| Tunable high-performance microwave absorption of cobalt nanoparticles wrapped in N-self-doped carbon nanofibers at ultralow filler loadings | |
| Yan, Liang1; Xiang, Jun1; Guan, Guangguang2,3; Zhang, Haoyan1; Zhang, Yamei1; Zhang, Kaiyin4 | |
| Corresponding Author | Xiang, Jun(jxiang@just.edu.cn) ; Zhang, Kaiyin(zhangkaiyin@wuyiu.edu.cn) |
| 2023-02-05 | |
| Source Publication | JOURNAL OF ALLOYS AND COMPOUNDS
 |
| ISSN | 0925-8388 |
| Volume | 933Pages:14 |
| Abstract | Manufacturing lightweight, ultralow filler loading, broad bandwidth and highly efficient microwave absorbers is still a challenge. Herein, we have synthesized Co nanoparticles decorated N-self-doped carbon nanofibers (Co@NCNFs) composite by electrospinning followed by a two-step heat treatment and investigated its electromagnetic (EM) and microwave absorption performances under different filler contents (from 2.5 to 7.5 wt%) in paraffin wax matrix. It is found that the Co@NCNFs composite has strong ferromagnetism and moderate graphitization degree as well as abundant polar groups and defects, and Co nanoparticles encapsulated by graphitic carbon layers with sizes around 45-115 nm are uniformly dispersed in the NCNFs. With increasing the filler loading, the EM attenuation ability is gradually strengthened while the impedance matching level is just the opposite. The EM absorbing properties of the composites are more superior within 5.0 wt% Co@NCNFs loading owing to the synergy of improved impedance matching and satisfactory EM dissipation ability. Under an ultralow filler loading of 2.5 wt%, the optimal reflection loss (RL) can reach as strong as -49.3 dB at 17.83 GHz with a thin thickness of 1.61 mm and the maximum effective absorption bandwidth (EAB, RL < -10.0 dB) is as wide as 5.44 GHz (12.56-16.99 GHz) at 1.92 mm. When the filler loading is only 5.0 wt%, a minimum RL value of -52.3 dB is achieved at 6.36 GHz with the thickness of 3.03 mm and the maximum EAB is 4.64 GHz (13.36-18.00 GHz) at 1.42 mm. Compared to other Co/C composite absorbers, the as-prepared Co@NCNFs composite with well-designed constitute and structure demonstrates the better comprehensive absorption performance at a much lower filler loading. Therefore, the present Co@NCNFs may be more promising for practical applications as lightweight and high-performance EM wave absorbers especially in the medium and high frequency range. |
| Keyword | Carbon nanofibers Co nanoparticles Microwave absorption Filler loading Electrospinning |
| Funding Organization | National Natural Science Foundation of China ; Natural Science Foundation of Fujian Province ; Postgraduate Research & Practice Innovation Program of Jiangsu Province |
| DOI | 10.1016/j.jallcom.2022.167808 |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | National Natural Science Foundation of China[51271059] ; Natural Science Foundation of Fujian Province[2020J01393] ; Postgraduate Research & Practice Innovation Program of Jiangsu Province[KYCX22-3816] |
| WOS Research Area | Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering |
| WOS Subject | Chemistry, Physical ; Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering |
| WOS ID | WOS:000893661700002 |
| Publisher | ELSEVIER SCIENCE SA |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/176105 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Xiang, Jun; Zhang, Kaiyin |
| Affiliation | 1.Jiangsu Univ Sci & Technol, Sch Sci, Zhenjiang 212100, Peoples R China 2.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China 3.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 4.Wuyi Univ, Coll Mech & Elect Engn, Wuyishan 354300, Peoples R China |
| Recommended Citation GB/T 7714 | Yan, Liang,Xiang, Jun,Guan, Guangguang,et al. Tunable high-performance microwave absorption of cobalt nanoparticles wrapped in N-self-doped carbon nanofibers at ultralow filler loadings[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2023,933:14. |
| APA | Yan, Liang,Xiang, Jun,Guan, Guangguang,Zhang, Haoyan,Zhang, Yamei,&Zhang, Kaiyin.(2023).Tunable high-performance microwave absorption of cobalt nanoparticles wrapped in N-self-doped carbon nanofibers at ultralow filler loadings.JOURNAL OF ALLOYS AND COMPOUNDS,933,14. |
| MLA | Yan, Liang,et al."Tunable high-performance microwave absorption of cobalt nanoparticles wrapped in N-self-doped carbon nanofibers at ultralow filler loadings".JOURNAL OF ALLOYS AND COMPOUNDS 933(2023):14. |
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