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Effect of oxygen impurity on corrosion behavior of a Zr-based bulk metallic glass in 0.5 M H2SO4 and 0.5 M NaOH solutions
Jiang, J.1,2; Wang, Z. B.3; Zheng, Y. G.3; Li, Y.1
Corresponding AuthorWang, Z. B.(zbwang12s@imr.ac.cn) ; Li, Y.(liyi@imr.ac.cn)
2023
Source PublicationMATERIALS LETTERS
ISSN0167-577X
Volume330Pages:4
AbstractEffects of unavoidable oxygen impurity in industrial-grade Zr-based bulk metallic glasses (BMGs) on their properties are the issues that must be considered. The studies on oxygen-related corrosion behaviors of Zr-based BMGs are rarely reported. This paper aims to clarify the effects of oxygen impurity on corrosion of the as-cast Zr61Ti2Cu25Al12 BMGs in 0.5 M H2SO4 and 0.5 M NaOH solutions. The results show that oxygen impurity has no effects on the corrosion in 0.5 M H2SO4, but is unexpectedly beneficial for improving the corrosion resistance in 0.5 M NaOH by inhibiting the cathodic reaction. The latter phenomenon could be correlated with the oxygeninduced annihilation of free volume. The finding herein further confirms that oxygen impurity is not harmful, even beneficial, for corrosion resistance of industrial-grade Zr61Ti2Cu25Al12 BMGs.
KeywordAmorphous materials Corrosion Zr-based bulk metallic glass Oxygen impurity Electrochemistry
Funding OrganizationShenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences
DOI10.1016/j.matlet.2022.133231
Indexed BySCI
Language英语
Funding ProjectShenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences
WOS Research AreaMaterials Science ; Physics
WOS SubjectMaterials Science, Multidisciplinary ; Physics, Applied
WOS IDWOS:000867682800007
PublisherELSEVIER
Citation statistics
Cited Times:2[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/176144
Collection中国科学院金属研究所
Corresponding AuthorWang, Z. B.; Li, Y.
Affiliation1.Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, Shenyang 110016, Peoples R China
2.Univ Sci & Technol China, Sch Mat Sci & Engn, Hefei 230026, Peoples R China
3.Chinese Acad Sci, Inst Met Res, CAS Key Lab Nucl Mat & Safety Assessment, Shenyang 110016, Peoples R China
Recommended Citation
GB/T 7714
Jiang, J.,Wang, Z. B.,Zheng, Y. G.,et al. Effect of oxygen impurity on corrosion behavior of a Zr-based bulk metallic glass in 0.5 M H2SO4 and 0.5 M NaOH solutions[J]. MATERIALS LETTERS,2023,330:4.
APA Jiang, J.,Wang, Z. B.,Zheng, Y. G.,&Li, Y..(2023).Effect of oxygen impurity on corrosion behavior of a Zr-based bulk metallic glass in 0.5 M H2SO4 and 0.5 M NaOH solutions.MATERIALS LETTERS,330,4.
MLA Jiang, J.,et al."Effect of oxygen impurity on corrosion behavior of a Zr-based bulk metallic glass in 0.5 M H2SO4 and 0.5 M NaOH solutions".MATERIALS LETTERS 330(2023):4.
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