Double Crosslinked Polymer Electrolyte by C-S-C Group and Metal-Organic Framework for Solid-State Lithium Batteries

doi:10.1002/sstr.202200206

IMR OpenIR

	Double Crosslinked Polymer Electrolyte by C-S-C Group and Metal-Organic Framework for Solid-State Lithium Batteries
	Xu, Ruogu 1,2; Xu, Shengjun 1,2; Wang, Fei 1,3; Xiao, Ru 1,2; Tang, Pei 1,2; Zhang, Xiaoyin 1,2; Bai, Shuo 1,2; Sun, Zhenhua 1,2; Li, Feng 1,2
通讯作者	Sun, Zhenhua(zhsun@imr.ac.cn) ; Li, Feng(fli@imr.ac.cn)
	2022-12-08
发表期刊	SMALL STRUCTURES
页码	9
摘要	Poly(ethylene oxide) (PEO) is among the most promising candidates for solid-state electrolytes in lithium metal batteries. However, the low ionic conductivity caused by strong coordination between Li ions and the EO chains limits the practical application of PEO-based electrolytes. Herein, a double crosslinked PEO-based electrolyte with alternate C-S-C groups and functionalized metal-organic frameworks (MOFs) is proposed. The incorporation of C-S-C groups not only accelerates Li ions transport by weakening the coordination between Li ions and polymer backbone, but also facilitates segmental relaxation of the polymer backbone. The PEO-based electrolyte with C-S-C groups shows a remarkable 13-fold increase in ionic conductivity. Furthermore, when functionalized MOFs are used as crosslinked centers, the double-crosslinked PEO-based electrolyte with a robust network structure possesses enhanced mechanical/electrochemical/thermal stability and limited anion transmission. As a result, the symmetrical Li\|\|Li cell enables over 2400 h cycling at room temperature. The LiFePO4\|\|Li cells show long cycle life over a wide temperature range from 25 to 100 degrees C, and a high areal capacity of 1.43 mAh cm(-2) is achieved with a cathode loading of 10.0 mg cm(-2). This study demonstrates a promising strategy to develop advanced electrolytes for potential solid-state lithium-metal batteries.
关键词	coordination group tuning metal-organic frameworks polymer electrolytes solid-state electrolytes solid-state lithium batteries
资助者	National Key R&D Program of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of Chinese Academy of Sciences ; Youth Innovation Promotion Association of the Chinese Academy of Sciences ; Liaoning Revitalization Talents Program ; DNL Cooperation Fund, CAS
DOI	10.1002/sstr.202200206
收录类别	SCI
语种	英语
资助项目	National Key R&D Program of China[2021YFB2800200] ; National Key R&D Program of China[2021YFB3800301] ; National Natural Science Foundation of China[51972313] ; National Natural Science Foundation of China[52020105010] ; National Natural Science Foundation of China[52188101] ; National Natural Science Foundation of China[52072378] ; Strategic Priority Research Program of Chinese Academy of Sciences[XDA22010602] ; Youth Innovation Promotion Association of the Chinese Academy of Sciences[Y201942] ; Liaoning Revitalization Talents Program[XLYC1908015] ; Liaoning Revitalization Talents Program[XLYC2007080] ; DNL Cooperation Fund, CAS[DNL202019]
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Materials Science
WOS类目	Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS记录号	WOS:000894619800001
出版者	WILEY
引用统计	被引频次：15[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/176170
专题	中国科学院金属研究所
通讯作者	Sun, Zhenhua; Li, Feng
作者单位	1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 2.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China 3.Hunan Univ, Coll Mat Sci & Engn, Changsha 410082, Peoples R China
推荐引用方式 GB/T 7714	Xu, Ruogu,Xu, Shengjun,Wang, Fei,et al. Double Crosslinked Polymer Electrolyte by C-S-C Group and Metal-Organic Framework for Solid-State Lithium Batteries[J]. SMALL STRUCTURES,2022:9.
APA	Xu, Ruogu.,Xu, Shengjun.,Wang, Fei.,Xiao, Ru.,Tang, Pei.,...&Li, Feng.(2022).Double Crosslinked Polymer Electrolyte by C-S-C Group and Metal-Organic Framework for Solid-State Lithium Batteries.SMALL STRUCTURES,9.
MLA	Xu, Ruogu,et al."Double Crosslinked Polymer Electrolyte by C-S-C Group and Metal-Organic Framework for Solid-State Lithium Batteries".SMALL STRUCTURES (2022):9.