sp<SUP>2</SUP>@sp<SUP>3</SUP> Effect of a Nanodiamond Greenly Driving Epoxy with Superior Fire Safety and Mechanical Properties

doi:10.1021/acssuschemeng.3c03984

IMR OpenIR

	sp²@sp³ Effect of a Nanodiamond Greenly Driving Epoxy with Superior Fire Safety and Mechanical Properties
	Wang, Qi 1,2,3; Dong, Yujie 1; Mao, Yangjiahua 1; Zhong, Bingwei 4; Zeng, You 2; Qu, Yan 3; Yang, Xuezheng 5; Zheng, Yaxuan 3; Ji, Lei 3; Sun, Xuran 3; Tan, Huabing 3; Shao, Zhu-Bao 6
通讯作者	Zhong, Bingwei(20140040@zafu.edu.cn) ; Zeng, You(yzeng@imr.ac.cn) ; Shao, Zhu-Bao(zhu871227@163.com)
	2023-10-18
发表期刊	ACS SUSTAINABLE CHEMISTRY & ENGINEERING
ISSN	2168-0485
页码	12
摘要	Greenly and efficiently reinforcing epoxy on both the mechanical properties and the fire safety is always desired for a nanodiamond (ND). Herein, the special sp(2)@sp(3) effect was found to answer the problem. Abandoning traditional energy-intensive methods, green, efficient, and energy-saving ball milling was successfully designed to transform ND from sp(3) carbon to sp(2)@sp(3) carbon (cND). The sp(2)@sp(3) structure was verified by Raman spectroscopy, X-ray diffraction, electron paramagnetic resonance, X-ray photoelectron spectroscopy (XPS), and high-resolution transmission electron microscopy. cND exhibited overall advantages over ND and successfully reinforced epoxy on both mechanical properties (tensile test, impact, and dynamic mechanical analysis) and fire safety [limited oxygen index (LOI) and cone calorimeter]. Especially, with only 2 wt % cND in epoxy, the impact strength was increased from 7.2 +/- 0.7 kJ/m(2) for neat epoxy to 25.9 +/- 0.2 kJ/m(2); the LOI value (26.8 +/- 0.2%) was 22.4% higher than that of neat epoxy (21.9 +/- 0.2%), and it could be further extended to 29.5 +/- 0.2%. Based on the thermogravimetric, differential thermogravimetric analysis, XPS, and scanning electron microscopy results, the impressive ability of cND to catalyze the char formation in the oxygen-poor atmosphere, the nice dispersion of cND in epoxy, and the strong interaction between cND and epoxy were found to result in superior fire safety and mechanical performances of cND/epoxy composites. The sp(2)@sp(3) effect of cND even defeated the free radical scavenging effect of carbon nanotubes on improving the fire safety of epoxy. Finally, the reinforcing mechanisms on both mechanical and fire safety properties of epoxy by cND were proposed.
关键词	nanodiamond graphene@nanodiamond sp(2)@sp(3) effect dispersion ball milling
资助者	Fundamental Research Programof Shanxi Province ; Shanxi Scholarship Council of China ; Shanxi Province 1331 Project Key Innovation Teamof Polymeric Functional New Materials ; Shanxi Province InnovativeDisciplinary Group of New Materials Industry
DOI	10.1021/acssuschemeng.3c03984
收录类别	SCI
语种	英语
资助项目	Fundamental Research Programof Shanxi Province[20210302124432] ; Shanxi Scholarship Council of China[2023-138] ; Shanxi Province 1331 Project Key Innovation Teamof Polymeric Functional New Materials ; Shanxi Province InnovativeDisciplinary Group of New Materials Industry
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Engineering
WOS类目	Chemistry, Multidisciplinary ; Green & Sustainable Science & Technology ; Engineering, Chemical
WOS记录号	WOS:001092730900001
出版者	AMER CHEMICAL SOC
引用统计	被引频次：3[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/177648
专题	中国科学院金属研究所
通讯作者	Zhong, Bingwei; Zeng, You; Shao, Zhu-Bao
作者单位	1.North Univ China, Res Ctr Engn Technol Polymer Composites Shanxi Pro, Sch Mat Sci & Engn, Shanxi Key Lab Nano Funct Composite Mat, Taiyuan 030051, Shanxi, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Liaoning, Peoples R China 3.Sixth Element Changzhou Mat Technol Co Ltd, , Jiang Su, Changzhou 213161, Peoples R China 4.Zhejiang A&F Univ, Jiyang Coll, Zhuji 311800, Zhejiang, Peoples R China 5.Baotou Res Inst Rare Earths, Baotou 014020, Inner Mongolia, Peoples R China 6.Qingdao Univ, Inst Funct Text & Adv Mat, Coll Text & Clothing, Natl Engn Res Ctr Adv Fire Safety Mat D&A Shandong, Qingdao 266071, Peoples R China
推荐引用方式 GB/T 7714	Wang, Qi,Dong, Yujie,Mao, Yangjiahua,et al. sp²@sp³ Effect of a Nanodiamond Greenly Driving Epoxy with Superior Fire Safety and Mechanical Properties[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2023:12.
APA	Wang, Qi.,Dong, Yujie.,Mao, Yangjiahua.,Zhong, Bingwei.,Zeng, You.,...&Shao, Zhu-Bao.(2023).sp²@sp³ Effect of a Nanodiamond Greenly Driving Epoxy with Superior Fire Safety and Mechanical Properties.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,12.
MLA	Wang, Qi,et al."sp²@sp³ Effect of a Nanodiamond Greenly Driving Epoxy with Superior Fire Safety and Mechanical Properties".ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2023):12.