Determining the contribution of Mo single atoms components in MoO2 nanocatalyst in transfer hydrogenation

doi:10.1007/s12274-022-5277-3

IMR OpenIR

	Determining the contribution of Mo single atoms components in MoO2 nanocatalyst in transfer hydrogenation
	Hu, Ze-Nan 1,2; Ai, Yongjian 3; Zhao, Yan 4; Wang, Yiming 2; Ding, Kelong 2; Zhang, Wenhui 2; Guo, Rongxiu 2; Zhang, Xinyue 2; Cai, Xiangbin 5; Wang, Ning 5; Hu, Jianshe 2; Liang, Qionglin 3; Liu, Hongyang 6; Huang, Fei 6; Wu, Limin 4; Zhang, Jiangwei 4; Sun, Hong-bin 2
通讯作者	Huang, Fei(fhuang17b@imr.ac.cn) ; Zhang, Jiangwei(jwz@imu.edu.cn) ; Sun, Hong-bin(sunhb@mail.neu.edu.cn)
	2022-12-13
发表期刊	NANO RESEARCH
ISSN	1998-0124
页码	9
摘要	Nanocatalysts are likely to contain undetected single-atom components, which may have been ignored but have significant effect in catalytic reactions. Herein, we report a catalyst composed of Mo single atoms (SAs) and MoO2 nanoparticles (NPs) (Mo-SAs-MoO2@NC), which is an exact model to understand how the SAs contribute to the nanocatalyst. Both experimental results and the density functional theory calculations reveal that Mo SAs on nitrogen-doped carbon provides the reaction zone for nitro reduction, while MoO2 is the active site for decomposing hydrazine hydrate to produce H-?. Thanks to the synergy between Mo SAs and MoO2 NPs, this catalyst exhibits noble metal-like catalytic activity (100% conversion at 4 min) for the dechlorination-proof transfer hydrogenation. Additionally, the hydrogen migration on the catalyst is verified by the electrochemical tests in the absence of a hydrogen source. This work provides a model for further study on the coexistence of single atoms in nanoparticle catalysts.
关键词	synergistic effect Mo single atoms MoO2 nanocatalyst transfer hydrogenation nitroarenes
资助者	National Key R&D Program of China ; National Natural Science Foundation of China ; Liaoning Revitalization Talents Program ; Natural Science Foundation of Liaoning Province ; Dalian National Lab for Clean Energy (DNL Cooperation Fund) ; Dalian high level talent innovation project
DOI	10.1007/s12274-022-5277-3
收录类别	SCI
语种	英语
资助项目	National Key R&D Program of China[2021YFA1502802] ; National Key R&D Program of China[2020YFA0406101] ; National Natural Science Foundation of China[21961160722] ; National Natural Science Foundation of China[21872020] ; National Natural Science Foundation of China[22072162] ; National Natural Science Foundation of China[91845201] ; National Natural Science Foundation of China[21701168] ; Liaoning Revitalization Talents Program[XLYC1907055] ; Natural Science Foundation of Liaoning Province[2021-MS-001] ; Dalian National Lab for Clean Energy (DNL Cooperation Fund)[202001] ; Dalian high level talent innovation project[2019RQ063]
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
WOS类目	Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied
WOS记录号	WOS:000898700700012
出版者	TSINGHUA UNIV PRESS
引用统计	被引频次：8[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/175589
专题	中国科学院金属研究所
通讯作者	Huang, Fei; Zhang, Jiangwei; Sun, Hong-bin
作者单位	1.Luoyang Inst Sci & Technol, Sch Environm Engn & Chem, Luoyang 471023, Peoples R China 2.Northeastern Univ, Dept Chem, Shenyang 110819, Peoples R China 3.Tsinghua Univ, Ctr Synthet & Syst Biol, Dept Chem, MOE Key Lab Bioorgan Phosphorus Chem & Chem Biol, Beijing 100084, Peoples R China 4.Inner Mongolia Univ, Coll Energy Mat & Chem, Hohhot 010021, Peoples R China 5.Hong Kong Univ Sci & Technol, Ctr Quantum Mat, Dept Phys, Clear Water Bay, Hong Kong, Peoples R China 6.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
推荐引用方式 GB/T 7714	Hu, Ze-Nan,Ai, Yongjian,Zhao, Yan,et al. Determining the contribution of Mo single atoms components in MoO2 nanocatalyst in transfer hydrogenation[J]. NANO RESEARCH,2022:9.
APA	Hu, Ze-Nan.,Ai, Yongjian.,Zhao, Yan.,Wang, Yiming.,Ding, Kelong.,...&Sun, Hong-bin.(2022).Determining the contribution of Mo single atoms components in MoO2 nanocatalyst in transfer hydrogenation.NANO RESEARCH,9.
MLA	Hu, Ze-Nan,et al."Determining the contribution of Mo single atoms components in MoO2 nanocatalyst in transfer hydrogenation".NANO RESEARCH (2022):9.