Acidic enol electrooxidation-coupled hydrogen production with ampere-level current density

doi:10.1038/s41467-023-39848-w

IMR OpenIR

	Acidic enol electrooxidation-coupled hydrogen production with ampere-level current density
	Chen, Zheng-Jie 1; Dong, Jiuyi 1; Wu, Jiajing 2; Shao, Qiting 1; Luo, Na 1; Xu, Minwei 1; Sun, Yuanmiao 1; Tang, Yongbing 1,3; Peng, Jing 1,3; Cheng, Hui-Ming 1,3,4
通讯作者	Peng, Jing(jing.peng@siat.ac.cn) ; Cheng, Hui-Ming(hm.cheng@siat.ac.cn)
	2023-07-14
发表期刊	NATURE COMMUNICATIONS
卷号	14 期号:1 页码:9
摘要	Hydrogen production coupled with biomass upgrading is vital for future sustainable energy developments. However, most biomass electrooxidation reactions suffer from high working voltage and low current density, which substantially hinder large-scale industrial applications. Herein, we report an acidic hydrogen production system that combined anodic ascorbic acid electrooxidation with cathodic hydrogen evolution. Unlike C-H and O-H bonds cleavage with slow kinetics in conventional organic oxidation, the highly active enol structure in ascorbic acid allows for an ultralow overpotential of only 12 mV@10 mA/cm(2) using Fe single-atom catalysts, and reaches 1 A/cm(2) at only 0.75 V (versus reversible hydrogen electrode) with approximately 100% Faraday efficiency for hydrogen production. Furthermore, the fabricated two-electrode membrane-free electrolyser delivers an industrial current density of 2 A/cm(2)@1.1 V at 60 degrees C (2.63 kWh/Nm(3) H-2), which requires half of the electricity consumption in conventional water electrolysis (similar to 5 kWh/Nm(3) H-2). This work provides a new avenue for achieving industrial-scale hydrogen production from biomass.
资助者	National Natural Science Foundation of China ; Shenzhen Basic Research Project ; Science and Technology Foundation of Shenzhen ; Guang Dong Basic and Applied Basic Research Foundation ; China Postdoctoral Fund~ ; Cross Institute Joint Research Youth Team Project of SIAT
DOI	10.1038/s41467-023-39848-w
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[52188101] ; National Natural Science Foundation of China[22275205] ; National Natural Science Foundation of China[22205148] ; Shenzhen Basic Research Project[JCYJ20200109144616617] ; Science and Technology Foundation of Shenzhen[JCYJ20220530154404010] ; Guang Dong Basic and Applied Basic Research Foundation[2023B1515020102] ; Guang Dong Basic and Applied Basic Research Foundation[2022A1515110408] ; China Postdoctoral Fund~[2022M713270] ; Cross Institute Joint Research Youth Team Project of SIAT[E25427]
WOS研究方向	Science & Technology - Other Topics
WOS类目	Multidisciplinary Sciences
WOS记录号	WOS:001033533300027
出版者	NATURE PORTFOLIO
引用统计	被引频次：51[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/178727
专题	中国科学院金属研究所
通讯作者	Peng, Jing; Cheng, Hui-Ming
作者单位	1.Chinese Acad Sci, Inst Technol Carbon Neutral, Shenzhen Inst Adv Technol, Fac Mat Sci & Energy Engn, Shenzhen 518055, Peoples R China 2.Shenzhen Inst Informat Technol, Inst Informat Technol, Shenzhen 518172, Peoples R China 3.Chinese Acad Sci, Shenzhen Inst Adv Technol, Shenzhen Key Lab Energy Mat Carbon Neutral, Shenzhen 518055, Peoples R China 4.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
推荐引用方式 GB/T 7714	Chen, Zheng-Jie,Dong, Jiuyi,Wu, Jiajing,et al. Acidic enol electrooxidation-coupled hydrogen production with ampere-level current density[J]. NATURE COMMUNICATIONS,2023,14(1):9.
APA	Chen, Zheng-Jie.,Dong, Jiuyi.,Wu, Jiajing.,Shao, Qiting.,Luo, Na.,...&Cheng, Hui-Ming.(2023).Acidic enol electrooxidation-coupled hydrogen production with ampere-level current density.NATURE COMMUNICATIONS,14(1),9.
MLA	Chen, Zheng-Jie,et al."Acidic enol electrooxidation-coupled hydrogen production with ampere-level current density".NATURE COMMUNICATIONS 14.1(2023):9.