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Thermo-responsive ReO4- composite membranes with SiO2 modified: Preparation, performances and application in secondary resources
Xu, Wan1,2; Zhao, Shengyuan1,2; Zhang, Huijuan1,2; Niu, Fangfang1,2; Liu, Xingsheng1,2; Chen, Zhenbin1,2,4; Sun, Yuan3
通讯作者Chen, Zhenbin(zhenbinchen@163.com)
2023-07-25
发表期刊JOURNAL OF APPLIED POLYMER SCIENCE
ISSN0021-8995
页码18
摘要With the continuous depletion of global rhenium resources, the separation and purification of rhenium (Re) from secondary resources became very important. Herein, an imprinted composite membrane with "flexible chain" thermo-responsive imprinted separation layer structure (Re-TIICM) was prepared to achieve selective separation and recovery of Re from secondary resources with complex composition. Re-TIICM's thermo-responsive imprinted separation layer occurred sol/gel phase transition by adjusting the temperature, which effectively mitigated the trade-off between selectivity and desorption. The structure and performance of Re-TIICM under optimum process conditions were tested and evaluated. The results showed that Re-TIICM exhibited a maximum adsorption capacity of 0.1036 mmol/g at 35?, a separation degree of 4.37 (MnO4- as disturbing ions), and remained good adsorption capacity and selectivity after 9 adsorption/desorption cycles. When Re-TIICM was applied in secondary resources, the purity of Re increased from 35.412% to 70.208% after one adsorption/desorption cycle, showing a great potential for industrial applications.
关键词imprinted composite membranes ReO4- separation and purification thermo-responsive
资助者Natural Science Foundation of Gansu Province (China) ; Shenyang National Laboratory for Materials Science and State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals. (China) ; Open Project of State Key Laboratory of Nickel and Cobalt Resources Comprehensive Utilization (China)
DOI10.1002/app.54480
收录类别SCI
语种英语
资助项目Natural Science Foundation of Gansu Province (China)[22JR5RA227] ; Shenyang National Laboratory for Materials Science and State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals. (China)[18LHZD003] ; Shenyang National Laboratory for Materials Science and State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals. (China)[18LHPY004] ; Open Project of State Key Laboratory of Nickel and Cobalt Resources Comprehensive Utilization (China)[2019- 16]
WOS研究方向Polymer Science
WOS类目Polymer Science
WOS记录号WOS:001036497300001
出版者WILEY
引用统计
被引频次:6[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/178661
专题中国科学院金属研究所
通讯作者Chen, Zhenbin
作者单位1.Lanzhou Univ Technol, State Key Lab Gansu Adv Nonferrous Met Mat, Lanzhou, Peoples R China
2.Lanzhou Univ Technol, Sch Mat Sci & Engn, Lanzhou, Peoples R China
3.Chinese Acad Sci, Inst Met Res, Shenyang, Peoples R China
4.Lanzhou Univ Technol, Sch Mat Sci & Engn, State Key Lab Adv progressing & Recycling Nonferro, Lanzhou, Peoples R China
推荐引用方式
GB/T 7714
Xu, Wan,Zhao, Shengyuan,Zhang, Huijuan,et al. Thermo-responsive ReO4- composite membranes with SiO2 modified: Preparation, performances and application in secondary resources[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2023:18.
APA Xu, Wan.,Zhao, Shengyuan.,Zhang, Huijuan.,Niu, Fangfang.,Liu, Xingsheng.,...&Sun, Yuan.(2023).Thermo-responsive ReO4- composite membranes with SiO2 modified: Preparation, performances and application in secondary resources.JOURNAL OF APPLIED POLYMER SCIENCE,18.
MLA Xu, Wan,et al."Thermo-responsive ReO4- composite membranes with SiO2 modified: Preparation, performances and application in secondary resources".JOURNAL OF APPLIED POLYMER SCIENCE (2023):18.
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