Thermo-responsive ReO4- composite membranes with SiO2 modified: Preparation, performances and application in secondary resources | |
Xu, Wan1,2; Zhao, Shengyuan1,2; Zhang, Huijuan1,2; Niu, Fangfang1,2; Liu, Xingsheng1,2; Chen, Zhenbin1,2,4; Sun, Yuan3 | |
通讯作者 | Chen, Zhenbin(zhenbinchen@163.com) |
2023-07-25 | |
发表期刊 | JOURNAL OF APPLIED POLYMER SCIENCE
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ISSN | 0021-8995 |
页码 | 18 |
摘要 | With the continuous depletion of global rhenium resources, the separation and purification of rhenium (Re) from secondary resources became very important. Herein, an imprinted composite membrane with "flexible chain" thermo-responsive imprinted separation layer structure (Re-TIICM) was prepared to achieve selective separation and recovery of Re from secondary resources with complex composition. Re-TIICM's thermo-responsive imprinted separation layer occurred sol/gel phase transition by adjusting the temperature, which effectively mitigated the trade-off between selectivity and desorption. The structure and performance of Re-TIICM under optimum process conditions were tested and evaluated. The results showed that Re-TIICM exhibited a maximum adsorption capacity of 0.1036 mmol/g at 35?, a separation degree of 4.37 (MnO4- as disturbing ions), and remained good adsorption capacity and selectivity after 9 adsorption/desorption cycles. When Re-TIICM was applied in secondary resources, the purity of Re increased from 35.412% to 70.208% after one adsorption/desorption cycle, showing a great potential for industrial applications. |
关键词 | imprinted composite membranes ReO4- separation and purification thermo-responsive |
资助者 | Natural Science Foundation of Gansu Province (China) ; Shenyang National Laboratory for Materials Science and State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals. (China) ; Open Project of State Key Laboratory of Nickel and Cobalt Resources Comprehensive Utilization (China) |
DOI | 10.1002/app.54480 |
收录类别 | SCI |
语种 | 英语 |
资助项目 | Natural Science Foundation of Gansu Province (China)[22JR5RA227] ; Shenyang National Laboratory for Materials Science and State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals. (China)[18LHZD003] ; Shenyang National Laboratory for Materials Science and State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals. (China)[18LHPY004] ; Open Project of State Key Laboratory of Nickel and Cobalt Resources Comprehensive Utilization (China)[2019- 16] |
WOS研究方向 | Polymer Science |
WOS类目 | Polymer Science |
WOS记录号 | WOS:001036497300001 |
出版者 | WILEY |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/178661 |
专题 | 中国科学院金属研究所 |
通讯作者 | Chen, Zhenbin |
作者单位 | 1.Lanzhou Univ Technol, State Key Lab Gansu Adv Nonferrous Met Mat, Lanzhou, Peoples R China 2.Lanzhou Univ Technol, Sch Mat Sci & Engn, Lanzhou, Peoples R China 3.Chinese Acad Sci, Inst Met Res, Shenyang, Peoples R China 4.Lanzhou Univ Technol, Sch Mat Sci & Engn, State Key Lab Adv progressing & Recycling Nonferro, Lanzhou, Peoples R China |
推荐引用方式 GB/T 7714 | Xu, Wan,Zhao, Shengyuan,Zhang, Huijuan,et al. Thermo-responsive ReO4- composite membranes with SiO2 modified: Preparation, performances and application in secondary resources[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2023:18. |
APA | Xu, Wan.,Zhao, Shengyuan.,Zhang, Huijuan.,Niu, Fangfang.,Liu, Xingsheng.,...&Sun, Yuan.(2023).Thermo-responsive ReO4- composite membranes with SiO2 modified: Preparation, performances and application in secondary resources.JOURNAL OF APPLIED POLYMER SCIENCE,18. |
MLA | Xu, Wan,et al."Thermo-responsive ReO4- composite membranes with SiO2 modified: Preparation, performances and application in secondary resources".JOURNAL OF APPLIED POLYMER SCIENCE (2023):18. |
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