Hydrogen damage process of dual-phase Ti-6Al-4V alloy: From surface passive film to the interior substrate | |
Liu, Xiaozhen1,2; Han, En-Hou1,3,4; Song, Yingwei1,3; Dong, Kaihui1,3 | |
通讯作者 | Han, En-Hou(ehhan@imr.ac.cn) ; Song, Yingwei(ywsong@imr.ac.cn) |
2023-10-01 | |
发表期刊 | ELECTROCHIMICA ACTA
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ISSN | 0013-4686 |
卷号 | 464页码:12 |
摘要 | Ti alloys show promising application prospects in marine field due to their excellent corrosion resistance. However, hydrogen damage of Ti alloys is inevitable during the actual applications in view of the high susceptibility of Ti to hydrogen. The hydrogen damage process from the surface passive film to the interior Ti substrate of dual-phase Ti-6Al-4 V (TC4) alloy was studied using scanning electron microscopy (SEM), X-ray diffraction (XRD), and secondary ion mass spectroscopy (SIMS). The results indicate that the dense passive film on the surface of TC4 alloy is first replaced by loose corrosion product film which mainly consists of TiH1.5 hydrides, and then hydrogen diffuses into the interior of Ti substrate and forms the hydrides of TiH1.971 which are precipitated along the & alpha;/& beta; interfaces, resulting in the cracks of TC4 alloy. Moreover, the element V which mainly locates in the & beta; phases of TC4 before hydrogen charging is transformed to enrich both in & beta; phases and the hydrides at & alpha;/& beta; interfaces after hydrogen charging. |
关键词 | Hydrogen damage Passive film Microstructure Ti-6al-4V alloy Hydrides |
资助者 | Innovation Group Project of Southern Marine Science and Engineering Guangdong Laboratory (Zhuhai) |
DOI | 10.1016/j.electacta.2023.142916 |
收录类别 | SCI |
语种 | 英语 |
资助项目 | Innovation Group Project of Southern Marine Science and Engineering Guangdong Laboratory (Zhuhai)[311021013] |
WOS研究方向 | Electrochemistry |
WOS类目 | Electrochemistry |
WOS记录号 | WOS:001050126900001 |
出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/178961 |
专题 | 中国科学院金属研究所 |
通讯作者 | Han, En-Hou; Song, Yingwei |
作者单位 | 1.Chinese Acad Sci, Inst Met Res, Key Lab Nucl Mat & Safety Assessment, Shenyang 110016, Peoples R China 2.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China 3.Southern Marine Sci & Engn Guangdong Lab Zhuhai, Zhuhai 519000, Peoples R China 4.Inst Corros Sci & Technol, Guangzhou 510535, Peoples R China |
推荐引用方式 GB/T 7714 | Liu, Xiaozhen,Han, En-Hou,Song, Yingwei,et al. Hydrogen damage process of dual-phase Ti-6Al-4V alloy: From surface passive film to the interior substrate[J]. ELECTROCHIMICA ACTA,2023,464:12. |
APA | Liu, Xiaozhen,Han, En-Hou,Song, Yingwei,&Dong, Kaihui.(2023).Hydrogen damage process of dual-phase Ti-6Al-4V alloy: From surface passive film to the interior substrate.ELECTROCHIMICA ACTA,464,12. |
MLA | Liu, Xiaozhen,et al."Hydrogen damage process of dual-phase Ti-6Al-4V alloy: From surface passive film to the interior substrate".ELECTROCHIMICA ACTA 464(2023):12. |
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