngby, Denmark 3.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 4.Univ Sci & Technol China, Sch Mat Sci & Engn, Hefei 230026, Peoples R China
推荐引用方式 GB/T 7714	Huang, Jie,Li, Xiaozhi,Xie, Rui-Hong,et al. Defect anchoring of atomically dispersed Pd on nitrogen-doped holey carbon nanotube for catalytic hydrogenation of nitroarenes[J]. APPLIED SURFACE SCIENCE,2023,615:8.
APA	Huang, Jie.,Li, Xiaozhi.,Xie, Rui-Hong.,Tan, Xinglong.,Xi, Jiangbo.,...&Bai, Zheng-Wu.(2023).Defect anchoring of atomically dispersed Pd on nitrogen-doped holey carbon nanotube for catalytic hydrogenation of nitroarenes.APPLIED SURFACE SCIENCE,615,8.
MLA	Huang, Jie,et al."Defect anchoring of atomically dispersed Pd on nitrogen-doped holey carbon nanotube for catalytic hydrogenation of nitroarenes".APPLIED SURFACE SCIENCE 615(2023):8.