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EFFECT OF ALKALINE SOLUTION CONCENTRATION ON THE PASSIVATION FILM OF Cu-Ni ALLOY
Li, Yue1; Zhao, Shuyan2; Zhang, Xinyu2; Zhang, Shuo2; Wu, Xiaoliang2; Wu, Nianchu1
通讯作者Wu, Nianchu(wunianchu@163.com)
2023
发表期刊MATERIALI IN TEHNOLOGIJE
ISSN1580-2949
卷号57期号:3页码:249-255
摘要Passive films formed on a Cu-Ni alloy in various concentrations of alkaline environment were investigated by potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), X-ray photoelectron spectroscopy and the Mott-Schottky approach. The wide passivation range of the copper-nickel alloy was tested in alkaline solutions of three concentrations. The oxide film on the specimen has a p-type semiconductor property, while the flat band potential (EFB) decreased with increasing solution concentration. The film resistance of the passive films increased with increasing solution concentration. The pAassive films showed a duplex structure, including an inner layer of oxide (Cu2O, NiO) and an outer layer of hydroxide (Cu(OH)2, Ni(OH)2).
关键词90Cu-10Ni alloy corrosion resistance oxidation film solution concentration passivation potential
资助者Natural Science Founda- tion of Liaoning Province ; Educational Commission of Liaoning Province of China ; Fushun Revitalization Talents Program
DOI10.17222/mit.2023.782
收录类别SCI
语种英语
资助项目Natural Science Founda- tion of Liaoning Province[2022 -MS -364] ; Educational Commission of Liaoning Province of China[L2020021] ; Fushun Revitalization Talents Program[FSYC202107011]
WOS研究方向Materials Science ; Metallurgy & Metallurgical Engineering
WOS类目Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering
WOS记录号WOS:001008264200005
出版者INST ZA KOVINSKE MATERIALE I IN TEHNOLOGIE
引用统计
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/178274
专题中国科学院金属研究所
通讯作者Wu, Nianchu
作者单位1.Liaoning Petrochem Univ, Sch Mech Engn, Fushun 113001, Peoples R China
2.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Peoples R China
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Li, Yue,Zhao, Shuyan,Zhang, Xinyu,et al. EFFECT OF ALKALINE SOLUTION CONCENTRATION ON THE PASSIVATION FILM OF Cu-Ni ALLOY[J]. MATERIALI IN TEHNOLOGIJE,2023,57(3):249-255.
APA Li, Yue,Zhao, Shuyan,Zhang, Xinyu,Zhang, Shuo,Wu, Xiaoliang,&Wu, Nianchu.(2023).EFFECT OF ALKALINE SOLUTION CONCENTRATION ON THE PASSIVATION FILM OF Cu-Ni ALLOY.MATERIALI IN TEHNOLOGIJE,57(3),249-255.
MLA Li, Yue,et al."EFFECT OF ALKALINE SOLUTION CONCENTRATION ON THE PASSIVATION FILM OF Cu-Ni ALLOY".MATERIALI IN TEHNOLOGIJE 57.3(2023):249-255.
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