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Protective Coatings Containing ZnMOF-BTA Metal-Organic Framework for Active Protection of AA2024-T3
Nwokolo, Izuchukwu K.1,2; Shi, Hongwei1,2,3; Uzoma, Paul C.4; Ahmed, Sharjeel1,2; Li, Jiwen1,2; Liu, Fuchun1,2,5
Corresponding AuthorShi, Hongwei(hwshi@imr.ac.cn) ; Liu, Fuchun(fcliu@imr.ac.cn)
2023-09-19
Source PublicationACTA METALLURGICA SINICA-ENGLISH LETTERS
ISSN1006-7191
Pages16
AbstractZnMOF-BTA, a new metal-organic framework with excellent anti-corrosion properties was prepared and characterized. Polarization and immersion tests in 3.5 wt% NaCl were performed on AA2024-T3 alloy to assess the corrosion inhibition ability of ZnMOF-BTA. It showed an inhibition efficiency of more than 90%, indicating excellent corrosion inhibition of ZnMOF-BTA on AA 2024-T3 in NaCl. Moreover, ZnMOF-BTA particles were incorporated into polyurethane coatings to create corrosion-resistant coatings. Electrochemical tests and neutral salt spray analysis were used to assess the corrosion protection ability of ZnMOF-BTA-laden polyurethane coatings. The results of electrochemical impedance spectra clearly showed the outstanding corrosion resistance and durability of ZnMOF-BTA coatings after 1440 h of immersion with a high pore resistance (Rpo) of 1.76 x 1010 & OHM; cm2. In addition, during the cross-cut adhesion test, the coating did not detach from the substrate, and after the impact test, there was scarcely any indication of a fracture, which further supports the notion that the coating has strong adhesion to the substrate.
KeywordAluminum alloy Benzotriazole Corrosion inhibition Electrochemical impedance spectroscopy (EIS) Metal-organic framework Organic coatings
Funding OrganizationNational Natural Science Foundation of China ; LingChuang Research Project of China National Nuclear Corporation
DOI10.1007/s40195-023-01600-0
Indexed BySCI
Language英语
Funding ProjectNational Natural Science Foundation of China[52171089] ; National Natural Science Foundation of China[51571202] ; LingChuang Research Project of China National Nuclear Corporation[E041F212Z1]
WOS Research AreaMetallurgy & Metallurgical Engineering
WOS SubjectMetallurgy & Metallurgical Engineering
WOS IDWOS:001067692700002
PublisherCHINESE ACAD SCIENCES, INST METAL RESEARCH
Citation statistics
Cited Times:3[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/179186
Collection中国科学院金属研究所
Corresponding AuthorShi, Hongwei; Liu, Fuchun
Affiliation1.Chinese Acad Sci, CAS Key Lab Nucl Mat & Safety Assessment, Inst Met Res, Shenyang 110016, Peoples R China
2.Univ Sci & Technol China, Sch Mat Sci & Engn, Hefei 230026, Peoples R China
3.Shenyang Univ Technol, Sch Mat Sci & Engn, Shenyang 110870, Peoples R China
4.Zhejiang Univ, ZJU UIUC Inst, Int Campus, Haining 314400, Peoples R China
5.Inst Corros Sci & Technol, Guangzhou 510530, Peoples R China
Recommended Citation
GB/T 7714
Nwokolo, Izuchukwu K.,Shi, Hongwei,Uzoma, Paul C.,et al. Protective Coatings Containing ZnMOF-BTA Metal-Organic Framework for Active Protection of AA2024-T3[J]. ACTA METALLURGICA SINICA-ENGLISH LETTERS,2023:16.
APA Nwokolo, Izuchukwu K.,Shi, Hongwei,Uzoma, Paul C.,Ahmed, Sharjeel,Li, Jiwen,&Liu, Fuchun.(2023).Protective Coatings Containing ZnMOF-BTA Metal-Organic Framework for Active Protection of AA2024-T3.ACTA METALLURGICA SINICA-ENGLISH LETTERS,16.
MLA Nwokolo, Izuchukwu K.,et al."Protective Coatings Containing ZnMOF-BTA Metal-Organic Framework for Active Protection of AA2024-T3".ACTA METALLURGICA SINICA-ENGLISH LETTERS (2023):16.
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