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Synthesis process and adsorption performance of temperature-sensitive ion-imprinted porous microspheres (ReO4--TIIM) for the selective separation of ReO4-
Niu, Fangfang1,2; Xu, Wan1,2; Wu, Gang1,2; Lu, Siyuan1,2; Ou, Xiaojian3; Chen, Zhenbin1,2; Zhao, Xinyu1,2; Sun, Yuan4; Song, Yuanjun3; Zhang, Peng3
Corresponding AuthorChen, Zhenbin(zhenbinchen@163.com)
2023-01-30
Source PublicationNEW JOURNAL OF CHEMISTRY
ISSN1144-0546
Volume47Issue:5Pages:2604-2618
AbstractIon imprinted polymers (IPs) are very promising for separation processes because of their intended selectivity. However, the trade-off between their selectivity and desorption leads to difficulties in reusing them, which seriously hampers their development. Herein, we design ReO4- temperature sensitive ion-imprinted porous microspheres (ReO4--TIIM) for the selective separation of ReO4- from aqueous solutions. The introduction of the temperature-sensitive block polymer PDEA-b-P(DEA-co-AM) allowed for a highly controlled blotting site in the ReO4--TIIM matrix, maintaining a high balance of selectivity and desorption. Pickering emulsion polymerization was used to provide the ReO4--TIIM with a porous and interoperable structure, thereby enhancing their mass transfer rate and adsorption performance. The adsorption properties of ReO4--TIIM prepared under optimum process conditions were investigated by adsorption kinetics and adsorption thermodynamics. FTIR, SEM, and BET-specific surface area analyses fully characterized their structure and morphology. The design of the ReO4--TIIM offers a new approach to the industrial precision separation of Re.
Funding OrganizationNatural Science Foundation of Gansu Province, China ; State Key Laboratory of Nickel and Cobalt Resources Comprehensive Utilization (China)
DOI10.1039/d2nj05400k
Indexed BySCI
Language英语
Funding ProjectNatural Science Foundation of Gansu Province, China[22JR5RA227] ; State Key Laboratory of Nickel and Cobalt Resources Comprehensive Utilization (China)[2019-16]
WOS Research AreaChemistry
WOS SubjectChemistry, Multidisciplinary
WOS IDWOS:000911809700001
PublisherROYAL SOC CHEMISTRY
Citation statistics
Cited Times:3[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/175392
Collection中国科学院金属研究所
Corresponding AuthorChen, Zhenbin
Affiliation1.Lanzhou Univ Technol, State Key Lab Gansu Adv Nonferrous Met Mat, Lanzhou, Gansu, Peoples R China
2.Lanzhou Univ Technol, Sch Mat Sci & Engn, Lanzhou, Gansu, Peoples R China
3.State Key Lab Nickel & Cobalt Resources Comprehens, Jinchang 737100, Gansu, Peoples R China
4.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Liaoning, Peoples R China
Recommended Citation
GB/T 7714
Niu, Fangfang,Xu, Wan,Wu, Gang,et al. Synthesis process and adsorption performance of temperature-sensitive ion-imprinted porous microspheres (ReO4--TIIM) for the selective separation of ReO4-[J]. NEW JOURNAL OF CHEMISTRY,2023,47(5):2604-2618.
APA Niu, Fangfang.,Xu, Wan.,Wu, Gang.,Lu, Siyuan.,Ou, Xiaojian.,...&Zhang, Peng.(2023).Synthesis process and adsorption performance of temperature-sensitive ion-imprinted porous microspheres (ReO4--TIIM) for the selective separation of ReO4-.NEW JOURNAL OF CHEMISTRY,47(5),2604-2618.
MLA Niu, Fangfang,et al."Synthesis process and adsorption performance of temperature-sensitive ion-imprinted porous microspheres (ReO4--TIIM) for the selective separation of ReO4-".NEW JOURNAL OF CHEMISTRY 47.5(2023):2604-2618.
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