Ferric ion substitution renders cadmium metal-organic framework derivatives for modulated Li storage based on local oxidation active centers

doi:10.1039/d2dt03392e

IMR OpenIR

	Ferric ion substitution renders cadmium metal-organic framework derivatives for modulated Li storage based on local oxidation active centers
	Jiang, Wei 1,4; Gao, Baihui 1; Yan, Guosong 1; Xu, Shichong 3; Chu, Xianyu 1; Che, Guangbo 1,5; Liu, Bo 1; Lu, Ming 2,3; Liu, Chunbo 1,4
通讯作者	Liu, Bo(liubo1999@jlnu.edu.cn) ; Lu, Ming(luming@jlnu.edu.cn) ; Liu, Chunbo(chunboliu@jlnu.edu.cn)
	2022-12-07
发表期刊	DALTON TRANSACTIONS
ISSN	1477-9226
页码	9
摘要	In this work, a novel anionic Cd-MOF ([(CH3)(2)NH2](n)[Cd(HL)DMF](n)center dot 2nH(2)O center dot nDMF, H4L = 1,2,4,5-tetrakis[(4-carboxy)phenoxymethyl]benzene) was synthesized for the first time. As a precursor, it was utilized to obtain Fe@Cd-MOF crystals via the substitution of Fe3+ ions due to a negatively charged framework and free-coordinated carboxyl group. Fe3O4/Fe-embedded carbon-based materials (Fe@Cd-MOFD) were further constructed by deriving Fe@Cd-MOF at high temperatures. The derived Fe@Cd-MOFD showed a structure resembling a central city with metal redox centers embedded into a carbon matrix. The introduced Fe3+ ions formed a local nano-sized metal oxide upon annealing, and these derived carbon materials offered high electronic conductivity. These pushed Fe@Cd-MOFD to remarkable electrochemical performance with an initial discharge capacity of 1703.8 mA h g(-1). This work offers new insights into the fabrication of novel MOF-derived iron oxide hybrids for lithium storage.
资助者	National Natural Science Foundation ; Natural Science Foundation Project of Jilin Province ; Project of Human Resources and Social Security Department of Jilin Province ; Science and Technology Research Project of Education Department of Jilin Province ; Center of 11 Future Science, Jilin 11 Technology Co., Ltd.
DOI	10.1039/d2dt03392e
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation[21902060] ; Natural Science Foundation Project of Jilin Province[20210203105SF] ; Natural Science Foundation Project of Jilin Province[20210101117JC] ; Natural Science Foundation Project of Jilin Province[YDZJ202101ZYTS078] ; Natural Science Foundation Project of Jilin Province[YDZJ202102CXJD049] ; Natural Science Foundation Project of Jilin Province[20210101113JC] ; Project of Human Resources and Social Security Department of Jilin Province[2021Y019] ; Project of Human Resources and Social Security Department of Jilin Province[2021Z007] ; Science and Technology Research Project of Education Department of Jilin Province[JJKH20210453KJ] ; Science and Technology Research Project of Education Department of Jilin Province[JJKH20210449KJ] ; Center of 11 Future Science, Jilin 11 Technology Co., Ltd.
WOS研究方向	Chemistry
WOS类目	Chemistry, Inorganic & Nuclear
WOS记录号	WOS:000903309300001
出版者	ROYAL SOC CHEMISTRY
引用统计	被引频次：2[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/175837
专题	中国科学院金属研究所
通讯作者	Liu, Bo; Lu, Ming; Liu, Chunbo
作者单位	1.Jilin Normal Univ, Minist Educ, Key Lab Preparat & Applicat Environm Friendly Mat, Changchun 130103, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China 3.Jilin Normal Univ, Key Lab Funct Mat Phys, Joint Lab MXene Mat, Chem Minist Educ, Changchun 130103, Jilin, Peoples R China 4.Jilin Normal Univ, Coll Engn, Siping 136000, Peoples R China 5.Baicheng Normal Univ, Coll Chem, Baicheng 137000, Peoples R China
推荐引用方式 GB/T 7714	Jiang, Wei,Gao, Baihui,Yan, Guosong,et al. Ferric ion substitution renders cadmium metal-organic framework derivatives for modulated Li storage based on local oxidation active centers[J]. DALTON TRANSACTIONS,2022:9.
APA	Jiang, Wei.,Gao, Baihui.,Yan, Guosong.,Xu, Shichong.,Chu, Xianyu.,...&Liu, Chunbo.(2022).Ferric ion substitution renders cadmium metal-organic framework derivatives for modulated Li storage based on local oxidation active centers.DALTON TRANSACTIONS,9.
MLA	Jiang, Wei,et al."Ferric ion substitution renders cadmium metal-organic framework derivatives for modulated Li storage based on local oxidation active centers".DALTON TRANSACTIONS (2022):9.