Bulk preparation of free-standing single-iron-atom catalysts directly as the air electrodes for high-performance zinc-air batteries

doi:10.1002/cey2.289

IMR OpenIR

	Bulk preparation of free-standing single-iron-atom catalysts directly as the air electrodes for high-performance zinc-air batteries
	Zhang, Hong-Bo 1; Meng, Yu 2; Zhong, Hong 3; Zhang, Lili 2; Ding, Shichao 3,7; Fang, Lingzhe 4,5; Li, Tao 4,5; Mei, Yi 1; Hou, Peng-Xiang 2; Liu, Chang 2,6; Beckman, Scott P.3; Lin, Yuehe 3; Cheng, Hui-Ming 2; Li, Jin-Cheng 1,8
通讯作者	Ding, Shichao(shichao.ding@wsu.edu) ; Liu, Chang(cliu@imr.ac.cn) ; Li, Jin-Cheng(jinchengli@kust.edu.cn)
	2022-12-09
发表期刊	CARBON ENERGY
页码	10
摘要	The keen interest in fuel cells and metal-air batteries stimulates a great deal of research on the development of a cost-efficient and high-performance catalyst as an alternative to traditional Pt to boost the sluggish oxygen reduction reaction (ORR) at the cathode. Herein, we report a facile and scalable strategy for the large-scale preparation of a free-standing and flexible porous atomically dispersed Fe-N-doped carbon microtube (FeSAC/PCMT) sponge. Benefiting from its unique structure that greatly facilitates the catalytic kinetics, mass transport, and electron transfer, our FeSAC/PCMT electrode exhibits excellent performance with an ORR potential of 0.942 V at -3 mA cm(-2). When the FeSAC/PCMT sponge was directly used as an oxygen electrode for liquid-state and flexible solid-state zinc-air batteries, high peak power densities of 183.1 and 58.0 mW cm(-2) were respectively achieved, better than its powdery counterpart and commercial Pt/C catalyst. Experimental and theoretical investigation results demonstrate that such ultrahigh ORR performance can be attributed to atomically dispersed Fe-N-5 species in FeSAC/PCMT. This study presents a cost-effective and scalable strategy for the fabrication of highly efficient and flexible oxygen electrodes, provides a significant new insight into the catalytic mechanisms, and helps to realize significant advances in energy devices.
关键词	atomic Fe-N-5 species free-standing electrode large-scale preparation oxygen reduction reaction zinc-air battery
资助者	Liaoning Revitalization Talents Program ; National Natural Science Foundation of China ; Basic Research Project of Natural Science Foundation of Shandong Province, China ; Kunming University of Science and Technology ; Applied Basic Research Program of Yunnan Province
DOI	10.1002/cey2.289
收录类别	SCI
语种	英语
资助项目	Liaoning Revitalization Talents Program[XLYC2002037] ; National Natural Science Foundation of China[51872293] ; National Natural Science Foundation of China[52072375] ; National Natural Science Foundation of China[52102046] ; National Natural Science Foundation of China[52130209] ; Basic Research Project of Natural Science Foundation of Shandong Province, China[ZR2019ZD49] ; Kunming University of Science and Technology ; Applied Basic Research Program of Yunnan Province[202201AU070113]
WOS研究方向	Chemistry ; Energy & Fuels ; Science & Technology - Other Topics ; Materials Science
WOS类目	Chemistry, Physical ; Energy & Fuels ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS记录号	WOS:000894799300001
出版者	WILEY
引用统计	被引频次：18[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/176148
专题	中国科学院金属研究所
通讯作者	Ding, Shichao; Liu, Chang; Li, Jin-Cheng
作者单位	1.Kunming Univ Sci & Technol, Fac Chem Engn, Yunnan Prov Key Lab Energy Saving Phosphorus Chem, Kunming, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang, Peoples R China 3.Washington State Univ, Sch Mech & Mat Engn, Pullman, WA USA 4.Northern Illinois Univ, Dept Chem & Biochem, De Kalb, IL USA 5.Argonne Natl Lab, Xray Sci Div, Lemont, IL USA 6.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 7.Washington State Univ, Sch Mech & Mat Engn, Pullman, WA 99164 USA 8.Kunming Univ Sci & Technol, Fac Chem Engn, Yunnan Prov Key Lab Energy Saving Phosphorus Chem, Kunming 650500, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Hong-Bo,Meng, Yu,Zhong, Hong,et al. Bulk preparation of free-standing single-iron-atom catalysts directly as the air electrodes for high-performance zinc-air batteries[J]. CARBON ENERGY,2022:10.
APA	Zhang, Hong-Bo.,Meng, Yu.,Zhong, Hong.,Zhang, Lili.,Ding, Shichao.,...&Li, Jin-Cheng.(2022).Bulk preparation of free-standing single-iron-atom catalysts directly as the air electrodes for high-performance zinc-air batteries.CARBON ENERGY,10.
MLA	Zhang, Hong-Bo,et al."Bulk preparation of free-standing single-iron-atom catalysts directly as the air electrodes for high-performance zinc-air batteries".CARBON ENERGY (2022):10.