Deoxidation purification of La-Ce alloy by solid state external gettering | |
Lu, Congli1; Chen, Yuzhen1; Bai, Yuhang1; Xu, Baoqiang1; Liu, Hang2; Yang, Bin1; Luan, Yikun2; Wang, Fei1,3 | |
通讯作者 | Wang, Fei(fayerswing@hotmail.com) |
2023-07-01 | |
发表期刊 | VACUUM
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ISSN | 0042-207X |
卷号 | 213页码:8 |
摘要 | Deep removal of interstitial impurities such as oxygen from La-Ce alloy is challenging due to their strong affinity and high chemical reactivity with oxygen. The method of external getter was employed to investigate the deoxidation process and thus to explore the deoxidation mechanism.Quantification of relevant elements including Ca, Y, and O were analyzed by inductively coupled plasma-mass spectrometry(ICP-MS) and inert gas analysis (IGA). The analysis results show that oxygen concentration decreased from 550 ppm to 54 ppm and 55 ppm respectively in La-Ce alloy by Ca and Y as the external getters. The interaction between the getters and base metal, the chemical driving force and deoxidation mechanism were discussed in details. |
关键词 | La-Ce Rare earth alloys External gettering Deoxidation Purification mechanism |
资助者 | Yunnan Provincial Scientists' Workshop and Top Young Talents of Yunnan Province Ten Thousand Talents Plan ; Yunnan Fundamental Research Projects General Project |
DOI | 10.1016/j.vacuum.2023.112086 |
收录类别 | SCI |
语种 | 英语 |
资助项目 | Yunnan Provincial Scientists' Workshop and Top Young Talents of Yunnan Province Ten Thousand Talents Plan[109720190004] ; Yunnan Fundamental Research Projects General Project[202201AT070206] |
WOS研究方向 | Materials Science ; Physics |
WOS类目 | Materials Science, Multidisciplinary ; Physics, Applied |
WOS记录号 | WOS:000983355200001 |
出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/177850 |
专题 | 中国科学院金属研究所 |
通讯作者 | Wang, Fei |
作者单位 | 1.Kunming Univ Sci & Technol, Natl Engn Res Ctr Vacuum Met, Key Lab Nonferrous Vacuum Met Yunnan Prov, State Key Lab Complex Nonferrous Met Resources Cle, Kunming 650093, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Peoples R China 3.Kunming Univ Sci & Technol, Natl Engn Res Ctr Vacuum Met, Kunming 650093, Yunnan, Peoples R China |
推荐引用方式 GB/T 7714 | Lu, Congli,Chen, Yuzhen,Bai, Yuhang,et al. Deoxidation purification of La-Ce alloy by solid state external gettering[J]. VACUUM,2023,213:8. |
APA | Lu, Congli.,Chen, Yuzhen.,Bai, Yuhang.,Xu, Baoqiang.,Liu, Hang.,...&Wang, Fei.(2023).Deoxidation purification of La-Ce alloy by solid state external gettering.VACUUM,213,8. |
MLA | Lu, Congli,et al."Deoxidation purification of La-Ce alloy by solid state external gettering".VACUUM 213(2023):8. |
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