Cooperative multifunctional nanocarbon as efficient electro-catalysts for CO2 fixation to value-added cyclic carbonates under mild conditions

doi:10.1016/j.carbon.2022.10.041

IMR OpenIR

	Cooperative multifunctional nanocarbon as efficient electro-catalysts for CO2 fixation to value-added cyclic carbonates under mild conditions
	Dai, Xueya 1,2; Qi, Ke 1,2; Liu, Chuangwei 3; Lu, Xingyu 1,2; Qi, Wei 1,2
通讯作者	Qi, Wei(wqi@imr.ac.cn)
	2023-01-15
发表期刊	CARBON
ISSN	0008-6223
卷号	202 页码:51-58
摘要	A novel electrochemical route for efficient cycloaddition of CO2 and styrene oxide (SO) forming the value-added product of styrene carbonate (SC) was proposed in this manuscript using non-metallic nanocarbon material as the catalyst electrode. The synthesized hollow nanospheres (HNSs) nanocarbon materials exhibited unique ad-vantages of porous structure with thin carbon layer, which effectively facilitated the mass and charge transfer process and promoted the electrochemical reaction kinetics. In addition, correlation between the detailed structure analysis and the catalytic activity evaluation results show that the cooperation of nitrogen and oxygen functionalities on nanocarbon played a vital role in enhancing the catalytic activity of the carbon materials. The optimized HNSs catalyst exhibited high SO conversion of 66.9% and SC selectivity of 99.8% under the chro-noamperometry at-0.5 mA for 6 hs, showing great potential in practical applications. The structure-function relations reported here may shed light on the rational design of the nanocarbon catalyst electrode and related reaction system for electrochemical synthesis of SC.
关键词	Nanocarbon catalysis Electrochemical cycloaddition Cyclic carbonates Active sites CO2 fixation and utilization
资助者	NSFC of China ; Natural Science Foundation of Liaoning Province of China ; China Baowu Low Carbon Metallurgy Innovation
DOI	10.1016/j.carbon.2022.10.041
收录类别	SCI
语种	英语
资助项目	NSFC of China ; Natural Science Foundation of Liaoning Province of China ; China Baowu Low Carbon Metallurgy Innovation ; [22072163] ; [2020-YQ-02] ; [Foudation-BWLCF202113]
WOS研究方向	Chemistry ; Materials Science
WOS类目	Chemistry, Physical ; Materials Science, Multidisciplinary
WOS记录号	WOS:000886919600002
出版者	PERGAMON-ELSEVIER SCIENCE LTD
引用统计	被引频次：9[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/176828
专题	中国科学院金属研究所
通讯作者	Qi, Wei
作者单位	1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 2.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China 3.Northeastern Univ, Sch Mat Sci & Engn, Shenyang 110819, Peoples R China
推荐引用方式 GB/T 7714	Dai, Xueya,Qi, Ke,Liu, Chuangwei,et al. Cooperative multifunctional nanocarbon as efficient electro-catalysts for CO2 fixation to value-added cyclic carbonates under mild conditions[J]. CARBON,2023,202:51-58.
APA	Dai, Xueya,Qi, Ke,Liu, Chuangwei,Lu, Xingyu,&Qi, Wei.(2023).Cooperative multifunctional nanocarbon as efficient electro-catalysts for CO2 fixation to value-added cyclic carbonates under mild conditions.CARBON,202,51-58.
MLA	Dai, Xueya,et al."Cooperative multifunctional nanocarbon as efficient electro-catalysts for CO2 fixation to value-added cyclic carbonates under mild conditions".CARBON 202(2023):51-58.