Synthesis process and adsorption performance of temperature-sensitive ion-imprinted porous microspheres (ReO4--TIIM) for the selective separation of ReO4-

doi:10.1039/d2nj05400k

IMR OpenIR

	Synthesis process and adsorption performance of temperature-sensitive ion-imprinted porous microspheres (ReO4--TIIM) for the selective separation of ReO4-
	Niu, Fangfang 1,2; Xu, Wan 1,2; Wu, Gang 1,2; Lu, Siyuan 1,2; Ou, Xiaojian 3; Chen, Zhenbin 1,2; Zhao, Xinyu 1,2; Sun, Yuan 4; Song, Yuanjun 3; Zhang, Peng 3
通讯作者	Chen, Zhenbin(zhenbinchen@163.com)
	2023-01-30
发表期刊	NEW JOURNAL OF CHEMISTRY
ISSN	1144-0546
卷号	47 期号:5 页码:2604-2618
摘要	Ion imprinted polymers (IPs) are very promising for separation processes because of their intended selectivity. However, the trade-off between their selectivity and desorption leads to difficulties in reusing them, which seriously hampers their development. Herein, we design ReO4- temperature sensitive ion-imprinted porous microspheres (ReO4--TIIM) for the selective separation of ReO4- from aqueous solutions. The introduction of the temperature-sensitive block polymer PDEA-b-P(DEA-co-AM) allowed for a highly controlled blotting site in the ReO4--TIIM matrix, maintaining a high balance of selectivity and desorption. Pickering emulsion polymerization was used to provide the ReO4--TIIM with a porous and interoperable structure, thereby enhancing their mass transfer rate and adsorption performance. The adsorption properties of ReO4--TIIM prepared under optimum process conditions were investigated by adsorption kinetics and adsorption thermodynamics. FTIR, SEM, and BET-specific surface area analyses fully characterized their structure and morphology. The design of the ReO4--TIIM offers a new approach to the industrial precision separation of Re.
资助者	Natural Science Foundation of Gansu Province, China ; State Key Laboratory of Nickel and Cobalt Resources Comprehensive Utilization (China)
DOI	10.1039/d2nj05400k
收录类别	SCI
语种	英语
资助项目	Natural Science Foundation of Gansu Province, China[22JR5RA227] ; State Key Laboratory of Nickel and Cobalt Resources Comprehensive Utilization (China)[2019-16]
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000911809700001
出版者	ROYAL SOC CHEMISTRY
引用统计	被引频次：6[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/175392
专题	中国科学院金属研究所
通讯作者	Chen, Zhenbin
作者单位	1.Lanzhou Univ Technol, State Key Lab Gansu Adv Nonferrous Met Mat, Lanzhou, Gansu, Peoples R China 2.Lanzhou Univ Technol, Sch Mat Sci & Engn, Lanzhou, Gansu, Peoples R China 3.State Key Lab Nickel & Cobalt Resources Comprehens, Jinchang 737100, Gansu, Peoples R China 4.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Liaoning, Peoples R China
推荐引用方式 GB/T 7714	Niu, Fangfang,Xu, Wan,Wu, Gang,et al. Synthesis process and adsorption performance of temperature-sensitive ion-imprinted porous microspheres (ReO4--TIIM) for the selective separation of ReO4-[J]. NEW JOURNAL OF CHEMISTRY,2023,47(5):2604-2618.
APA	Niu, Fangfang.,Xu, Wan.,Wu, Gang.,Lu, Siyuan.,Ou, Xiaojian.,...&Zhang, Peng.(2023).Synthesis process and adsorption performance of temperature-sensitive ion-imprinted porous microspheres (ReO4--TIIM) for the selective separation of ReO4-.NEW JOURNAL OF CHEMISTRY,47(5),2604-2618.
MLA	Niu, Fangfang,et al."Synthesis process and adsorption performance of temperature-sensitive ion-imprinted porous microspheres (ReO4--TIIM) for the selective separation of ReO4-".NEW JOURNAL OF CHEMISTRY 47.5(2023):2604-2618.