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Hydrogen damage process of dual-phase Ti-6Al-4V alloy: From surface passive film to the interior substrate
Liu, Xiaozhen1,2; Han, En-Hou1,3,4; Song, Yingwei1,3; Dong, Kaihui1,3
通讯作者Han, En-Hou(ehhan@imr.ac.cn) ; Song, Yingwei(ywsong@imr.ac.cn)
2023-10-01
发表期刊ELECTROCHIMICA ACTA
ISSN0013-4686
卷号464页码:12
摘要Ti alloys show promising application prospects in marine field due to their excellent corrosion resistance. However, hydrogen damage of Ti alloys is inevitable during the actual applications in view of the high susceptibility of Ti to hydrogen. The hydrogen damage process from the surface passive film to the interior Ti substrate of dual-phase Ti-6Al-4 V (TC4) alloy was studied using scanning electron microscopy (SEM), X-ray diffraction (XRD), and secondary ion mass spectroscopy (SIMS). The results indicate that the dense passive film on the surface of TC4 alloy is first replaced by loose corrosion product film which mainly consists of TiH1.5 hydrides, and then hydrogen diffuses into the interior of Ti substrate and forms the hydrides of TiH1.971 which are precipitated along the & alpha;/& beta; interfaces, resulting in the cracks of TC4 alloy. Moreover, the element V which mainly locates in the & beta; phases of TC4 before hydrogen charging is transformed to enrich both in & beta; phases and the hydrides at & alpha;/& beta; interfaces after hydrogen charging.
关键词Hydrogen damage Passive film Microstructure Ti-6al-4V alloy Hydrides
资助者Innovation Group Project of Southern Marine Science and Engineering Guangdong Laboratory (Zhuhai)
DOI10.1016/j.electacta.2023.142916
收录类别SCI
语种英语
资助项目Innovation Group Project of Southern Marine Science and Engineering Guangdong Laboratory (Zhuhai)[311021013]
WOS研究方向Electrochemistry
WOS类目Electrochemistry
WOS记录号WOS:001050126900001
出版者PERGAMON-ELSEVIER SCIENCE LTD
引用统计
被引频次:4[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/178961
专题中国科学院金属研究所
通讯作者Han, En-Hou; Song, Yingwei
作者单位1.Chinese Acad Sci, Inst Met Res, Key Lab Nucl Mat & Safety Assessment, Shenyang 110016, Peoples R China
2.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China
3.Southern Marine Sci & Engn Guangdong Lab Zhuhai, Zhuhai 519000, Peoples R China
4.Inst Corros Sci & Technol, Guangzhou 510535, Peoples R China
推荐引用方式
GB/T 7714
Liu, Xiaozhen,Han, En-Hou,Song, Yingwei,et al. Hydrogen damage process of dual-phase Ti-6Al-4V alloy: From surface passive film to the interior substrate[J]. ELECTROCHIMICA ACTA,2023,464:12.
APA Liu, Xiaozhen,Han, En-Hou,Song, Yingwei,&Dong, Kaihui.(2023).Hydrogen damage process of dual-phase Ti-6Al-4V alloy: From surface passive film to the interior substrate.ELECTROCHIMICA ACTA,464,12.
MLA Liu, Xiaozhen,et al."Hydrogen damage process of dual-phase Ti-6Al-4V alloy: From surface passive film to the interior substrate".ELECTROCHIMICA ACTA 464(2023):12.
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