Atomic design of bidirectional electrocatalysts for reversible Li-CO2 batteries

doi:10.1016/j.mattod.2022.12.008

IMR OpenIR

	Atomic design of bidirectional electrocatalysts for reversible Li-CO2 batteries
	Liu, Yingqi 1,2; Mao, Rui 1,2; Chen, Biao 3; Lu, Bingyi 1,2; Piao, Zhihong 1,2; Song, Yanze 1,2; Zhou, Guangmin 1,2; Cheng, Hui-Ming 1,2,4,5
通讯作者	Zhou, Guangmin(guangminzhou@sz.tsinghua.edu.cn) ; Cheng, Hui-Ming(cheng@imr.ac.cn)
	2023-03-01
发表期刊	MATERIALS TODAY
ISSN	1369-7021
卷号	63 页码:120-136
摘要	With the increasing demand for carbon neutrality, Li-CO2 batteries are a promising technology for using CO2 as an energy storage medium and have attracted extensive attention. However, the sluggish kinetics and complex reaction mechanism significantly affect the reversibility of Li-CO2 batteries, which has stimulated the study of reaction pathways, product regulations, and bidirectional catalysts. Modulating the structure of catalysts at the atomic level has attracted increasing attention recently for improving their selectivity and activity, thus accelerating reaction kinetics and regulating the reaction pathways. In this review, we systematically discuss the conversion reaction mechanisms and analyze the key factors that affect the reaction pathways during discharge and charge in Li-CO2 batteries. Then the strategies at the atomic level for developing efficient bidirectional catalysts are highlighted, including their features, advantages, and limitations. Finally, a summary and outlook on fundamental investigation and advanced catalysts development for high-performance Li-CO2 batteries are presented.
关键词	Li-CO2 batteries Bidirectional catalyst Reaction pathway Atomic structure level Atomic active sites
资助者	National Key Research and Development Program of China ; Joint Funds of the National Natural Science Foundation of China ; Shenzhen Stabilization Support Program ; Shenzhen Science and Technology Program ; Overseas Research Cooperation Fund of Tsinghua Shenzhen International Graduate School ; Shenzhen Geim Graphene Center
DOI	10.1016/j.mattod.2022.12.008
收录类别	SCI
语种	英语
资助项目	National Key Research and Development Program of China[2021YFB2500200] ; Joint Funds of the National Natural Science Foundation of China[U21A20174] ; Shenzhen Stabilization Support Program[WDZC20200824091903001] ; Shenzhen Science and Technology Program[KQTD20210811090112002] ; Overseas Research Cooperation Fund of Tsinghua Shenzhen International Graduate School ; Shenzhen Geim Graphene Center
WOS研究方向	Materials Science
WOS类目	Materials Science, Multidisciplinary
WOS记录号	WOS:000990657200001
出版者	ELSEVIER SCI LTD
引用统计	被引频次：20[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/177786
专题	中国科学院金属研究所
通讯作者	Zhou, Guangmin; Cheng, Hui-Ming
作者单位	1.Tsinghua Univ, Tsinghua Berkeley Shenzhen Inst, Shenzhen 518055, Peoples R China 2.Tsinghua Univ, Tsinghua Shenzhen Int Grad Sch, Shenzhen 518055, Peoples R China 3.Tianjin Univ, Sch Mat Sci & Engn, Tianjin Key Lab Composite & Funct Mat, Tianjin 300350, Peoples R China 4.Chinese Acad Sci, Inst Technol Carbon Neutral, Shenzhen Inst Adv Technol, Shenzhen 518055, Peoples R China 5.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
推荐引用方式 GB/T 7714	Liu, Yingqi,Mao, Rui,Chen, Biao,et al. Atomic design of bidirectional electrocatalysts for reversible Li-CO2 batteries[J]. MATERIALS TODAY,2023,63:120-136.
APA	Liu, Yingqi.,Mao, Rui.,Chen, Biao.,Lu, Bingyi.,Piao, Zhihong.,...&Cheng, Hui-Ming.(2023).Atomic design of bidirectional electrocatalysts for reversible Li-CO2 batteries.MATERIALS TODAY,63,120-136.
MLA	Liu, Yingqi,et al."Atomic design of bidirectional electrocatalysts for reversible Li-CO2 batteries".MATERIALS TODAY 63(2023):120-136.