The highly efficient electrocatalytic oxidation of 5-hydroxymethylfurfural on copper nanocrystalline/carbon hybrid catalysts: structure-function relations

doi:10.1039/d2cy01165d

IMR OpenIR

	The highly efficient electrocatalytic oxidation of 5-hydroxymethylfurfural on copper nanocrystalline/carbon hybrid catalysts: structure-function relations
	Lu, Xingyu 1,2; Qi, Ke 1,2; Wang, Di 1,2,3; Dai, Xueya 1,2; Qi, Wei 1,2
通讯作者	Qi, Wei(wqi@imr.ac.cn)
	2022-09-23
发表期刊	CATALYSIS SCIENCE & TECHNOLOGY
ISSN	2044-4753
页码	7
摘要	2,5-Furandicarboxylic acid (FDCA) is a high-value platform molecule that can replace the fossil derivative terephthalic acid in the synthesis of important chemicals. FDCA can be synthesized from the oxidation of the biomass derivative 5-hydroxymethylfurfural (HMF). In this study, we loaded Cu-based catalysts with different morphologies and chemical states on carbon paper, and it was found that the Cu nanocrystalline/carbon paper catalyst with a thin and scattered dendrite structure (Cu(NSD)/CP) exhibits the best performance for the electrooxidation of HMF (96% yield and 100% selectivity for FDCA), which is attributed to the fact that the Cu-0 and Cu1+ species in the catalyst are easily oxidized in situ to Cu2+ species, showing high catalytic activity during the reaction process. This paper highlights the importance of the identification of active sites and the rational design of catalysts based on structure-function relations.
资助者	NSFC of China ; Natural Science Foundation of Liaoning Province of China ; China Baowu Low Carbon Metallurgy Innovation
DOI	10.1039/d2cy01165d
收录类别	SCI
语种	英语
资助项目	NSFC of China[22072163] ; Natural Science Foundation of Liaoning Province of China[2020-YQ-02] ; China Baowu Low Carbon Metallurgy Innovation[Foudation-BWLCF202113]
WOS研究方向	Chemistry
WOS类目	Chemistry, Physical
WOS记录号	WOS:000865265600001
出版者	ROYAL SOC CHEMISTRY
引用统计	被引频次：9[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/176014
专题	中国科学院金属研究所
通讯作者	Qi, Wei
作者单位	1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China 2.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Liaoning, Peoples R China 3.Shenyang Pharmaceut Univ, Sch Pharm, Shenyang 110016, Peoples R China
推荐引用方式 GB/T 7714	Lu, Xingyu,Qi, Ke,Wang, Di,et al. The highly efficient electrocatalytic oxidation of 5-hydroxymethylfurfural on copper nanocrystalline/carbon hybrid catalysts: structure-function relations[J]. CATALYSIS SCIENCE & TECHNOLOGY,2022:7.
APA	Lu, Xingyu,Qi, Ke,Wang, Di,Dai, Xueya,&Qi, Wei.(2022).The highly efficient electrocatalytic oxidation of 5-hydroxymethylfurfural on copper nanocrystalline/carbon hybrid catalysts: structure-function relations.CATALYSIS SCIENCE & TECHNOLOGY,7.
MLA	Lu, Xingyu,et al."The highly efficient electrocatalytic oxidation of 5-hydroxymethylfurfural on copper nanocrystalline/carbon hybrid catalysts: structure-function relations".CATALYSIS SCIENCE & TECHNOLOGY (2022):7.