Renewable green reactive diluent for bisphenol a epoxy resin system: curing kinetics and properties

doi:10.1039/d2ra05160e

IMR OpenIR

	Renewable green reactive diluent for bisphenol a epoxy resin system: curing kinetics and properties
	Li, Jingyu 1,2; Zhao, Haichao 3; Sui, Guoxin 1,2
通讯作者	Zhao, Haichao(zhaohaichao@nimte.ac.cn) ; Sui, Guoxin(gxsui@imr.ac.cn)
	2022-11-03
发表期刊	RSC ADVANCES
卷号	12 期号:49 页码:31699-31710
摘要	Hydrosilylation epoxidized eugenol (HSI-EP-EU) is successfully synthesized and used as a reactive diluent for epoxy/anhydride (marked as P) and epoxy/imidazole (marked as I) curing systems. The reactive bio-based diluent HSI-EP-EU has an excellent dilution effect on petroleum-based epoxy resin (E44). The curing kinetics of P + HSI-EP-EU and I + HSI-EP-EU are studied by a non-isothermal DSC method. The kinetics parameters are calculated by using the Kissinger model, Crnae model, Ozawa model and beta-T (temperature-heating speed) extrapolation, respectively, to determine theoretically reasonable curing conditions. In addition, the effects of HSI-EP-EU on the antibacterial properties, thermo-mechanical properties and thermal stability of P + HSI-EP-EU and I + HSI-EP-EU systems are also studied. It is found that HSI-EP-EU possessed obvious antibacterial properties and could effectively improve the mechanical properties for the I + HSI-EP-EU.
资助者	Chinese Academy of Sciences-China ; Zhejiang Key Research and Development Program ; Graduate Innovation Research Fund of Institute of Metal Research, Chinese Academy of Sciences
DOI	10.1039/d2ra05160e
收录类别	SCI
语种	英语
资助项目	Chinese Academy of Sciences-China[Y60707WR04] ; Zhejiang Key Research and Development Program[2022C01213] ; Graduate Innovation Research Fund of Institute of Metal Research, Chinese Academy of Sciences[1193002090]
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000880759900001
出版者	ROYAL SOC CHEMISTRY
引用统计	被引频次：7[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/176568
专题	中国科学院金属研究所
通讯作者	Zhao, Haichao; Sui, Guoxin
作者单位	1.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Peoples R China 2.Univ Sci & Technol China, Sch Mat Sci & Engn, Hefei 230000, Peoples R China 3.Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Key Lab Marine Mat & Related Technol, Zhejiang Key Lab Marine Mat & Protect Technol, Ningbo 315201, Peoples R China
推荐引用方式 GB/T 7714	Li, Jingyu,Zhao, Haichao,Sui, Guoxin. Renewable green reactive diluent for bisphenol a epoxy resin system: curing kinetics and properties[J]. RSC ADVANCES,2022,12(49):31699-31710.
APA	Li, Jingyu,Zhao, Haichao,&Sui, Guoxin.(2022).Renewable green reactive diluent for bisphenol a epoxy resin system: curing kinetics and properties.RSC ADVANCES,12(49),31699-31710.
MLA	Li, Jingyu,et al."Renewable green reactive diluent for bisphenol a epoxy resin system: curing kinetics and properties".RSC ADVANCES 12.49(2022):31699-31710.