IMR OpenIR
Construction of C/SiC-Cu3Si-Cu interpenetrating composites for long-duration thermal protection at 2500 °C by cooperative active-passive cooling
Wu, Yue1,2; Zhao, Rida1; Liang, Bin1; Pang, Shengyang1; Hu, Chenglong1; Li, Jian1; Cheng, Hui -Ming3; Tang, Sufang1
通讯作者Tang, Sufang(sftang@imr.ac.cn)
2023-11-01
发表期刊COMPOSITES PART B-ENGINEERING
ISSN1359-8368
卷号266页码:11
摘要Developing materials which can resist long-term ablation at ultra-high temperatures above 2200 degrees C in oxygen-containing environments is of prime importance for the thermal protection of aerospace vehicles, but remains a great challenge. C/SiC composites are attractive candidates for long-term use, but they are often severely ablated above 1650 degrees C due to the damage of protective oxide scale. Here, C/SiC-Cu3Si-Cu interpenetrating composites with interconnected ceramic and metal matrixes are developed by the selective ceramization of carbon-fiber reinforced carbon aerogel preforms. The heat radiation of C/SiC-Cu3Si-Cu, transpiration of Cu2O, evaporation of SiO2, as well as inhibition of oxygen diffusion in the glassy scale, jointly lead to the cooperative active-passive cooling during ablation. Resultantly, their surface temperatures are 150 degrees C, 450 degrees C and 750 degrees C lower than those for C/SiC (1900 degrees C, 2200 degrees C and 2500 degrees C) with a duration of 600 s ablation, respectively. They also exhibit remarkably low mass and linear ablation rates with respective 0.054-0.064 mg cm(-2) s(-1) and -0.157-0.018 mu m s(-1). Additionally, the composites can endure 1160 s ablation with a surface temperature of 1750 degrees C under the ablation condition where the surface temperature of C/SiC is 2200 degrees C. The developed C/SiC-Cu3Si-Cu interpenetrating composites are so far the only known light-weight (<3.0 g cm(-3)), non-ablation materials which can offer long-duration (>= 600 s) thermal protection at 2200-2500 degrees C in high-enthalpy-flow and oxidizing environments.
关键词Ceramic-metal matrix composites C/SiC-Cu3Si-Cu Selective ceramization Ablation resistance Active -passive cooling
资助者National Natural Science Foundation of China ; Defense Industrial Technology Development Program ; IMR Innovation Fund ; Research Fund of Youth Innovation Promotion Association of CAS, China ; directional institutionalized scientific research platform relies on China Spallation Neutron Source of Chinese Academy of Sciences ; National Key R&D Program of China
DOI10.1016/j.compositesb.2023.111015
收录类别SCI
语种英语
资助项目National Natural Science Foundation of China[U20A20242] ; National Natural Science Foundation of China[52022101] ; National Natural Science Foundation of China[52272075] ; National Natural Science Foundation of China[52188101] ; Defense Industrial Technology Development Program[JCKY2021130B007] ; IMR Innovation Fund[E255A901] ; Research Fund of Youth Innovation Promotion Association of CAS, China[2021190] ; directional institutionalized scientific research platform relies on China Spallation Neutron Source of Chinese Academy of Sciences ; National Key R&D Program of China[2021YFA1500804]
WOS研究方向Engineering ; Materials Science
WOS类目Engineering, Multidisciplinary ; Materials Science, Composites
WOS记录号WOS:001085382500001
出版者ELSEVIER SCI LTD
引用统计
被引频次:15[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/179452
专题中国科学院金属研究所
通讯作者Tang, Sufang
作者单位1.Chinese Acad Sci, Shi Changxu Innovat Ctr Adv Mat, Inst Met Res, Shenyang 110016, Peoples R China
2.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China
3.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
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GB/T 7714
Wu, Yue,Zhao, Rida,Liang, Bin,et al. Construction of C/SiC-Cu3Si-Cu interpenetrating composites for long-duration thermal protection at 2500 &deg;C by cooperative active-passive cooling[J]. COMPOSITES PART B-ENGINEERING,2023,266:11.
APA Wu, Yue.,Zhao, Rida.,Liang, Bin.,Pang, Shengyang.,Hu, Chenglong.,...&Tang, Sufang.(2023).Construction of C/SiC-Cu3Si-Cu interpenetrating composites for long-duration thermal protection at 2500 °C by cooperative active-passive cooling.COMPOSITES PART B-ENGINEERING,266,11.
MLA Wu, Yue,et al."Construction of C/SiC-Cu3Si-Cu interpenetrating composites for long-duration thermal protection at 2500 °C by cooperative active-passive cooling".COMPOSITES PART B-ENGINEERING 266(2023):11.
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